Electrochemical Synthesis of Indium(0) Nanoparticles in Haloindate(III) Ionic Liquids
A synthetic route to indium(0) nanoparticles via an electrochemical reduction of haloindate(III) ionic liquids to indium(I), and its subsequent disproportionation to indium(0) and indium(III) in the bulk electrolyte, is described. In this sustainable method, the ionic liquid acts simultaneously as m...
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| Veröffentlicht in: | ChemSusChem 2012-01, Vol.5 (1), p.117-124 |
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| creator | Estager, Julien Nockemann, Peter Seddon, Kenneth R. Srinivasan, Geetha Swadźba-Kwaśny, Małgorzata |
| description | A synthetic route to indium(0) nanoparticles via an electrochemical reduction of haloindate(III) ionic liquids to indium(I), and its subsequent disproportionation to indium(0) and indium(III) in the bulk electrolyte, is described. In this sustainable method, the ionic liquid acts simultaneously as metal source, templating agent, and stabilising agent, with the electron as the only reducing agent. The nature of the ionic liquid cation is demonstrated to strongly affect the morphology and size distribution of the indium(0) nanoparticles.
Halo III: A new synthetic route to indium(0) nanoparticles via an electrochemical reduction of haloindate(III) ionic liquids to indium(I), and its subsequent disproportionation to indium(0) and indium(III) in the bulk electrolyte, is reported. In this sustainable method, the ionic liquid acts simultaneously as metal source, templating agent, and stabilizing agent, with the electron as the only reducing agent. |
| doi_str_mv | 10.1002/cssc.201100331 |
| format | Article |
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Halo III: A new synthetic route to indium(0) nanoparticles via an electrochemical reduction of haloindate(III) ionic liquids to indium(I), and its subsequent disproportionation to indium(0) and indium(III) in the bulk electrolyte, is reported. In this sustainable method, the ionic liquid acts simultaneously as metal source, templating agent, and stabilizing agent, with the electron as the only reducing agent.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.201100331</identifier><identifier>PMID: 22086860</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Chemistry Techniques, Synthetic - methods ; electrochemistry ; Electrochemistry - methods ; green chemistry ; Halogenation ; indium ; Indium - chemistry ; ionic liquids ; Ionic Liquids - chemistry ; Metal Nanoparticles - chemistry ; nanoparticles ; Oxidation-Reduction ; Temperature</subject><ispartof>ChemSusChem, 2012-01, Vol.5 (1), p.117-124</ispartof><rights>Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4481-d5d6468519e29ccbe0492a9c7da10b41bbff31c2854512ff7ecb4300f3f186203</citedby><cites>FETCH-LOGICAL-c4481-d5d6468519e29ccbe0492a9c7da10b41bbff31c2854512ff7ecb4300f3f186203</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcssc.201100331$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcssc.201100331$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,27911,27912,45561,45562</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22086860$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Estager, Julien</creatorcontrib><creatorcontrib>Nockemann, Peter</creatorcontrib><creatorcontrib>Seddon, Kenneth R.</creatorcontrib><creatorcontrib>Srinivasan, Geetha</creatorcontrib><creatorcontrib>Swadźba-Kwaśny, Małgorzata</creatorcontrib><title>Electrochemical Synthesis of Indium(0) Nanoparticles in Haloindate(III) Ionic Liquids</title><title>ChemSusChem</title><addtitle>ChemSusChem</addtitle><description>A synthetic route to indium(0) nanoparticles via an electrochemical reduction of haloindate(III) ionic liquids to indium(I), and its subsequent disproportionation to indium(0) and indium(III) in the bulk electrolyte, is described. In this sustainable method, the ionic liquid acts simultaneously as metal source, templating agent, and stabilising agent, with the electron as the only reducing agent. The nature of the ionic liquid cation is demonstrated to strongly affect the morphology and size distribution of the indium(0) nanoparticles.
