Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies

Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies

Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high D(Am) and D(Pu) values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Tran...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2012-01, Vol.41 (2), p.360-363
Hauptverfasser: Mohapatra, Prasanta K, Iqbal, Mudassir, Raut, Dhaval R, Verboom, Willem, Huskens, Jurriaan, Godbole, Shrikant V
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Mohapatra, Prasanta K
Iqbal, Mudassir
Raut, Dhaval R
Verboom, Willem
Huskens, Jurriaan
Godbole, Shrikant V
description Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high D(Am) and D(Pu) values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Transport and laser induced fluorescence studies indicated strong complexation of the trivalent metal ions with the calix[4]-4DGA ligand.
doi_str_mv 10.1039/c1dt11561h
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title Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies
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