Efficient Photocatalytic Hydrogen Production in a Single-Component System Using Ru,Rh,Ru Supramolecules Containing 4,7-Diphenyl-1,10-Phenanthroline

Small changes go a long way: Modification of the terminal ligand to incorporate 4,7‐diphenyl‐1,10‐phenanthroline has generated superior Ru,Rh,Ru photocatalysts (see scheme; ochre Ru, red Rh, blue N, yellow Cl or Br) displaying significantly enhanced photocatalytic H2 production from H2O with long‐te...

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Veröffentlicht in:	Angewandte Chemie International Edition 2011-12, Vol.50 (51), p.12209-12213
Hauptverfasser:	White, Travis A., Higgins, Samantha L. H., Arachchige, Shamindri M., Brewer, Karen J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Hydrogen production Ligands Photocatalysis Photocatalysts rhodium ruthenium supramolecular complexes Terminals water splitting
Online-Zugang:	Volltext
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