Synthesis of silica-coated ZnO nanocomposite: the resonance structure of polyvinyl pyrrolidone (PVP) as a coupling agent
The preparation of silica-coated ZnO nanocomposite using polyvinyl pyrrolidone (PVP) as a coupling agent was investigated. Transmission electron microscopy analysis revealed that silica has been deposited on the surface of PVP-capped ZnO nanoparticles as a continuous thin layer. Two-dimensional corr...
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Veröffentlicht in: | Colloid and polymer science 2010-12, Vol.288 (18), p.1705-1711 |
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creator | Wang, Jinfeng Tsuzuki, Takuya Tang, Bin Cizek, Pavel Sun, Lu Wang, Xungai |
description | The preparation of silica-coated ZnO nanocomposite using polyvinyl pyrrolidone (PVP) as a coupling agent was investigated. Transmission electron microscopy analysis revealed that silica has been deposited on the surface of PVP-capped ZnO nanoparticles as a continuous thin layer. Two-dimensional correlation analysis based on the time-dependent UV-vis spectra was introduced to study the interaction governing the deposition of silica on to PVP-capped ZnO. Strong hydrogen bonds formed between the amphiphilic PVP molecules and silica in the silica-coated PVP-capped ZnO composites. The reduced photocatalytic activity of silica-coated ZnO nanoparticles will enhance their performance as durable, safe, and non-reactive UV blockers in plastics, paints, and coating for outdoor textile and timber products. |
doi_str_mv | 10.1007/s00396-010-2313-8 |
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Transmission electron microscopy analysis revealed that silica has been deposited on the surface of PVP-capped ZnO nanoparticles as a continuous thin layer. Two-dimensional correlation analysis based on the time-dependent UV-vis spectra was introduced to study the interaction governing the deposition of silica on to PVP-capped ZnO. Strong hydrogen bonds formed between the amphiphilic PVP molecules and silica in the silica-coated PVP-capped ZnO composites. The reduced photocatalytic activity of silica-coated ZnO nanoparticles will enhance their performance as durable, safe, and non-reactive UV blockers in plastics, paints, and coating for outdoor textile and timber products.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-010-2313-8</identifier><identifier>CODEN: CPMSB6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Berlin/Heidelberg : Springer-Verlag</publisher><subject>Applied sciences ; Catalysis ; Catalysts: preparations and properties ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Coupling agent ; Coupling agents ; Deposition ; Exact sciences and technology ; Food Science ; General and physical chemistry ; Nanomaterials ; Nanostructure ; Nanotechnology and Microengineering ; Organic polymers ; Original Contribution ; Paints ; Photocatalytic activity ; Physical Chemistry ; Physicochemistry of polymers ; Polymer Sciences ; Properties and characterization ; Protective coatings ; PVP ; Silicon dioxide ; Soft and Granular Matter ; Special properties (catalyst, reagent or carrier) ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ; Zinc oxide ; ZnO nanoparticles</subject><ispartof>Colloid and polymer science, 2010-12, Vol.288 (18), p.1705-1711</ispartof><rights>Springer-Verlag 2010</rights><rights>2015 INIST-CNRS</rights><rights>Colloid and Polymer Science is a copyright of Springer, 2010.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c468t-c8d4fc77b4b8b02e9270c00e6dd5c456c2fd85dd52e90cc25091f041cb0be78c3</citedby><cites>FETCH-LOGICAL-c468t-c8d4fc77b4b8b02e9270c00e6dd5c456c2fd85dd52e90cc25091f041cb0be78c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-010-2313-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-010-2313-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23451983$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Jinfeng</creatorcontrib><creatorcontrib>Tsuzuki, Takuya</creatorcontrib><creatorcontrib>Tang, Bin</creatorcontrib><creatorcontrib>Cizek, Pavel</creatorcontrib><creatorcontrib>Sun, Lu</creatorcontrib><creatorcontrib>Wang, Xungai</creatorcontrib><title>Synthesis of silica-coated ZnO nanocomposite: the resonance structure of polyvinyl pyrrolidone (PVP) as a coupling agent</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>The preparation of silica-coated ZnO nanocomposite using polyvinyl pyrrolidone (PVP) as a coupling agent was investigated. Transmission electron microscopy analysis revealed that silica has been deposited on the surface of PVP-capped ZnO nanoparticles as a continuous thin layer. Two-dimensional correlation analysis based on the time-dependent UV-vis spectra was introduced to study the interaction governing the deposition of silica on to PVP-capped ZnO. Strong hydrogen bonds formed between the amphiphilic PVP molecules and silica in the silica-coated PVP-capped ZnO composites. The reduced photocatalytic activity of silica-coated ZnO nanoparticles will enhance their performance as durable, safe, and non-reactive UV blockers in plastics, paints, and coating for outdoor textile and timber products.