Synthesis and Methane-Binding Properties of Disulfide-Linked Cryptophane-0.0.0

Synthesis and Methane-Binding Properties of Disulfide-Linked Cryptophane-0.0.0

Into the crypt: Direct coupling of cyclotrithiophenolene gives a new class of cryptophane with labile disulfide linkages, which is the smallest cryptophane yet reported. The new cryptophane (see structure, S yellow, C gray, H light gray) is shown to bind methane or nitrogen in solution.

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2012-01, Vol.51 (3), p.764-766
Hauptverfasser: Little, Marc A., Donkin, Jessica, Fisher, Julie, Halcrow, Malcolm A., Loder, Jordan, Hardie, Michaele J.
Format: Artikel
Sprache:eng
Schlagworte:
cryptophanes
disulfide bonds
host-guest chemistry
methane binding
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Beschreibung
Zusammenfassung:Into the crypt: Direct coupling of cyclotrithiophenolene gives a new class of cryptophane with labile disulfide linkages, which is the smallest cryptophane yet reported. The new cryptophane (see structure, S yellow, C gray, H light gray) is shown to bind methane or nitrogen in solution.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201106512