Stereodivergency in Catalytic Asymmetric Conjugate Addition Reactions of Glycine (Ket)imines

Stereodivergent catalytic asymmetric conjugate reactions of glycine (ket)­imines with nitroalkenes have been achieved using various chiral catalyst systems derived from a multidentate amino alcohol (1). The stepwise nature of the [3 + 2] cycloaddition reactions of N-metalated azomethine ylides has a...

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Veröffentlicht in:	Journal of the American Chemical Society 2011-12, Vol.133 (51), p.20750-20753
Hauptverfasser:	Kim, Hun Young, Li, Jian-Yuan, Kim, Sungkyung, Oh, Kyungsoo
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Amino Alcohols - chemistry Catalysis Glycine - chemistry Imines - chemistry Stereoisomerism
Online-Zugang:	Volltext
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