Thermal and IR studies on copper doped polyvinyl alcohol

5 mol% PVA: x mol% Cu2+ polymer films were prepared by casting process. Thermal transitions and thermal degradation of samples with respect to copper concentration were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. Increase in glass transition...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Bulletin of materials science 2007-06, Vol.30 (3), p.215-218
Hauptverfasser: Raju, Ch. Linga, Rao, J. L., Reddy, B. C. V., Veera Brahmam, K.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 218
container_issue 3
container_start_page 215
container_title Bulletin of materials science
container_volume 30
creator Raju, Ch. Linga
Rao, J. L.
Reddy, B. C. V.
Veera Brahmam, K.
description 5 mol% PVA: x mol% Cu2+ polymer films were prepared by casting process. Thermal transitions and thermal degradation of samples with respect to copper concentration were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. Increase in glass transition temperature as a function of copper concentration shows a strong branching and steric effects in copper doped PVA complexes. Thermal degradation of films to an extent of 4–5% was found with an increase in copper content. FTIR spectrum of PVA doped Cu2+ ions indicate the presence of O-H, C-H, C=C and C-O groups.
doi_str_mv 10.1007/s12034-007-0038-1
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_914659378</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>914659378</sourcerecordid><originalsourceid>FETCH-LOGICAL-c347t-b5236de9fe239909297b8faf75f8ca5fea56b15761ecee6adaf355109481ae123</originalsourceid><addsrcrecordid>eNpdkE1LAzEQhoMoWKs_wNvixdNqZvO1OYr4USgIUs8hzU7olnSzJl2h_96UevIwzHt4eJl5CLkF-gCUqscMDWW8LrEMa2s4IzOqFauVlPq85EbQmiuqLslVzltKQXMOM9KuNph2NlR26KrFZ5X3U9djruJQuTiOmKoujthVYwyHn344FDC4uInhmlx4GzLe_O05-Xp9WT2_18uPt8Xz07J2jKt9vRYNkx1qjw3TmupGq3XrrVfCt84Kj1bINQglAR2itJ31TAigmrdgERo2J_en3jHF7wnz3uz67DAEO2CcstHApdBMtYW8-0du45SGcpxplZaclYcLBCfIpZhzQm_G1O9sOhig5mjSnEyaYzyaNMB-AVOxZT8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>879643441</pqid></control><display><type>article</type><title>Thermal and IR studies on copper doped polyvinyl alcohol</title><source>Indian Academy of Sciences</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>Free Full-Text Journals in Chemistry</source><source>SpringerLink Journals - AutoHoldings</source><source>ProQuest Central</source><creator>Raju, Ch. Linga ; Rao, J. L. ; Reddy, B. C. V. ; Veera Brahmam, K.</creator><creatorcontrib>Raju, Ch. Linga ; Rao, J. L. ; Reddy, B. C. V. ; Veera Brahmam, K.</creatorcontrib><description>5 mol% PVA: x mol% Cu2+ polymer films were prepared by casting process. Thermal transitions and thermal degradation of samples with respect to copper concentration were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. Increase in glass transition temperature as a function of copper concentration shows a strong branching and steric effects in copper doped PVA complexes. Thermal degradation of films to an extent of 4–5% was found with an increase in copper content. FTIR spectrum of PVA doped Cu2+ ions indicate the presence of O-H, C-H, C=C and C-O groups.</description><identifier>ISSN: 0250-4707</identifier><identifier>EISSN: 0973-7669</identifier><identifier>DOI: 10.1007/s12034-007-0038-1</identifier><language>eng</language><publisher>Bangalore: Springer Nature B.V</publisher><subject>ALCOHOLS ; CALORIMETRY ; Copper ; Differential scanning calorimetry ; DOPING ; Glass transition temperature ; Infrared radiation ; INFRARED RAYS ; Polymer films ; Polymeric films ; POLYMERS ; Polyvinyl alcohol ; Polyvinyl alcohols ; Steric effects ; Thermal degradation ; THERMOGRAVIMETRIC ANALYSIS ; TRANSITION TEMPERATURE</subject><ispartof>Bulletin of materials science, 2007-06, Vol.30 (3), p.215-218</ispartof><rights>Indian Academy of Sciences 2007.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c347t-b5236de9fe239909297b8faf75f8ca5fea56b15761ecee6adaf355109481ae123</citedby><cites>FETCH-LOGICAL-c347t-b5236de9fe239909297b8faf75f8ca5fea56b15761ecee6adaf355109481ae123</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/879643441/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/879643441?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21367,27901,27902,33721,33722,43781,74045</link.rule.ids></links><search><creatorcontrib>Raju, Ch. Linga</creatorcontrib><creatorcontrib>Rao, J. L.</creatorcontrib><creatorcontrib>Reddy, B. C. V.</creatorcontrib><creatorcontrib>Veera Brahmam, K.</creatorcontrib><title>Thermal and IR studies on copper doped polyvinyl alcohol</title><title>Bulletin of materials science</title><description>5 mol% PVA: x mol% Cu2+ polymer films were prepared by casting process. Thermal transitions and thermal degradation of samples with respect to copper concentration were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. Increase in glass transition temperature as a function of copper concentration shows a strong branching and steric effects in copper doped PVA complexes. Thermal degradation of films to an extent of 4–5% was found with an increase in copper content. FTIR spectrum of PVA doped Cu2+ ions indicate the presence of O-H, C-H, C=C and C-O groups.