Oxidative Mizoroki-Heck-Type Reaction of Arylsulfonyl Hydrazides for a Highly Regio- and Stereoselective Synthesis of Polysubstituted Alkenes

A useful source: Arylsulfonyl hydrazides have been identified as synthetically useful aryl sources for the Pd(OAc)2 catalyzed oxidative Mizoroki–Heck‐type reaction under molecular oxygen to provide a convenient access to polysubstituted alkenes in a highly regio‐ and stereoselective manner (see sche...

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Veröffentlicht in:	Chemistry : a European journal 2012-02, Vol.18 (6), p.1582-1585
Hauptverfasser:	Yang, Fu-Lai, Ma, Xian-Tao, Tian, Shi-Kai
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Alkenes - chemical synthesis Alkenes - chemistry Amides Aromatic compounds Carboxylic acids Catalysis Chemical reactions Chemistry Combinatorial Chemistry Techniques cross-coupling Esters Halos Hydrazides Hydrazines - chemistry Mizoroki-Heck reaction Molecular Structure oxidation Oxidation-Reduction palladium Palladium - chemistry Spectrometry, Mass, Electrospray Ionization Stereoisomerism Sulfones - chemistry
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