Development of Three End-Capped Para-Benzoyl Calix[4,6, or 8]arene Bonded Stationary Phases for HPLC
Three end-capped para-benzoyl calixarene bonded silica gel stationary phases are prepared and characterized by elemental analysis, infrared spectroscopy, and thermal analysis. The comparison and selectivity of these phases are investigated by using PAHs, disubstituted benezene, and naphthalene posit...
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| Veröffentlicht in: | Journal of chromatographic science 2012-02, Vol.50 (2), p.123-130 |
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| container_title | Journal of chromatographic science |
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| creator | Hu, Kai Yu, Ajuan Zhang, Junqiang Wen, Fuyong Liang, Song Zhao, Xiaolan Ye, Baoxian Wu, Yangjie Zhang, Shusheng |
| description | Three end-capped para-benzoyl calixarene bonded silica gel stationary phases are prepared and characterized by elemental analysis, infrared spectroscopy, and thermal analysis. The comparison and selectivity of these phases are investigated by using PAHs, disubstituted benezene, and naphthalene positional isomers as probes. Possible separation mechanism based on the different interactions between calixarenes and analytes are discussed. The results indicate that the separation for those analytes are influenced by the supramolecular interaction including π-π interaction, π-electron transfer interactions, space steric hindrance, and hydrogen bonding interaction on the calixarene columns. Importantly, the aromatic probes with polar groups such as -OH, -NO2, and -NH2 could regulate the selectivity of calixarene-bonded stationary phases. |
| doi_str_mv | 10.1093/chromsci/bmr041 |
| format | Article |
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The comparison and selectivity of these phases are investigated by using PAHs, disubstituted benezene, and naphthalene positional isomers as probes. Possible separation mechanism based on the different interactions between calixarenes and analytes are discussed. The results indicate that the separation for those analytes are influenced by the supramolecular interaction including π-π interaction, π-electron transfer interactions, space steric hindrance, and hydrogen bonding interaction on the calixarene columns. Importantly, the aromatic probes with polar groups such as -OH, -NO2, and -NH2 could regulate the selectivity of calixarene-bonded stationary phases.</description><identifier>ISSN: 0021-9665</identifier><identifier>EISSN: 1945-239X</identifier><identifier>DOI: 10.1093/chromsci/bmr041</identifier><identifier>PMID: 22298762</identifier><identifier>CODEN: JCHSBZ</identifier><language>eng</language><publisher>Niles, IL: Oxford University Press</publisher><subject>Analytical chemistry ; Chemistry ; Chromatographic methods and physical methods associated with chromatography ; Exact sciences and technology ; Other chromatographic methods</subject><ispartof>Journal of chromatographic science, 2012-02, Vol.50 (2), p.123-130</ispartof><rights>The Author [2012]. Published by Oxford University Press. All rights reserved. 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The comparison and selectivity of these phases are investigated by using PAHs, disubstituted benezene, and naphthalene positional isomers as probes. Possible separation mechanism based on the different interactions between calixarenes and analytes are discussed. The results indicate that the separation for those analytes are influenced by the supramolecular interaction including π-π interaction, π-electron transfer interactions, space steric hindrance, and hydrogen bonding interaction on the calixarene columns. 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The comparison and selectivity of these phases are investigated by using PAHs, disubstituted benezene, and naphthalene positional isomers as probes. Possible separation mechanism based on the different interactions between calixarenes and analytes are discussed. The results indicate that the separation for those analytes are influenced by the supramolecular interaction including π-π interaction, π-electron transfer interactions, space steric hindrance, and hydrogen bonding interaction on the calixarene columns. Importantly, the aromatic probes with polar groups such as -OH, -NO2, and -NH2 could regulate the selectivity of calixarene-bonded stationary phases.</abstract><cop>Niles, IL</cop><pub>Oxford University Press</pub><pmid>22298762</pmid><doi>10.1093/chromsci/bmr041</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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| source | Oxford University Press Journals All Titles (1996-Current); EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry |
| subjects | Analytical chemistry Chemistry Chromatographic methods and physical methods associated with chromatography Exact sciences and technology Other chromatographic methods |
| title | Development of Three End-Capped Para-Benzoyl Calix[4,6, or 8]arene Bonded Stationary Phases for HPLC |
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