Theoretical study of the electronic structure of a tetragonal chromium(III) complex

The low-temperature single-crystal polarized absorption and the luminescence spectra of Cs 2[CrCl 2(H 2O) 4]Cl 3 are theoretically analyzed in order to determine the electronic structure of the trans-[CrCl 2(H 2O) 4] + complex. This study, based on the Racah theory, leads to a good agreement between...

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Veröffentlicht in:	Journal of luminescence 2011-12, Vol.131 (12), p.2515-2520
Hauptverfasser:	Souissi, Hajer, Kammoun, Souha
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: electronic structure, electrical, magnetic, and optical properties CrCl 2(H 2O) 4 chromophore Crystal and ligand fields Electron states Electronic structure Emittance Energy levels Exact sciences and technology Jahn-Teller effect Joining Level splitting and interactions Luminescence Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Photoluminescence Physics Progressions Spectra Transition-metal compounds
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