Transamidation of Primary Amides with Amines Using Hydroxylamine Hydrochloride as an Inorganic Catalyst

Metal‐free catalysis: A method for the transamidation of primary amides with primary or secondary amines provides access to secondary and tertiary amides, by utilizing catalytic quantities of hydroxylamine hydrochloride to activate the chemically robust primary amide group (see scheme). A mechanism...

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Veröffentlicht in:	Angewandte Chemie International Edition 2012-02, Vol.51 (6), p.1383-1386
Hauptverfasser:	Allen, C. Liana, Atkinson, Benjamin N., Williams, Jonathan M. J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Amides Amides - chemical synthesis Amides - chemistry Amines Amines - chemistry Catalysis Catalysts Hydrochlorides Hydroxylamine - chemistry hydroxylamines Magnetic Resonance Spectroscopy metal-free catalysis primary amides transamidation
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creator	Allen, C. Liana Atkinson, Benjamin N. Williams, Jonathan M. J.
description	Metal‐free catalysis: A method for the transamidation of primary amides with primary or secondary amines provides access to secondary and tertiary amides, by utilizing catalytic quantities of hydroxylamine hydrochloride to activate the chemically robust primary amide group (see scheme). A mechanism of primary amide activation through a hydrogen‐bonding complex is proposed.
doi_str_mv	10.1002/anie.201107348
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subjects	Activation Amides Amides - chemical synthesis Amides - chemistry Amines Amines - chemistry Catalysis Catalysts Hydrochlorides Hydroxylamine - chemistry hydroxylamines Magnetic Resonance Spectroscopy metal-free catalysis primary amides transamidation
title	Transamidation of Primary Amides with Amines Using Hydroxylamine Hydrochloride as an Inorganic Catalyst
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