</description><subject>ALCOHOLS</subject><subject>CALORIMETRY</subject><subject>Copper</subject><subject>Differential scanning calorimetry</subject><subject>DOPING</subject><subject>Glass transition temperature</subject><subject>Infrared radiation</subject><subject>INFRARED RAYS</subject><subject>Polymer films</subject><subject>Polymeric films</subject><subject>POLYMERS</subject><subject>Polyvinyl alcohol</subject><subject>Polyvinyl alcohols</subject><subject>Steric effects</subject><subject>Thermal degradation</subject><subject>THERMOGRAVIMETRIC ANALYSIS</subject><subject>TRANSITION TEMPERATURE</subject><issn>0250-4707</issn><issn>0973-7669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdkE1LAzEQhoMoWKs_wNvixdNqZvO1OYr4USgIUs8hzU7olnSzJl2h_96UevIwzHt4eJl5CLkF-gCUqscMDWW8LrEMa2s4IzOqFauVlPq85EbQmiuqLslVzltKQXMOM9KuNph2NlR26KrFZ5X3U9djruJQuTiOmKoujthVYwyHn344FDC4uInhmlx4GzLe_O05-Xp9WT2_18uPt8Xz07J2jKt9vRYNkx1qjw3TmupGq3XrrVfCt84Kj1bINQglAR2itJ31TAigmrdgERo2J_en3jHF7wnz3uz67DAEO2CcstHApdBMtYW8-0du45SGcpxplZaclYcLBCfIpZhzQm_G1O9sOhig5mjSnEyaYzyaNMB-AVOxZT8</recordid><startdate>20070601</startdate><enddate>20070601</enddate><creator>Raju, Ch. Linga</creator><creator>Rao, J. L.</creator><creator>Reddy, B. C. V.</creator><creator>Veera Brahmam, K.</creator><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>H8G</scope></search><sort><creationdate>20070601</creationdate><title>Thermal and IR studies on copper doped polyvinyl alcohol</title><author>Raju, Ch. Linga ; Rao, J. L. ; Reddy, B. C. V. ; Veera Brahmam, K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c347t-b5236de9fe239909297b8faf75f8ca5fea56b15761ecee6adaf355109481ae123</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>ALCOHOLS</topic><topic>CALORIMETRY</topic><topic>Copper</topic><topic>Differential scanning calorimetry</topic><topic>DOPING</topic><topic>Glass transition temperature</topic><topic>Infrared radiation</topic><topic>INFRARED RAYS</topic><topic>Polymer films</topic><topic>Polymeric films</topic><topic>POLYMERS</topic><topic>Polyvinyl alcohol</topic><topic>Polyvinyl alcohols</topic><topic>Steric effects</topic><topic>Thermal degradation</topic><topic>THERMOGRAVIMETRIC ANALYSIS</topic><topic>TRANSITION TEMPERATURE</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Raju, Ch. Linga</creatorcontrib><creatorcontrib>Rao, J. L.</creatorcontrib><creatorcontrib>Reddy, B. C. V.</creatorcontrib><creatorcontrib>Veera Brahmam, K.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Copper Technical Reference Library</collection><jtitle>Bulletin of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Raju, Ch. Linga</au><au>Rao, J. L.</au><au>Reddy, B. C. V.</au><au>Veera Brahmam, K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal and IR studies on copper doped polyvinyl alcohol</atitle><jtitle>Bulletin of materials science</jtitle><date>2007-06-01</date><risdate>2007</risdate><volume>30</volume><issue>3</issue><spage>215</spage><epage>218</epage><pages>215-218</pages><issn>0250-4707</issn><eissn>0973-7669</eissn><abstract>5 mol% PVA: x mol% Cu2+ polymer films were prepared by casting process. Thermal transitions and thermal degradation of samples with respect to copper concentration were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. Increase in glass transition temperature as a function of copper concentration shows a strong branching and steric effects in copper doped PVA complexes. Thermal degradation of films to an extent of 4–5% was found with an increase in copper content. FTIR spectrum of PVA doped Cu2+ ions indicate the presence of O-H, C-H, C=C and C-O groups.</abstract><cop>Bangalore</cop><pub>Springer Nature B.V</pub><doi>10.1007/s12034-007-0038-1</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0250-4707
ispartof Bulletin of materials science, 2007-06, Vol.30 (3), p.215-218
issn 0250-4707
0973-7669
language eng
recordid cdi_proquest_miscellaneous_914659378
source Indian Academy of Sciences; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry; SpringerLink Journals - AutoHoldings; ProQuest Central
subjects ALCOHOLS
CALORIMETRY
Copper
Differential scanning calorimetry
DOPING
Glass transition temperature
Infrared radiation
INFRARED RAYS
Polymer films
Polymeric films
POLYMERS
Polyvinyl alcohol
Polyvinyl alcohols
Steric effects
Thermal degradation
THERMOGRAVIMETRIC ANALYSIS
TRANSITION TEMPERATURE
title Thermal and IR studies on copper doped polyvinyl alcohol
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-09T03%3A37%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Thermal%20and%20IR%20studies%20on%20copper%20doped%20polyvinyl%20alcohol&rft.jtitle=Bulletin%20of%20materials%20science&rft.au=Raju,%20Ch.%20Linga&rft.date=2007-06-01&rft.volume=30&rft.issue=3&rft.spage=215&rft.epage=218&rft.pages=215-218&rft.issn=0250-4707&rft.eissn=0973-7669&rft_id=info:doi/10.1007/s12034-007-0038-1&rft_dat=%3Cproquest_cross%3E914659378%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=879643441&rft_id=info:pmid/&rfr_iscdi=true