Enhanced Binding Affinity, Remarkable Selectivity, and High Capacity of CO2 by Dual Functionalization of a rht-Type Metal-Organic Framework

Open and friendly: The smallest member of the rht‐type metal–organic frameworks (MOFs, see picture) constructed by a hexacarboxylate ligand with a nitrogen‐rich imino triazine backbone shows a significantly enhanced gas binding affinity relative to all other isoreticular rht‐type MOFs. The high adso...

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Veröffentlicht in:	Angewandte Chemie International Edition 2012-02, Vol.51 (6), p.1412-1415
Hauptverfasser:	Li, Baiyan, Zhang, Zhijuan, Li, Yi, Yao, Kexin, Zhu, Yihan, Deng, Zhiyong, Yang, Fen, Zhou, Xiaojing, Li, Guanghua, Wu, Haohan, Nijem, Nour, Chabal, Yves J., Lai, Zhiping, Han, Yu, Shi, Zhan, Feng, Shouhua, Li, Jing
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide carbon dioxide capture gas separation Lewis basic sites metal-organic frameworks open metal sites
Online-Zugang:	Volltext
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