A New Synthesis of Triarylsilylium Ions and Their Application in Dihydrogen Activation
Well‐shuffled: An unexpected substituent distribution reaction via alkyldiarylsilylium ions leads to a distribution of substituents. Starting from alkyldiaryl silanes, this reaction provides a facile synthetic approach to sterically highly hindered triarylsilylium ions. These silylium ions can be ap...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie International Edition 2011-12, Vol.50 (52), p.12636-12638 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 12638 |
|---|---|
| container_issue | 52 |
| container_start_page | 12636 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 50 |
| creator | Schäfer, André Reißmann, Matti Schäfer, Annemarie Saak, Wolfgang Haase, Detlev Müller, Thomas |
| description | Well‐shuffled: An unexpected substituent distribution reaction via alkyldiarylsilylium ions leads to a distribution of substituents. Starting from alkyldiaryl silanes, this reaction provides a facile synthetic approach to sterically highly hindered triarylsilylium ions. These silylium ions can be applied in dihydrogen activation reactions. |
| doi_str_mv | 10.1002/anie.201106582 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_918936597</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3277172891</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4432-2ab937c089c407c38b9073cfc75772508521284fec7613b2ba9481c702cf599c3</originalsourceid><addsrcrecordid>eNqFkUtPGzEUha2Kqry67RJZYlE2E_wYj-3lKA0QCYVKBNqd5XE8xHTiCfYMdP59DaERYtGufCV_5-jecwD4gtEII0ROtXd2RBDGqGCCfAB7mBGcUc7pTppzSjMuGN4F-zHeJ14IVHwCu4QgThgu9sBtCWf2CV4Pvlva6CJsazgPToehia4ZGtev4LT1EWq_gPOldQGW63XjjO5c66Hz8JtbDovQ3lkPS9O5x5ePQ_Cx1k20n1_fA3BzNpmPL7LLq_PpuLzMTJ5TkhFdScoNEtLkiBsqKok4NbXhjKcFkUjHEJHX1vAC04pUWuYCG46IqZmUhh6ArxvfdWgfehs7tXLR2KbR3rZ9VBILSQsmeSJP_klinkLEjCKW0ON36H3bB5_uUDiFVjCesESNNpQJbYzB1mod3CoFpzBSz92o527UtpskOHq17auVXWzxv2UkQG6AJ9fY4T92qpxNJ2_Ns43Wxc7-3mp1-KUKTjlTP2bnio1_Xn-fF1jd0j_t-6fP</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1516657530</pqid></control><display><type>article</type><title>A New Synthesis of Triarylsilylium Ions and Their Application in Dihydrogen Activation</title><source>MEDLINE</source><source>Access via Wiley Online Library</source><creator>Schäfer, André ; Reißmann, Matti ; Schäfer, Annemarie ; Saak, Wolfgang ; Haase, Detlev ; Müller, Thomas</creator><creatorcontrib>Schäfer, André ; Reißmann, Matti ; Schäfer, Annemarie ; Saak, Wolfgang ; Haase, Detlev ; Müller, Thomas</creatorcontrib><description>Well‐shuffled: An unexpected substituent distribution reaction via alkyldiarylsilylium ions leads to a distribution of substituents. Starting from alkyldiaryl silanes, this reaction provides a facile synthetic approach to sterically highly hindered triarylsilylium ions. These silylium ions can be applied in dihydrogen activation reactions.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201106582</identifier><identifier>PMID: 22072516</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Activation ; dihydrogen activation ; frustrated Lewis pairs ; Hydrogen - chemistry ; Ions - chemical synthesis ; Ions - chemistry ; Lewis acids ; Molecular Structure ; NMR spectroscopy ; Organosilicon Compounds - chemical synthesis ; Organosilicon Compounds - chemistry ; Silanes ; silylium ions ; Synthesis</subject><ispartof>Angewandte Chemie International Edition, 2011-12, Vol.50 (52), p.12636-12638</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4432-2ab937c089c407c38b9073cfc75772508521284fec7613b2ba9481c702cf599c3</citedby><cites>FETCH-LOGICAL-c4432-2ab937c089c407c38b9073cfc75772508521284fec7613b2ba9481c702cf599c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201106582$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201106582$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22072516$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Schäfer, André</creatorcontrib><creatorcontrib>Reißmann, Matti</creatorcontrib><creatorcontrib>Schäfer, Annemarie</creatorcontrib><creatorcontrib>Saak, Wolfgang</creatorcontrib><creatorcontrib>Haase, Detlev</creatorcontrib><creatorcontrib>Müller, Thomas</creatorcontrib><title>A New Synthesis of Triarylsilylium Ions and Their Application in Dihydrogen Activation</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Well‐shuffled: An unexpected substituent distribution reaction via alkyldiarylsilylium ions leads to a distribution of substituents. Starting from alkyldiaryl silanes, this reaction provides a facile synthetic approach to sterically highly hindered triarylsilylium ions. These silylium ions can be applied in dihydrogen activation reactions.