Characterization of nonvolatile aqueous chlorination products of humic substances
The effects were studied of chlorination parameters, such as reaction time, chlorine/carbon ratio, pH and source of humic material, on the formation of nonvolatile organic chlorine compounds during the chlorination process. The process was followed both qualitatively and quantitatively. The quantita...
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| Veröffentlicht in: | Environ. Sci. Technol.; (United States) 1983-03, Vol.17 (3), p.150-157 |
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| container_title | Environ. Sci. Technol.; (United States) |
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| creator | Miller, Joel W Uden, Peter C |
| description | The effects were studied of chlorination parameters, such as reaction time, chlorine/carbon ratio, pH and source of humic material, on the formation of nonvolatile organic chlorine compounds during the chlorination process. The process was followed both qualitatively and quantitatively. The quantitation procedure for haloforms in the chlorine/fulvic acid reaction consists of air-tight sampling vials, purge and trap techniques and gas chromatography with a microwave plasma emission detector. Chlorine-selection fingerprint studies were undertaken to follow the formation of 17 major chlorinated products. Detailed data are presented on the formation of chloroform, dichloroacetic acid, trichloroacetic acid and chloral hydrate. |
| doi_str_mv | 10.1021/es00109a006 |
| format | Article |
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The process was followed both qualitatively and quantitatively. The quantitation procedure for haloforms in the chlorine/fulvic acid reaction consists of air-tight sampling vials, purge and trap techniques and gas chromatography with a microwave plasma emission detector. Chlorine-selection fingerprint studies were undertaken to follow the formation of 17 major chlorinated products. 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Sci. Technol.; (United States)</title><addtitle>Environ. Sci. Technol</addtitle><description>The effects were studied of chlorination parameters, such as reaction time, chlorine/carbon ratio, pH and source of humic material, on the formation of nonvolatile organic chlorine compounds during the chlorination process. The process was followed both qualitatively and quantitatively. The quantitation procedure for haloforms in the chlorine/fulvic acid reaction consists of air-tight sampling vials, purge and trap techniques and gas chromatography with a microwave plasma emission detector. Chlorine-selection fingerprint studies were undertaken to follow the formation of 17 major chlorinated products. Detailed data are presented on the formation of chloroform, dichloroacetic acid, trichloroacetic acid and chloral hydrate.</description><subject>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</subject><subject>520200 - Environment, Aquatic- Chemicals Monitoring & Transport- (-1989)</subject><subject>CHEMICAL ANALYSIS</subject><subject>CHEMICAL REACTION KINETICS</subject><subject>CHEMICAL REACTIONS</subject><subject>CHLORINATION</subject><subject>CHROMATOGRAPHY</subject><subject>ENVIRONMENTAL SCIENCES</subject><subject>FULVIC ACIDS</subject><subject>GAS CHROMATOGRAPHY</subject><subject>HALOGENATION</subject><subject>HUMIC ACIDS</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>KINETICS</subject><subject>ORGANIC ACIDS</subject><subject>ORGANIC CHLORINE COMPOUNDS</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC HALOGEN COMPOUNDS</subject><subject>PH VALUE</subject><subject>QUALITATIVE CHEMICAL ANALYSIS</subject><subject>QUANTITATIVE CHEMICAL ANALYSIS</subject><subject>REACTION KINETICS</subject><subject>SEPARATION PROCESSES</subject><subject>SURFACE WATERS</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1983</creationdate><recordtype>article</recordtype><recordid>eNp90c9vFCEUB3BiNHZdPXk3Ew96MKOP38Ox2Whr2vgjbY03wjDgUmehwoxR_3rZTG09GE8E-OTxHl-EHmN4iYHgV64AYFAGQNxBK8wJtLzj-C5a1XPaKio-H6AHpVwCAKHQ3UcHhBBBhVQr9HGzNdnYyeXwy0whxSb5Jqb4PY11O7rGfJtdmktjt2PKIS7mKqdhtlPZ4-28C7Ypc18mE60rD9E9b8biHl2va3Tx5vX55rg9fX_0dnN42hrKQbV-sL1U0BMuGKVEeNV5BoJK4k3fG8YxFrwn1Fs6SOwHx7ACxaVhivCBWbpGT5e6qUxBFxsmZ7c2xejspDkQpqiq6PmCasd1kDLpXSjWjaOJ-6m0wpJLpRir8tl_JaadBFW_bY1eLNDmVEp2Xl_lsDP5p8ag94HovwKp-sl12bnfueHG_kmggnYBoUzux829yV-1kFRyff7hTJ-86-Do0zHTJ7cFvUnafMmh6IszrDq2f1NwdjuysUVfpjnHmsI_e_sNfb2p-w</recordid><startdate>19830301</startdate><enddate>19830301</enddate><creator>Miller, Joel