Temperature dependence of pressure broadening and shifts of acetylene at 1550nm by He, Ne, and Ar
Pressure broadening and shift coefficients for the Delta *n1+ Delta *n3 band of 12C2H2 have been measured for He, Ne, and Ar at a temperature of 195 K using high resolution diode laser spectroscopy. The pressure broadening and shifts follow patterns with rotational assignment that are similar to tho...
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Veröffentlicht in: | Applied physics. B, Lasers and optics Lasers and optics, 2008-02, Vol.90 (2), p.255-262 |
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container_title | Applied physics. B, Lasers and optics |
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creator | Bond, K S Collett, N D Fuller, E P Hardwick, J L Hinds, E E Keiber, T W Kelly-Morgan, I S G Matthys, C M Pilkenton, M J Sinclair, K W |
description | Pressure broadening and shift coefficients for the Delta *n1+ Delta *n3 band of 12C2H2 have been measured for He, Ne, and Ar at a temperature of 195 K using high resolution diode laser spectroscopy. The pressure broadening and shifts follow patterns with rotational assignment that are similar to those at room temperature but are generally larger in magnitude. The change in magnitude is qualitatively described by assuming, for each transition, a constant cross section for pressure broadening or shifting. Better agreement may be obtained for pressure broadening coefficients by using empirically determined temperature exponents; better agreement still is obtained from close coupling calculations of the pressure broadening cross sections. |
doi_str_mv | 10.1007/s00340-007-2842-0 |
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The pressure broadening and shifts follow patterns with rotational assignment that are similar to those at room temperature but are generally larger in magnitude. The change in magnitude is qualitatively described by assuming, for each transition, a constant cross section for pressure broadening or shifting. Better agreement may be obtained for pressure broadening coefficients by using empirically determined temperature exponents; better agreement still is obtained from close coupling calculations of the pressure broadening cross sections.</description><identifier>ISSN: 0946-2171</identifier><identifier>DOI: 10.1007/s00340-007-2842-0</identifier><language>eng</language><subject>Acetylene ; Band spectra ; Cross sections ; Lasers ; Mathematical analysis ; Pressure broadening ; Rotational ; Temperature dependence</subject><ispartof>Applied physics. 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B, Lasers and optics</title><description>Pressure broadening and shift coefficients for the Delta *n1+ Delta *n3 band of 12C2H2 have been measured for He, Ne, and Ar at a temperature of 195 K using high resolution diode laser spectroscopy. The pressure broadening and shifts follow patterns with rotational assignment that are similar to those at room temperature but are generally larger in magnitude. The change in magnitude is qualitatively described by assuming, for each transition, a constant cross section for pressure broadening or shifting. Better agreement may be obtained for pressure broadening coefficients by using empirically determined temperature exponents; better agreement still is obtained from close coupling calculations of the pressure broadening cross sections.</description><subject>Acetylene</subject><subject>Band spectra</subject><subject>Cross sections</subject><subject>Lasers</subject><subject>Mathematical analysis</subject><subject>Pressure broadening</subject><subject>Rotational</subject><subject>Temperature dependence</subject><issn>0946-2171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqNirsOgkAQRbfQRHx8gN10Nq7OAvIojdFYWdmbFQbFwII7S-HfC4kf4E1u7s3JEWKpcKMQ4y0jBiHK_ko_CX2JI-FhGkbSV7GaiCnzC_tESeIJfaW6JatdZwlyasnkZDKCpoDWEvOA77bRPS3NA7TJgZ9l4XgwdEbuU5Eh0A7UboemhvsHzrSGS99B3tu5GBe6Ylr8diZWp-P1cJatbd4dsbvVJWdUVdpQ0_EtVWkaYhwHwf_mFzskS7Y</recordid><startdate>20080201</startdate><enddate>20080201</enddate><creator>Bond, K S</creator><creator>Collett, N D</creator><creator>Fuller, E P</creator><creator>Hardwick, J L</creator><creator>Hinds, E E</creator><creator>Keiber, T W</creator><creator>Kelly-Morgan, I S G</creator><creator>Matthys, C M</creator><creator>Pilkenton, M J</creator><creator>Sinclair, K W</creator><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20080201</creationdate><title>Temperature dependence of pressure broadening and shifts of acetylene at 1550nm by He, Ne, and Ar</title><author>Bond, K S ; Collett, N D ; Fuller, E P ; Hardwick, J L ; Hinds, E E ; Keiber, T W ; Kelly-Morgan, I S G ; Matthys, C M ; Pilkenton, M J ; Sinclair, K W</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_9199407733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Acetylene</topic><topic>Band spectra</topic><topic>Cross sections</topic><topic>Lasers</topic><topic>Mathematical analysis</topic><topic>Pressure broadening</topic><topic>Rotational</topic><topic>Temperature dependence</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bond, K S</creatorcontrib><creatorcontrib>Collett, N D</creatorcontrib><creatorcontrib>Fuller, E P</creatorcontrib><creatorcontrib>Hardwick, J L</creatorcontrib><creatorcontrib>Hinds, E E</creatorcontrib><creatorcontrib>Keiber, T W</creatorcontrib><creatorcontrib>Kelly-Morgan, I S G</creatorcontrib><creatorcontrib>Matthys, C M</creatorcontrib><creatorcontrib>Pilkenton, M J</creatorcontrib><creatorcontrib>Sinclair, K W</creatorcontrib><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied physics. B, Lasers and optics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bond, K S</au><au>Collett, N D</au><au>Fuller, E P</au><au>Hardwick, J L</au><au>Hinds, E E</au><au>Keiber, T W</au><au>Kelly-Morgan, I S G</au><au>Matthys, C M</au><au>Pilkenton, M J</au><au>Sinclair, K W</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Temperature dependence of pressure broadening and shifts of acetylene at 1550nm by He, Ne, and Ar</atitle><jtitle>Applied physics. B, Lasers and optics</jtitle><date>2008-02-01</date><risdate>2008</risdate><volume>90</volume><issue>2</issue><spage>255</spage><epage>262</epage><pages>255-262</pages><issn>0946-2171</issn><abstract>Pressure broadening and shift coefficients for the Delta *n1+ Delta *n3 band of 12C2H2 have been measured for He, Ne, and Ar at a temperature of 195 K using high resolution diode laser spectroscopy. The pressure broadening and shifts follow patterns with rotational assignment that are similar to those at room temperature but are generally larger in magnitude. The change in magnitude is qualitatively described by assuming, for each transition, a constant cross section for pressure broadening or shifting. Better agreement may be obtained for pressure broadening coefficients by using empirically determined temperature exponents; better agreement still is obtained from close coupling calculations of the pressure broadening cross sections.</abstract><doi>10.1007/s00340-007-2842-0</doi></addata></record> |
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subjects | Acetylene Band spectra Cross sections Lasers Mathematical analysis Pressure broadening Rotational Temperature dependence |
title | Temperature dependence of pressure broadening and shifts of acetylene at 1550nm by He, Ne, and Ar |
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