Vapor-phase concentrations of arsenic, selenium, bromine, iodine, and mercury in the stack of a coal-fired power plant
A sampling and analysis procedure is described for determining vapor-phase concentrations of As, Se, Br, I, and Hg in the stack of a coal-fired power plant. The percentages of the total in-stack concentrations for these elements present in the vapor phase are as follows: Br, 98%; Hg, 98%; Se, 59%; A...
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Veröffentlicht in: | Environ. Sci. Technol.; (United States) 1988-09, Vol.22 (9), p.1079-1085 |
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creator | Germani, Mark S Zoller, William H |
description | A sampling and analysis procedure is described for determining vapor-phase concentrations of As, Se, Br, I, and Hg in the stack of a coal-fired power plant. The percentages of the total in-stack concentrations for these elements present in the vapor phase are as follows: Br, 98%; Hg, 98%; Se, 59%; As 0.7-52%; and I, greater than or equal to 99%. A lower limit of 99% was obtained for Cl. The vapor-phase concentration of As appears to be dependent upon the in-stack or filter mass loading. This indicates that a vaporization-condensation mechanism may control the vapor-phase concentration of As. |
doi_str_mv | 10.1021/es00174a013 |
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The percentages of the total in-stack concentrations for these elements present in the vapor phase are as follows: Br, 98%; Hg, 98%; Se, 59%; As 0.7-52%; and I, greater than or equal to 99%. A lower limit of 99% was obtained for Cl. The vapor-phase concentration of As appears to be dependent upon the in-stack or filter mass loading. This indicates that a vaporization-condensation mechanism may control the vapor-phase concentration of As.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es00174a013</identifier><identifier>PMID: 22148663</identifier><identifier>CODEN: ESTHAG</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>01 COAL, LIGNITE, AND PEAT ; 010800 - Coal, Lignite, & Peat- Waste Management ; 500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989) ; Applied sciences ; ARSENIC ; Atmospheric pollution ; BROMINE ; CARBONACEOUS MATERIALS ; CHEMICAL COMPOSITION ; COAL ; Combustion and energy production ; COMBUSTION PRODUCTS ; ECOLOGICAL CONCENTRATION ; ELEMENTS ; ENERGY SOURCES ; ENVIRONMENTAL SCIENCES ; Exact sciences and technology ; FLUIDS ; FOSSIL FUELS ; FOSSIL-FUEL POWER PLANTS ; FRACTIONATION ; FUELS ; GASES ; HALOGENS ; IODINE ; MANAGEMENT ; MATERIALS ; MERCURY ; METALS ; NONMETALS ; Pollution ; Pollution sources. Measurement results ; POWER PLANTS ; SAMPLING ; SELENIUM ; SEMIMETALS ; SEPARATION PROCESSES ; STACK DISPOSAL ; THERMAL POWER PLANTS ; VAPORS ; WASTE DISPOSAL ; WASTE MANAGEMENT</subject><ispartof>Environ. Sci. 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Sci. Technol.; (United States)</title><addtitle>Environ. Sci. Technol</addtitle><description>A sampling and analysis procedure is described for determining vapor-phase concentrations of As, Se, Br, I, and Hg in the stack of a coal-fired power plant. The percentages of the total in-stack concentrations for these elements present in the vapor phase are as follows: Br, 98%; Hg, 98%; Se, 59%; As 0.7-52%; and I, greater than or equal to 99%. A lower limit of 99% was obtained for Cl. The vapor-phase concentration of As appears to be dependent upon the in-stack or filter mass loading. This indicates that a vaporization-condensation mechanism may control the vapor-phase concentration of As.</description><subject>01 COAL, LIGNITE, AND PEAT</subject><subject>010800 - Coal, Lignite, & Peat- Waste Management</subject><subject>500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989)</subject><subject>Applied sciences</subject><subject>ARSENIC</subject><subject>Atmospheric pollution</subject><subject>BROMINE</subject><subject>CARBONACEOUS MATERIALS</subject><subject>CHEMICAL COMPOSITION</subject><subject>COAL</subject><subject>Combustion and energy production</subject><subject>COMBUSTION PRODUCTS</subject><subject>ECOLOGICAL CONCENTRATION</subject><subject>ELEMENTS</subject><subject>ENERGY SOURCES</subject><subject>ENVIRONMENTAL SCIENCES</subject><subject>Exact sciences and technology</subject><subject>FLUIDS</subject><subject>FOSSIL FUELS</subject><subject>FOSSIL-FUEL POWER PLANTS</subject><subject>FRACTIONATION</subject><subject>FUELS</subject><subject>GASES</subject><subject>HALOGENS</subject><subject>IODINE</subject><subject>MANAGEMENT</subject><subject>MATERIALS</subject><subject>MERCURY</subject><subject>METALS</subject><subject>NONMETALS</subject><subject>Pollution</subject><subject>Pollution sources. Measurement results</subject><subject>POWER PLANTS</subject><subject>SAMPLING</subject><subject>SELENIUM</subject><subject>SEMIMETALS</subject><subject>SEPARATION PROCESSES</subject><subject>STACK DISPOSAL</subject><subject>THERMAL POWER PLANTS</subject><subject>VAPORS</subject><subject>WASTE DISPOSAL</subject><subject>WASTE