Thermal and IR studies on copper doped polyvinyl alcohol
5 mol% PVA: x mol% Cu2+ polymer films were prepared by casting process. Thermal transitions and thermal degradation of samples with respect to copper concentration were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. Increase in glass transition...
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Veröffentlicht in: | Bulletin of materials science 2007-06, Vol.30 (3), p.215-218 |
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description | 5 mol% PVA: x mol% Cu2+ polymer films were prepared by casting process. Thermal transitions and thermal degradation of samples with respect to copper concentration were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. Increase in glass transition temperature as a function of copper concentration shows a strong branching and steric effects in copper doped PVA complexes. Thermal degradation of films to an extent of 4–5% was found with an increase in copper content. FTIR spectrum of PVA doped Cu2+ ions indicate the presence of O-H, C-H, C=C and C-O groups. |
doi_str_mv | 10.1007/s12034-007-0038-1 |
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FTIR spectrum of PVA doped Cu2+ ions indicate the presence of O-H, C-H, C=C and C-O groups.</description><identifier>ISSN: 0250-4707</identifier><identifier>EISSN: 0973-7669</identifier><identifier>DOI: 10.1007/s12034-007-0038-1</identifier><language>eng</language><publisher>Bangalore: Springer Nature B.V</publisher><subject>ALCOHOLS ; CALORIMETRY ; Copper ; Differential scanning calorimetry ; DOPING ; Glass transition temperature ; Infrared radiation ; INFRARED RAYS ; Polymer films ; Polymeric films ; POLYMERS ; Polyvinyl alcohol ; Polyvinyl alcohols ; Steric effects ; Thermal degradation ; THERMOGRAVIMETRIC ANALYSIS ; TRANSITION TEMPERATURE</subject><ispartof>Bulletin of materials science, 2007-06, Vol.30 (3), p.215-218</ispartof><rights>Indian Academy of Sciences 2007.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c347t-b5236de9fe239909297b8faf75f8ca5fea56b15761ecee6adaf355109481ae123</citedby><cites>FETCH-LOGICAL-c347t-b5236de9fe239909297b8faf75f8ca5fea56b15761ecee6adaf355109481ae123</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/879643441/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/879643441?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21367,27901,27902,33721,33722,43781,74045</link.rule.ids></links><search><creatorcontrib>Raju, Ch. 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FTIR spectrum of PVA doped Cu2+ ions indicate the presence of O-H, C-H, C=C and C-O groups.</description><subject>ALCOHOLS</subject><subject>CALORIMETRY</subject><subject>Copper</subject><subject>Differential scanning calorimetry</subject><subject>DOPING</subject><subject>Glass transition temperature</subject><subject>Infrared radiation</subject><subject>INFRARED RAYS</subject><subject>Polymer films</subject><subject>Polymeric films</subject><subject>POLYMERS</subject><subject>Polyvinyl alcohol</subject><subject>Polyvinyl alcohols</subject><subject>Steric effects</subject><subject>Thermal degradation</subject><subject>THERMOGRAVIMETRIC ANALYSIS</subject><subject>TRANSITION TEMPERATURE</subject><issn>0250-4707</issn><issn>0973-7669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdkE1LAzEQhoMoWKs_wNvixdNqZvO1OYr4USgIUs8hzU7olnSzJl2h_96UevIwzHt4eJl5CLkF-gCUqscMDWW8LrEMa2s4IzOqFauVlPq85EbQmiuqLslVzltKQXMOM9KuNph2NlR26KrFZ5X3U9djruJQuTiOmKoujthVYwyHn344FDC4uInhmlx4GzLe_O05-Xp9WT2_18uPt8Xz07J2jKt9vRYNkx1qjw3TmupGq3XrrVfCt84Kj1bINQglAR2itJ31TAigmrdgERo2J_en3jHF7wnz3uz67DAEO2CcstHApdBMtYW8-0du45SGcpxplZaclYcLBCfIpZhzQm_G1O9sOhig5mjSnEyaYzyaNMB-AVOxZT8</recordid><startdate>20070601</startdate><enddate>20070601</enddate><creator>Raju, Ch. 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source | Indian Academy of Sciences; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry; SpringerLink Journals - AutoHoldings; ProQuest Central |
subjects | ALCOHOLS CALORIMETRY Copper Differential scanning calorimetry DOPING Glass transition temperature Infrared radiation INFRARED RAYS Polymer films Polymeric films POLYMERS Polyvinyl alcohol Polyvinyl alcohols Steric effects Thermal degradation THERMOGRAVIMETRIC ANALYSIS TRANSITION TEMPERATURE |
title | Thermal and IR studies on copper doped polyvinyl alcohol |
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