Fabrication of n-Type Mesoporous Silicon Nanowires by One-Step Etching
In general, n-type mesoporous silicon nanowires (mp-SiNWs) are exclusively created by the two-step metal-assisted chemical etching (MACE). This work first reports that one-step MACE (in HF and AgNO3) is also capable of producing the n-type mp-SiNWs, and the developed formula is generally adapted to...
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Veröffentlicht in: | Nano letters 2011-12, Vol.11 (12), p.5252-5258 |
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creator | To, Wai-Keung Tsang, Chi-Him Li, Hau-Hau Huang, Zhifeng |
description | In general, n-type mesoporous silicon nanowires (mp-SiNWs) are exclusively created by the two-step metal-assisted chemical etching (MACE). This work first reports that one-step MACE (in HF and AgNO3) is also capable of producing the n-type mp-SiNWs, and the developed formula is generally adapted to generate SiNWs by etching n-Si(100) with electrical resistivity over a range of 10–3–101 Ω·cm. Integrating the contribution of silicon intrinsic properties in the existing MACE mechanism explicitly accounts for the new findings and contradictions with previous studies. The as-generated mesoporous structures emit red light under laser excitation at room temperature. The red-color emission sensitively varies with temperature over a range of 16–300 K, attributed to a temperature-dependent photoluminescent mechanism. |
doi_str_mv | 10.1021/nl202674t |
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The red-color emission sensitively varies with temperature over a range of 16–300 K, attributed to a temperature-dependent photoluminescent mechanism.</description><subject>Chemical etching</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Electrical resistivity</subject><subject>Emittance</subject><subject>Etching</subject><subject>Exact sciences and technology</subject><subject>Lasers</subject><subject>Materials science</subject><subject>Nanocrystalline materials</subject><subject>Nanoscale materials and structures: fabrication and characterization</subject><subject>Nanostructure</subject><subject>Nanowires</subject><subject>Photoluminescence</subject><subject>Physics</subject><subject>Quantum wires</subject><subject>Silicon</subject><issn>1530-6984</issn><issn>1530-6992</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp90EtLw0AQB_BFFN8Hv4DkIuohOvtI0j1KsSqoPajnsI-JrqS7cTdF-u2NtNaLeJqB-TEz_Ak5onBBgdFL3zJgZSX6DbJLCw55KSXbXPcjsUP2UnoHAMkL2CY7jAFUEtgumUyUjs6o3gWfhSbz-fOiw-wBU-hCDPOUPbnWmWH4qHz4dBFTphfZ1GP-1GOXXffmzfnXA7LVqDbh4aruk5fJ9fP4Nr-f3tyNr-5zJQTvczbiVlFqta0QKEDBrDDSVg0wwNIwFLbQujCouMaixArKka6EZVxqWnHL98npcm8Xw8ccU1_PXDLYtsrj8GwtKZV8JAAGefavpFXJoKBSlgM9X1ITQ0oRm7qLbqbioqZQfwdcrwMe7PFq7VzP0K7lT6IDOFkBlYxqm6i8cenXFZwKJuSvUybV72Ee_ZDbHwe_ALTAjUo</recordid><startdate>20111214</startdate><enddate>20111214</enddate><creator>To, Wai-Keung</creator><creator>Tsang, Chi-Him</creator><creator>Li, Hau-Hau</creator><creator>Huang, Zhifeng</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20111214</creationdate><title>Fabrication of n-Type Mesoporous Silicon Nanowires by One-Step Etching</title><author>To, Wai-Keung ; Tsang, Chi-Him ; Li, Hau-Hau ; Huang, Zhifeng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a443t-283da11dbd7e010052d4c9d7f020e6c2e4d5bb5cea3be56e7068b74d239b173d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemical etching</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Electrical resistivity</topic><topic>Emittance</topic><topic>Etching</topic><topic>Exact sciences and technology</topic><topic>Lasers</topic><topic>Materials science</topic><topic>Nanocrystalline materials</topic><topic>Nanoscale materials and structures: fabrication and characterization</topic><topic>Nanostructure</topic><topic>Nanowires</topic><topic>Photoluminescence</topic><topic>Physics</topic><topic>Quantum wires</topic><topic>Silicon</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>To, Wai-Keung</creatorcontrib><creatorcontrib>Tsang, Chi-Him</creatorcontrib><creatorcontrib>Li, Hau-Hau</creatorcontrib><creatorcontrib>Huang, Zhifeng</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Nano letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>To, Wai-Keung</au><au>Tsang, Chi-Him</au><au>Li, Hau-Hau</au><au>Huang, Zhifeng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of n-Type Mesoporous Silicon Nanowires by One-Step Etching</atitle><jtitle>Nano letters</jtitle><addtitle>Nano Lett</addtitle><date>2011-12-14</date><risdate>2011</risdate><volume>11</volume><issue>12</issue><spage>5252</spage><epage>5258</epage><pages>5252-5258</pages><issn>1530-6984</issn><eissn>1530-6992</eissn><abstract>In general, n-type mesoporous silicon nanowires (mp-SiNWs) are exclusively created by the two-step metal-assisted chemical etching (MACE). 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subjects | Chemical etching Cross-disciplinary physics: materials science rheology Electrical resistivity Emittance Etching Exact sciences and technology Lasers Materials science Nanocrystalline materials Nanoscale materials and structures: fabrication and characterization Nanostructure Nanowires Photoluminescence Physics Quantum wires Silicon |
title | Fabrication of n-Type Mesoporous Silicon Nanowires by One-Step Etching |
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