MANAGEMENT</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1988</creationdate><recordtype>article</recordtype><recordid>eNqF0c9vFCEUB_CJ0dhaPXk3xBg9uKPAMDAcTf1RkyY2cW28EWDeZGlnYAqM2v9e2l1XD0ZPj8CHlwffqnpM8CuCKXkNCWMimMakuVMdkpbiuu1acrc6LPtNLRv-9aB6kNIFxpg2uLtfHVBKWMd5c1h9O9dziPW80QmQDd6Cz1FnF3xCYUA6JvDOrlCCsSyWaYVMDJPzsEIu9LdV-x5NEO0Sr5HzKG8Apazt5e390lOP9eAi9GgO3yGiedQ-P6zuDXpM8GhXj6ov79-tj0_q008fPh6_Oa01EyzXxAxE61bzvqNEirYBEKbvBm463Jm-Z4yb3hBqiDUMQEowUkqNOcfWgubNUfV02zek7FSyLoPdlGd6sFlxykgrREEvtmiO4WqBlNXkkoWxDAphSUoSIhlrOSny-T8laW-i4N3_IaOUdrwp8OUW2hhSijCoObpJx2tFsLqJV_0Rb9FPdm0XM0G_t7_yLODZDuhk9ThE7a1LeyeoIEzIwuotcynDj_2xjpeKi0a0an32Wa1ld75-i8_Uye8f0japi7BEX0L764Q_AZnlyEI</recordid><startdate>19880901</startdate><enddate>19880901</enddate><creator>Germani, Mark S</creator><creator>Zoller, William H</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7TV</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>19880901</creationdate><title>Vapor-phase concentrations of arsenic, selenium, bromine, iodine, and mercury in the stack of a coal-fired power plant</title><author>Germani, Mark S ; Zoller, William H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a474t-1bf1aa5a6d8219753ee7bd8f6b808bdd446bdb12b1cb4ee99eb999a0660ccea63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1988</creationdate><topic>01 COAL, LIGNITE, AND PEAT</topic><topic>010800 - Coal, Lignite, & Peat- Waste Management</topic><topic>500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989)</topic><topic>Applied sciences</topic><topic>ARSENIC</topic><topic>Atmospheric pollution</topic><topic>BROMINE</topic><topic>CARBONACEOUS MATERIALS</topic><topic>CHEMICAL COMPOSITION</topic><topic>COAL</topic><topic>Combustion and energy production</topic><topic>COMBUSTION PRODUCTS</topic><topic>ECOLOGICAL CONCENTRATION</topic><topic>ELEMENTS</topic><topic>ENERGY SOURCES</topic><topic>ENVIRONMENTAL SCIENCES</topic><topic>Exact sciences and technology</topic><topic>FLUIDS</topic><topic>FOSSIL FUELS</topic><topic>FOSSIL-FUEL POWER PLANTS</topic><topic>FRACTIONATION</topic><topic>FUELS</topic><topic>GASES</topic><topic>HALOGENS</topic><topic>IODINE</topic><topic>MANAGEMENT</topic><topic>MATERIALS</topic><topic>MERCURY</topic><topic>METALS</topic><topic>NONMETALS</topic><topic>Pollution</topic><topic>Pollution sources. Measurement results</topic><topic>POWER PLANTS</topic><topic>SAMPLING</topic><topic>SELENIUM</topic><topic>SEMIMETALS</topic><topic>SEPARATION PROCESSES</topic><topic>STACK DISPOSAL</topic><topic>THERMAL POWER PLANTS</topic><topic>VAPORS</topic><topic>WASTE DISPOSAL</topic><topic>WASTE MANAGEMENT</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Germani, Mark S</creatorcontrib><creatorcontrib>Zoller, William H</creatorcontrib><creatorcontrib>Univ. of Maryland, College Park (USA)</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Pollution Abstracts</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>Environ. Sci. Technol.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Germani, Mark S</au><au>Zoller, William H</au><aucorp>Univ. of Maryland, College Park (USA)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Vapor-phase concentrations of arsenic, selenium, bromine, iodine, and mercury in the stack of a coal-fired power plant</atitle><jtitle>Environ. Sci. Technol.; (United States)</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>1988-09-01</date><risdate>1988</risdate><volume>22</volume><issue>9</issue><spage>1079</spage><epage>1085</epage><pages>1079-1085</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><coden>ESTHAG</coden><abstract>A sampling and analysis procedure is described for determining vapor-phase concentrations of As, Se, Br, I, and Hg in the stack of a coal-fired power plant. The percentages of the total in-stack concentrations for these elements present in the vapor phase are as follows: Br, 98%; Hg, 98%; Se, 59%; As 0.7-52%; and I, greater than or equal to 99%. A lower limit of 99% was obtained for Cl. The vapor-phase concentration of As appears to be dependent upon the in-stack or filter mass loading. This indicates that a vaporization-condensation mechanism may control the vapor-phase concentration of As.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>22148663</pmid><doi>10.1021/es00174a013</doi><tpages>7</tpages></addata></record> |
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subjects | 01 COAL, LIGNITE, AND PEAT 010800 - Coal, Lignite, & Peat- Waste Management 500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989) Applied sciences ARSENIC Atmospheric pollution BROMINE CARBONACEOUS MATERIALS CHEMICAL COMPOSITION COAL Combustion and energy production COMBUSTION PRODUCTS ECOLOGICAL CONCENTRATION ELEMENTS ENERGY SOURCES ENVIRONMENTAL SCIENCES Exact sciences and technology FLUIDS FOSSIL FUELS FOSSIL-FUEL POWER PLANTS FRACTIONATION FUELS GASES HALOGENS IODINE MANAGEMENT MATERIALS MERCURY METALS NONMETALS Pollution Pollution sources. Measurement results POWER PLANTS SAMPLING SELENIUM SEMIMETALS SEPARATION PROCESSES STACK DISPOSAL THERMAL POWER PLANTS VAPORS WASTE DISPOSAL WASTE MANAGEMENT |
title | Vapor-phase concentrations of arsenic, selenium, bromine, iodine, and mercury in the stack of a coal-fired power plant |
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