Crossed beam reaction of phenyl and D5-phenyl radicals with propene and deuterated counterparts—competing atomic hydrogen and methyl loss pathways

We conducted the crossed molecular beams reactions of the phenyl and D5-phenyl radicals with propylene together with its partially deuterated reactants at collision energies of ~45 kJ mol(-1) under single collision conditions. The scattering dynamics were found to be indirect and were mainly dictate...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2012-01, Vol.14 (2), p.720-729
Hauptverfasser:	KAISER, R. I, PARKER, D. S. N, GOSWAMI, M, ZHANG, F, KISLOV, V. V, MEBEL, A. M, AGUILERA-IPARRAGUIRRE, J, GREEN, W. H
Format:	Artikel
Sprache:	eng
Schlagworte:	Channels Chemistry Collision dynamics Combustion Deuteration Exact sciences and technology Forming General and physical chemistry Phenyls Radicals Styrenes
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