</description><subject>Applied sciences</subject><subject>Catalysis</subject><subject>Catalysts: preparations and properties</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Coupling agent</subject><subject>Coupling agents</subject><subject>Deposition</subject><subject>Exact sciences and technology</subject><subject>Food Science</subject><subject>General and physical chemistry</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Nanotechnology and Microengineering</subject><subject>Organic polymers</subject><subject>Original Contribution</subject><subject>Paints</subject><subject>Photocatalytic activity</subject><subject>Physical Chemistry</subject><subject>Physicochemistry of polymers</subject><subject>Polymer Sciences</subject><subject>Properties and characterization</subject><subject>Protective coatings</subject><subject>PVP</subject><subject>Silicon dioxide</subject><subject>Soft and Granular Matter</subject><subject>Special properties (catalyst, reagent or carrier)</subject><subject>Theory of reactions, general kinetics. 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Nomenclature, chemical documentation, computer chemistry</topic><topic>Zinc oxide</topic><topic>ZnO nanoparticles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Jinfeng</creatorcontrib><creatorcontrib>Tsuzuki, Takuya</creatorcontrib><creatorcontrib>Tang, Bin</creatorcontrib><creatorcontrib>Cizek, Pavel</creatorcontrib><creatorcontrib>Sun, Lu</creatorcontrib><creatorcontrib>Wang, Xungai</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Jinfeng</au><au>Tsuzuki, Takuya</au><au>Tang, Bin</au><au>Cizek, Pavel</au><au>Sun, Lu</au><au>Wang, Xungai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of silica-coated ZnO nanocomposite: the resonance structure of polyvinyl pyrrolidone (PVP) as a coupling agent</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2010-12-01</date><risdate>2010</risdate><volume>288</volume><issue>18</issue><spage>1705</spage><epage>1711</epage><pages>1705-1711</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><coden>CPMSB6</coden><abstract>The preparation of silica-coated ZnO nanocomposite using polyvinyl pyrrolidone (PVP) as a coupling agent was investigated. Transmission electron microscopy analysis revealed that silica has been deposited on the surface of PVP-capped ZnO nanoparticles as a continuous thin layer. Two-dimensional correlation analysis based on the time-dependent UV-vis spectra was introduced to study the interaction governing the deposition of silica on to PVP-capped ZnO. Strong hydrogen bonds formed between the amphiphilic PVP molecules and silica in the silica-coated PVP-capped ZnO composites. The reduced photocatalytic activity of silica-coated ZnO nanoparticles will enhance their performance as durable, safe, and non-reactive UV blockers in plastics, paints, and coating for outdoor textile and timber products.</abstract><cop>Berlin/Heidelberg</cop><pub>Berlin/Heidelberg : Springer-Verlag</pub><doi>10.1007/s00396-010-2313-8</doi><tpages>7</tpages></addata></record> |
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subjects | Applied sciences Catalysis Catalysts: preparations and properties Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Coupling agent Coupling agents Deposition Exact sciences and technology Food Science General and physical chemistry Nanomaterials Nanostructure Nanotechnology and Microengineering Organic polymers Original Contribution Paints Photocatalytic activity Physical Chemistry Physicochemistry of polymers Polymer Sciences Properties and characterization Protective coatings PVP Silicon dioxide Soft and Granular Matter Special properties (catalyst, reagent or carrier) Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Zinc oxide ZnO nanoparticles |
title | Synthesis of silica-coated ZnO nanocomposite: the resonance structure of polyvinyl pyrrolidone (PVP) as a coupling agent |
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