Synthetic studies on soft coral norcembranolides: total synthesis of (+)-10-epigyrosanolide E

Synthetic studies on soft coral norcembranolides: total synthesis of (+)-10-epigyrosanolide E

Total synthesis of (+)-10-epigyrosanolide E was accomplished employing SmI 2-mediated 5- exo cyclization of an aldehydo β-alkoxyvinyl sulfoxide and ring-closing metathesis reaction. [Display omitted]

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Veröffentlicht in:Tetrahedron 2011-12, Vol.67 (52), p.10179-10185
Hauptverfasser: Kwon, Min Sang, Sim, So Hee, Chung, Young Keun, Lee, Eun
Format: Artikel
Sprache:eng
Schlagworte:
10-Epigyrosanolide E
Beta-alkoxyvinyl sulfoxides
Chemistry
Corals
Decomposition reactions
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Metathesis
Norcembranolides
Organic chemistry
Preparations and properties
Ring-closing olefin metathesis
Samarium iodide
Synthesis (chemistry)
Tetrahedrons
Total synthesis
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Zusammenfassung:Total synthesis of (+)-10-epigyrosanolide E was accomplished employing SmI 2-mediated 5- exo cyclization of an aldehydo β-alkoxyvinyl sulfoxide and ring-closing metathesis reaction. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2011.09.011