Determination of Oxygen Content in Magnesium and Its Alloys by Inert Gas Fusion-Infrared Absorptiometry

A method for the determination of the oxygen content in magnesium and magnesium alloys has been developed. Inert gas fusion-infrared absorptiometry was modified by introducing a multistep heating process; a sample containing oxygen is fused with tin to form an eutectic mixture at 900°C in a graphite...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Analytical Sciences 2011/07/10, Vol.27(7), pp.721-721
Hauptverfasser:	TSUGE, Akira, ACHIWA, Hatsumi, MORIKAWA, Hisashi, UEMOTO, Michihisa, KANEMATSU, Wataru
Format:	Artikel
Sprache:	eng
Schlagworte:	Alloys Analytical Chemistry Chemistry Evaporation Magnesium Oxygen Tin
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	721
container_issue	7
container_start_page	721
container_title	Analytical Sciences
container_volume	27
creator	TSUGE, Akira ACHIWA, Hatsumi MORIKAWA, Hisashi UEMOTO, Michihisa KANEMATSU, Wataru
description	A method for the determination of the oxygen content in magnesium and magnesium alloys has been developed. Inert gas fusion-infrared absorptiometry was modified by introducing a multistep heating process; a sample containing oxygen is fused with tin to form an eutectic mixture at 900°C in a graphite crucible, followed by a subsequent gradual temperature increase of up to 2000°C, which enables the evaporation of magnesium from the mixture, and subsequent solidification at the rim of the crucible. Residual tin including magnesium oxide remained at the bottom of the crucible. The oxygen in the tin is measured by a conventional inert gas fusion (IGF) method. From a comparison with the results of charged particle activation analysis, the IGF method is considered to be an attractive candidate for measuring the oxygen content in Mg and its alloys.
doi_str_mv	10.2116/analsci.27.721
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_910671082</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3118237181</sourcerecordid><originalsourceid>FETCH-LOGICAL-c647t-3058e5e79cdfaa9aec6551fdadcd8cd858c75f86ee02bf3b05ac258c6ba89d513</originalsourceid><addsrcrecordid>eNqFkc1r3DAQxUVpaLZprz0WQQ89eSPJ1scel22TLiTkkp6FLI9dL7a0lWSI__sqeLu0hRIQEmh-82Z4D6EPlKwZpeLaODNE26-ZXEtGX6EVLStVMFaJ12hFNpQUoqzIJXob44EQyhRjb9Alo7KSVJEV6r5AgjD2zqTeO-xb_PA0d-DwzrsELuHe4XvTOYj9NGLjGrxPEW-Hwc8R1zPeOwgJ35qIb6aYFYq9a4MJ0OBtHX04ZtURUpjfoYs2bwrvT-8V-n7z9XH3rbh7uN3vtneFFZVMRUm4Ag5yY5vWmI0BKzinbWMa26h8uLKSt0oAEFa3ZU24sSx_itqoTcNpeYU-L7rH4H9OEJMe-2hhGIwDP0WdHRGSEsVeJJUU2UXBRCY__UMe_BSejde0qvJOquRlptYLZYOPMUCrj6EfTZg1Jfo5K33KSjOpc1a54eNJdqpHaM7473AycL0AMZdcB-GPuf-T3C0dh5hMB2dJE1JvB_gLX67cda7aHyZocOUvlhK6lQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1448588353</pqid></control><display><type>article</type><title>Determination of Oxygen Content in Magnesium and Its Alloys by Inert Gas Fusion-Infrared Absorptiometry</title><source>J-STAGE Free</source><source>Springer Nature - Complete Springer Journals</source><source>Freely Accessible Japanese Titles</source><source>EZB-FREE-00999 freely available EZB journals</source><source>Free Full-Text Journals in Chemistry</source><creator>TSUGE, Akira ; ACHIWA, Hatsumi ; MORIKAWA, Hisashi ; UEMOTO, Michihisa ; KANEMATSU, Wataru</creator><creatorcontrib>TSUGE, Akira ; ACHIWA, Hatsumi ; MORIKAWA, Hisashi ; UEMOTO, Michihisa ; KANEMATSU, Wataru</creatorcontrib><description>A method for the determination of the oxygen content in magnesium and magnesium alloys has been developed. Inert gas fusion-infrared absorptiometry was modified by introducing a multistep heating process; a sample containing oxygen is fused with tin to form an eutectic mixture at 900°C in a graphite crucible, followed by a subsequent gradual temperature increase of up to 2000°C, which enables the evaporation of magnesium from the mixture, and subsequent solidification at the rim of the crucible. Residual tin including magnesium oxide remained at the bottom of the crucible. The oxygen in the tin is measured by a conventional inert gas fusion (IGF) method. From a comparison with the results of charged particle activation analysis, the IGF method is considered to be an attractive candidate for measuring the oxygen content in Mg and its alloys.