Halo III: A new synthetic route to indium(0) nanoparticles via an electrochemical reduction of haloindate(III) ionic liquids to indium(I), and its subsequent disproportionation to indium(0) and indium(III) in the bulk electrolyte, is reported. In this sustainable method, the ionic liquid acts simultaneously as metal source, templating agent, and stabilizing agent, with the electron as the only reducing agent.</description><subject>Chemistry Techniques, Synthetic - methods</subject><subject>electrochemistry</subject><subject>Electrochemistry - methods</subject><subject>green chemistry</subject><subject>Halogenation</subject><subject>indium</subject><subject>Indium - chemistry</subject><subject>ionic liquids</subject><subject>Ionic Liquids - chemistry</subject><subject>Metal Nanoparticles - chemistry</subject><subject>nanoparticles</subject><subject>Oxidation-Reduction</subject><subject>Temperature</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkM9LwzAUx4Mobv64epTenIfOvCRN26OMqYUxwTr0FtI0YdH-2JoW3X9vZVq8eXrvwef7hfdB6ALwFDAmN8o5NSUY-oNSOEBjiDjzA85eD4edwgidOPeGMccx58doRAiOeMTxGK3mhVZtU6u1Lq2ShZfuqnatnXVebbykym1XTvC1t5RVvZFNa1WhnWcr70EWta1y2epJkiTXXlJXVnkLu-1s7s7QkZGF0-c_8xSt7ubPswd_8XifzG4XvmIsAj8Pcs54FECsSaxUpjGLiYxVmEvAGYMsM4aCIlHAAiDGhFpljGJsqOlfI5ieoqt976apt512rSitU7ooZKXrzokYOI9DgKAnp3tSNbVzjTZi09hSNjsBWHybFN8mxWCyD1z-VHdZqfMB_1XXA_Ee-LCF3v1TJ2ZpOvtb7u-z1rX6c8jK5l3wkIaBeFneC4hocPcUpeKJfgE8qI3z</recordid><startdate>20120109</startdate><enddate>20120109</enddate><creator>Estager, Julien</creator><creator>Nockemann, Peter</creator><creator>Seddon, Kenneth R.</creator><creator>Srinivasan, Geetha</creator><creator>Swadźba-Kwaśny, Małgorzata</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20120109</creationdate><title>Electrochemical Synthesis of Indium(0) Nanoparticles in Haloindate(III) Ionic Liquids</title><author>Estager, Julien ; Nockemann, Peter ; Seddon, Kenneth R. ; Srinivasan, Geetha ; Swadźba-Kwaśny, Małgorzata</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4481-d5d6468519e29ccbe0492a9c7da10b41bbff31c2854512ff7ecb4300f3f186203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Chemistry Techniques, Synthetic - methods</topic><topic>electrochemistry</topic><topic>Electrochemistry - methods</topic><topic>green chemistry</topic><topic>Halogenation</topic><topic>indium</topic><topic>Indium - chemistry</topic><topic>ionic liquids</topic><topic>Ionic Liquids - chemistry</topic><topic>Metal Nanoparticles - chemistry</topic><topic>nanoparticles</topic><topic>Oxidation-Reduction</topic><topic>Temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Estager, Julien</creatorcontrib><creatorcontrib>Nockemann, Peter</creatorcontrib><creatorcontrib>Seddon, Kenneth R.</creatorcontrib><creatorcontrib>Srinivasan, Geetha</creatorcontrib><creatorcontrib>Swadźba-Kwaśny, Małgorzata</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Estager, Julien</au><au>Nockemann, Peter</au><au>Seddon, Kenneth R.</au><au>Srinivasan, Geetha</au><au>Swadźba-Kwaśny, Małgorzata</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical Synthesis of Indium(0) Nanoparticles in Haloindate(III) Ionic Liquids</atitle><jtitle>ChemSusChem</jtitle><addtitle>ChemSusChem</addtitle><date>2012-01-09</date><risdate>2012</risdate><volume>5</volume><issue>1</issue><spage>117</spage><epage>124</epage><pages>117-124</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>A synthetic route to indium(0) nanoparticles via an electrochemical reduction of haloindate(III) ionic liquids to indium(I), and its subsequent disproportionation to indium(0) and indium(III) in the bulk electrolyte, is described. In this sustainable method, the ionic liquid acts simultaneously as metal source, templating agent, and stabilising agent, with the electron as the only reducing agent. The nature of the ionic liquid cation is demonstrated to strongly affect the morphology and size distribution of the indium(0) nanoparticles.
Halo III: A new synthetic route to indium(0) nanoparticles via an electrochemical reduction of haloindate(III) ionic liquids to indium(I), and its subsequent disproportionation to indium(0) and indium(III) in the bulk electrolyte, is reported. In this sustainable method, the ionic liquid acts simultaneously as metal source, templating agent, and stabilizing agent, with the electron as the only reducing agent.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>22086860</pmid><doi>10.1002/cssc.201100331</doi><tpages>8</tpages></addata></record> |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Chemistry Techniques, Synthetic - methods electrochemistry Electrochemistry - methods green chemistry Halogenation indium Indium - chemistry ionic liquids Ionic Liquids - chemistry Metal Nanoparticles - chemistry nanoparticles Oxidation-Reduction Temperature |
| title | Electrochemical Synthesis of Indium(0) Nanoparticles in Haloindate(III) Ionic Liquids |
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