W</creator><creator>Uden, Peter C</creator><general>American Chemical Society</general><scope>FBQ</scope><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>19830301</creationdate><title>Characterization of nonvolatile aqueous chlorination products of humic substances</title><author>Miller, Joel W ; Uden, Peter C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a3509-fdcb790b25643326f98f406372fabba451165b23fc3d71fde4190957a4925d4c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1983</creationdate><topic>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</topic><topic>520200 - Environment, Aquatic- Chemicals Monitoring & Transport- (-1989)</topic><topic>CHEMICAL ANALYSIS</topic><topic>CHEMICAL REACTION KINETICS</topic><topic>CHEMICAL REACTIONS</topic><topic>CHLORINATION</topic><topic>CHROMATOGRAPHY</topic><topic>ENVIRONMENTAL SCIENCES</topic><topic>FULVIC ACIDS</topic><topic>GAS CHROMATOGRAPHY</topic><topic>HALOGENATION</topic><topic>HUMIC ACIDS</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>KINETICS</topic><topic>ORGANIC ACIDS</topic><topic>ORGANIC CHLORINE COMPOUNDS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC HALOGEN COMPOUNDS</topic><topic>PH VALUE</topic><topic>QUALITATIVE CHEMICAL ANALYSIS</topic><topic>QUANTITATIVE CHEMICAL ANALYSIS</topic><topic>REACTION KINETICS</topic><topic>SEPARATION PROCESSES</topic><topic>SURFACE WATERS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Miller, Joel W</creatorcontrib><creatorcontrib>Uden, Peter C</creatorcontrib><creatorcontrib>Univ. of Massachusetts, Amherst</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>Environ. Sci. Technol.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Miller, Joel W</au><au>Uden, Peter C</au><aucorp>Univ. of Massachusetts, Amherst</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of nonvolatile aqueous chlorination products of humic substances</atitle><jtitle>Environ. Sci. Technol.; (United States)</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>1983-03-01</date><risdate>1983</risdate><volume>17</volume><issue>3</issue><spage>150</spage><epage>157</epage><pages>150-157</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><abstract>The effects were studied of chlorination parameters, such as reaction time, chlorine/carbon ratio, pH and source of humic material, on the formation of nonvolatile organic chlorine compounds during the chlorination process. The process was followed both qualitatively and quantitatively. The quantitation procedure for haloforms in the chlorine/fulvic acid reaction consists of air-tight sampling vials, purge and trap techniques and gas chromatography with a microwave plasma emission detector. Chlorine-selection fingerprint studies were undertaken to follow the formation of 17 major chlorinated products. Detailed data are presented on the formation of chloroform, dichloroacetic acid, trichloroacetic acid and chloral hydrate.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>22263679</pmid><doi>10.1021/es00109a006</doi><tpages>8</tpages></addata></record> |
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| identifier | ISSN: 0013-936X |
| ispartof | Environ. Sci. Technol.; (United States), 1983-03, Vol.17 (3), p.150-157 |
| issn | 0013-936X 1520-5851 |
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| source | ACS Publications |
| subjects | 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) 520200 - Environment, Aquatic- Chemicals Monitoring & Transport- (-1989) CHEMICAL ANALYSIS CHEMICAL REACTION KINETICS CHEMICAL REACTIONS CHLORINATION CHROMATOGRAPHY ENVIRONMENTAL SCIENCES FULVIC ACIDS GAS CHROMATOGRAPHY HALOGENATION HUMIC ACIDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KINETICS ORGANIC ACIDS ORGANIC CHLORINE COMPOUNDS ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS PH VALUE QUALITATIVE CHEMICAL ANALYSIS QUANTITATIVE CHEMICAL ANALYSIS REACTION KINETICS SEPARATION PROCESSES SURFACE WATERS |
| title | Characterization of nonvolatile aqueous chlorination products of humic substances |
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