</description><identifier>ISSN: 0910-6340</identifier><identifier>ISSN: 1348-2246</identifier><identifier>EISSN: 1348-2246</identifier><identifier>DOI: 10.2116/analsci.27.721</identifier><identifier>PMID: 21747180</identifier><language>eng</language><publisher>Singapore: The Japan Society for Analytical Chemistry</publisher><subject>Alloys ; Analytical Chemistry ; Chemistry ; Evaporation ; Magnesium ; Oxygen ; Tin</subject><ispartof>Analytical Sciences, 2011/07/10, Vol.27(7), pp.721-721</ispartof><rights>2011 by The Japan Society for Analytical Chemistry</rights><rights>The Japan Society for Analytical Chemistry 2011</rights><rights>Copyright Japan Science and Technology Agency 2011</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c647t-3058e5e79cdfaa9aec6551fdadcd8cd858c75f86ee02bf3b05ac258c6ba89d513</citedby><cites>FETCH-LOGICAL-c647t-3058e5e79cdfaa9aec6551fdadcd8cd858c75f86ee02bf3b05ac258c6ba89d513</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.2116/analsci.27.721$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.2116/analsci.27.721$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,1879,27911,27912,41475,42544,51306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21747180$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>TSUGE, Akira</creatorcontrib><creatorcontrib>ACHIWA, Hatsumi</creatorcontrib><creatorcontrib>MORIKAWA, Hisashi</creatorcontrib><creatorcontrib>UEMOTO, Michihisa</creatorcontrib><creatorcontrib>KANEMATSU, Wataru</creatorcontrib><title>Determination of Oxygen Content in Magnesium and Its Alloys by Inert Gas Fusion-Infrared Absorptiometry</title><title>Analytical Sciences</title><addtitle>ANAL. SCI</addtitle><addtitle>Anal Sci</addtitle><description>A method for the determination of the oxygen content in magnesium and magnesium alloys has been developed. Inert gas fusion-infrared absorptiometry was modified by introducing a multistep heating process; a sample containing oxygen is fused with tin to form an eutectic mixture at 900°C in a graphite crucible, followed by a subsequent gradual temperature increase of up to 2000°C, which enables the evaporation of magnesium from the mixture, and subsequent solidification at the rim of the crucible. Residual tin including magnesium oxide remained at the bottom of the crucible. The oxygen in the tin is measured by a conventional inert gas fusion (IGF) method. From a comparison with the results of charged particle activation analysis, the IGF method is considered to be an attractive candidate for measuring the oxygen content in Mg and its alloys.</description><subject>Alloys</subject><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Evaporation</subject><subject>Magnesium</subject><subject>Oxygen</subject><subject>Tin</subject><issn>0910-6340</issn><issn>1348-2246</issn><issn>1348-2246</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkc1r3DAQxUVpaLZprz0WQQ89eSPJ1scel22TLiTkkp6FLI9dL7a0lWSI__sqeLu0hRIQEmh-82Z4D6EPlKwZpeLaODNE26-ZXEtGX6EVLStVMFaJ12hFNpQUoqzIJXob44EQyhRjb9Alo7KSVJEV6r5AgjD2zqTeO-xb_PA0d-DwzrsELuHe4XvTOYj9NGLjGrxPEW-Hwc8R1zPeOwgJ35qIb6aYFYq9a4MJ0OBtHX04ZtURUpjfoYs2bwrvT-8V-n7z9XH3rbh7uN3vtneFFZVMRUm4Ag5yY5vWmI0BKzinbWMa26h8uLKSt0oAEFa3ZU24sSx_itqoTcNpeYU-L7rH4H9OEJMe-2hhGIwDP0WdHRGSEsVeJJUU2UXBRCY__UMe_BSejde0qvJOquRlptYLZYOPMUCrj6EfTZg1Jfo5K33KSjOpc1a54eNJdqpHaM7473AycL0AMZdcB-GPuf-T3C0dh5hMB2dJE1JvB_gLX67cda7aHyZocOUvlhK6lQ</recordid><startdate>2011</startdate><enddate>2011</enddate><creator>TSUGE, Akira</creator><creator>ACHIWA, Hatsumi</creator><creator>MORIKAWA, Hisashi</creator><creator>UEMOTO, Michihisa</creator><creator>KANEMATSU, Wataru</creator><general>The Japan Society for Analytical