</description><subject>Activation</subject><subject>dihydrogen activation</subject><subject>frustrated Lewis pairs</subject><subject>Hydrogen - chemistry</subject><subject>Ions - chemical synthesis</subject><subject>Ions - chemistry</subject><subject>Lewis acids</subject><subject>Molecular Structure</subject><subject>NMR spectroscopy</subject><subject>Organosilicon Compounds - chemical synthesis</subject><subject>Organosilicon Compounds - chemistry</subject><subject>Silanes</subject><subject>silylium ions</subject><subject>Synthesis</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUtPGzEUha2Kqry67RJZYlE2E_wYj-3lKA0QCYVKBNqd5XE8xHTiCfYMdP59DaERYtGufCV_5-jecwD4gtEII0ROtXd2RBDGqGCCfAB7mBGcUc7pTppzSjMuGN4F-zHeJ14IVHwCu4QgThgu9sBtCWf2CV4Pvlva6CJsazgPToehia4ZGtev4LT1EWq_gPOldQGW63XjjO5c66Hz8JtbDovQ3lkPS9O5x5ePQ_Cx1k20n1_fA3BzNpmPL7LLq_PpuLzMTJ5TkhFdScoNEtLkiBsqKok4NbXhjKcFkUjHEJHX1vAC04pUWuYCG46IqZmUhh6ArxvfdWgfehs7tXLR2KbR3rZ9VBILSQsmeSJP_klinkLEjCKW0ON36H3bB5_uUDiFVjCesESNNpQJbYzB1mod3CoFpzBSz92o527UtpskOHq17auVXWzxv2UkQG6AJ9fY4T92qpxNJ2_Ns43Wxc7-3mp1-KUKTjlTP2bnio1_Xn-fF1jd0j_t-6fP</recordid><startdate>20111223</startdate><enddate>20111223</enddate><creator>Schäfer, André</creator><creator>Reißmann, Matti</creator><creator>Schäfer, Annemarie</creator><creator>Saak, Wolfgang</creator><creator>Haase, Detlev</creator><creator>Müller, Thomas</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope></search><sort><creationdate>20111223</creationdate><title>A New Synthesis of Triarylsilylium Ions and Their Application in Dihydrogen Activation</title><author>Schäfer, André ; Reißmann, Matti ; Schäfer, Annemarie ; Saak, Wolfgang ; Haase, Detlev ; Müller, Thomas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4432-2ab937c089c407c38b9073cfc75772508521284fec7613b2ba9481c702cf599c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Activation</topic><topic>dihydrogen activation</topic><topic>frustrated Lewis pairs</topic><topic>Hydrogen - chemistry</topic><topic>Ions - chemical synthesis</topic><topic>Ions - chemistry</topic><topic>Lewis acids</topic><topic>Molecular Structure</topic><topic>NMR spectroscopy</topic><topic>Organosilicon Compounds - chemical synthesis</topic><topic>Organosilicon Compounds - chemistry</topic><topic>Silanes</topic><topic>silylium ions</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schäfer, André</creatorcontrib><creatorcontrib>Reißmann, Matti</creatorcontrib><creatorcontrib>Schäfer, Annemarie</creatorcontrib><creatorcontrib>Saak, Wolfgang</creatorcontrib><creatorcontrib>Haase, Detlev</creatorcontrib><creatorcontrib>Müller, Thomas</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schäfer, André</au><au>Reißmann, Matti</au><au>Schäfer, Annemarie</au><au>Saak, Wolfgang</au><au>Haase, Detlev</au><au>Müller, Thomas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A New Synthesis of Triarylsilylium Ions and Their Application in Dihydrogen Activation</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2011-12-23</date><risdate>2011</risdate><volume>50</volume><issue>52</issue><spage>12636</spage><epage>12638</epage><pages>12636-12638</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>Well‐shuffled: An unexpected substituent distribution reaction via alkyldiarylsilylium ions leads to a distribution of substituents. Starting from alkyldiaryl silanes, this reaction provides a facile synthetic approach to sterically highly hindered triarylsilylium ions. These silylium ions can be applied in dihydrogen activation reactions.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>22072516</pmid><doi>10.1002/anie.201106582</doi><tpages>3</tpages><edition>International ed. in English</edition></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2011-12, Vol.50 (52), p.12636-12638 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_918936597 |
| source | MEDLINE; Access via Wiley Online Library |
| subjects | Activation dihydrogen activation frustrated Lewis pairs Hydrogen - chemistry Ions - chemical synthesis Ions - chemistry Lewis acids Molecular Structure NMR spectroscopy Organosilicon Compounds - chemical synthesis Organosilicon Compounds - chemistry Silanes silylium ions Synthesis |
| title | A New Synthesis of Triarylsilylium Ions and Their Application in Dihydrogen Activation |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-21T12%3A05%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20New%20Synthesis%20of%20Triarylsilylium%20Ions%20and%20Their%20Application%20in%20Dihydrogen%20Activation&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Sch%C3%A4fer,%20Andr%C3%A9&rft.date=2011-12-23&rft.volume=50&rft.issue=52&rft.spage=12636&rft.epage=12638&rft.pages=12636-12638&rft.issn=1433-7851&rft.eissn=1521-3773&rft.coden=ACIEAY&rft_id=info:doi/10.1002/anie.201106582&rft_dat=%3Cproquest_cross%3E3277172891%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1516657530&rft_id=info:pmid/22072516&rfr_iscdi=true |