Hydrogen production using cobalt-based molecular catalysts containing a proton relay in the second coordination sphere

The cobalt analogue of a highly active nickel electrocatalyst for hydrogen production has been synthesized and characterized as [Co(PPh2NPh2)2(CH3CN)](BF4)2. In the presence of triflic acid in acetonitrile solution, the complex loses one cyclic diphosphine ligand to form [Co(PPh2NPh2)(CH3CN)3](BF4)2...

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Veröffentlicht in:	Energy & Environmental Science, 1(1):167-174 1(1):167-174, 2008-01, Vol.1 (1), p.167-174
Hauptverfasser:	Jacobsen, George M, Yang, Jenny Y, Twamley, Brendan, Wilson, Aaron D, Bullock, RMorris, Rakowski DuBois, M, DuBois, Daniel L
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Catalysis Catalysts Cobalt Electrocatalysts Hydrogen production Ligands Triflic acid
Online-Zugang:	Volltext
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