Chemistry</general><general>Springer Nature Singapore</general><general>Japan Science and Technology Agency</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope><scope>7X8</scope><scope>F1W</scope><scope>H96</scope><scope>L.G</scope></search><sort><creationdate>2011</creationdate><title>Determination of Oxygen Content in Magnesium and Its Alloys by Inert Gas Fusion-Infrared Absorptiometry</title><author>TSUGE, Akira ; ACHIWA, Hatsumi ; MORIKAWA, Hisashi ; UEMOTO, Michihisa ; KANEMATSU, Wataru</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c647t-3058e5e79cdfaa9aec6551fdadcd8cd858c75f86ee02bf3b05ac258c6ba89d513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Alloys</topic><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Evaporation</topic><topic>Magnesium</topic><topic>Oxygen</topic><topic>Tin</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>TSUGE, Akira</creatorcontrib><creatorcontrib>ACHIWA, Hatsumi</creatorcontrib><creatorcontrib>MORIKAWA, Hisashi</creatorcontrib><creatorcontrib>UEMOTO, Michihisa</creatorcontrib><creatorcontrib>KANEMATSU, Wataru</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Analytical Sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>TSUGE, Akira</au><au>ACHIWA, Hatsumi</au><au>MORIKAWA, Hisashi</au><au>UEMOTO, Michihisa</au><au>KANEMATSU, Wataru</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of Oxygen Content in Magnesium and Its Alloys by Inert Gas Fusion-Infrared Absorptiometry</atitle><jtitle>Analytical Sciences</jtitle><stitle>ANAL. SCI</stitle><addtitle>Anal Sci</addtitle><date>2011</date><risdate>2011</risdate><volume>27</volume><issue>7</issue><spage>721</spage><epage>721</epage><pages>721-721</pages><issn>0910-6340</issn><issn>1348-2246</issn><eissn>1348-2246</eissn><abstract>A method for the determination of the oxygen content in magnesium and magnesium alloys has been developed. Inert gas fusion-infrared absorptiometry was modified by introducing a multistep heating process; a sample containing oxygen is fused with tin to form an eutectic mixture at 900°C in a graphite crucible, followed by a subsequent gradual temperature increase of up to 2000°C, which enables the evaporation of magnesium from the mixture, and subsequent solidification at the rim of the crucible. Residual tin including magnesium oxide remained at the bottom of the crucible. The oxygen in the tin is measured by a conventional inert gas fusion (IGF) method. From a comparison with the results of charged particle activation analysis, the IGF method is considered to be an attractive candidate for measuring the oxygen content in Mg and its alloys.</abstract><cop>Singapore</cop><pub>The Japan Society for Analytical Chemistry</pub><pmid>21747180</pmid><doi>10.2116/analsci.27.721</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record>
fulltext	fulltext
identifier	ISSN: 0910-6340
ispartof	Analytical Sciences, 2011/07/10, Vol.27(7), pp.721-721
issn	0910-6340 1348-2246 1348-2246
language	eng
recordid	cdi_proquest_miscellaneous_910671082
source	J-STAGE Free; Springer Nature - Complete Springer Journals; Freely Accessible Japanese Titles; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry
subjects	Alloys Analytical Chemistry Chemistry Evaporation Magnesium Oxygen Tin
title	Determination of Oxygen Content in Magnesium and Its Alloys by Inert Gas Fusion-Infrared Absorptiometry
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T22%3A22%3A42IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Determination%20of%20Oxygen%20Content%20in%20Magnesium%20and%20Its%20Alloys%20by%20Inert%20Gas%20Fusion-Infrared%20Absorptiometry&rft.jtitle=Analytical%20Sciences&rft.au=TSUGE,%20Akira&rft.date=2011&rft.volume=27&rft.issue=7&rft.spage=721&rft.epage=721&rft.pages=721-721&rft.issn=0910-6340&rft.eissn=1348-2246&rft_id=info:doi/10.2116/analsci.27.721&rft_dat=%3Cproquest_cross%3E3118237181%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1448588353&rft_id=info:pmid/21747180&rfr_iscdi=true