Synthesis of silica-coated ZnO nanocomposite: the resonance structure of polyvinyl pyrrolidone (PVP) as a coupling agent

The preparation of silica-coated ZnO nanocomposite using polyvinyl pyrrolidone (PVP) as a coupling agent was investigated. Transmission electron microscopy analysis revealed that silica has been deposited on the surface of PVP-capped ZnO nanoparticles as a continuous thin layer. Two-dimensional corr...

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Veröffentlicht in:Colloid and polymer science 2010-12, Vol.288 (18), p.1705-1711
Hauptverfasser: Wang, Jinfeng, Tsuzuki, Takuya, Tang, Bin, Cizek, Pavel, Sun, Lu, Wang, Xungai
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container_end_page 1711
container_issue 18
container_start_page 1705
container_title Colloid and polymer science
container_volume 288
creator Wang, Jinfeng
Tsuzuki, Takuya
Tang, Bin
Cizek, Pavel
Sun, Lu
Wang, Xungai
description The preparation of silica-coated ZnO nanocomposite using polyvinyl pyrrolidone (PVP) as a coupling agent was investigated. Transmission electron microscopy analysis revealed that silica has been deposited on the surface of PVP-capped ZnO nanoparticles as a continuous thin layer. Two-dimensional correlation analysis based on the time-dependent UV-vis spectra was introduced to study the interaction governing the deposition of silica on to PVP-capped ZnO. Strong hydrogen bonds formed between the amphiphilic PVP molecules and silica in the silica-coated PVP-capped ZnO composites. The reduced photocatalytic activity of silica-coated ZnO nanoparticles will enhance their performance as durable, safe, and non-reactive UV blockers in plastics, paints, and coating for outdoor textile and timber products.
doi_str_mv 10.1007/s00396-010-2313-8
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source Springer Nature - Complete Springer Journals
subjects Applied sciences
Catalysis
Catalysts: preparations and properties
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Complex Fluids and Microfluidics
Coupling agent
Coupling agents
Deposition
Exact sciences and technology
Food Science
General and physical chemistry
Nanomaterials
Nanostructure
Nanotechnology and Microengineering
Organic polymers
Original Contribution
Paints
Photocatalytic activity
Physical Chemistry
Physicochemistry of polymers
Polymer Sciences
Properties and characterization
Protective coatings
PVP
Silicon dioxide
Soft and Granular Matter
Special properties (catalyst, reagent or carrier)
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Zinc oxide
ZnO nanoparticles
title Synthesis of silica-coated ZnO nanocomposite: the resonance structure of polyvinyl pyrrolidone (PVP) as a coupling agent
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