Thermal Decomposition of Methyl 2-Azidopropionate Studied by UV Photoelectron Spectroscopy and Matrix Isolation IR Spectroscopy: Heterocyclic Intermediate vs Imine Formation

Methyl 2-azidopropionate (N3CH3CHCOOCH3, M2AP) has been synthesized and characterized by different spectroscopic methods, and the thermal decomposition of this molecule has been investigated by matrix isolation infrared (IR) spectroscopy and ultraviolet photoelectron spectroscopy (UVPES). Computatio...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2011-08, Vol.115 (30), p.8447-8457
Hauptverfasser:	Pinto, R. M, Dias, A. A, Costa, M. L, Rodrigues, P, Barros, M. T, Ogden, J. S, Dyke, J. M
Format:	Artikel
Sprache:	eng
Schlagworte:	A: Kinetics, Spectroscopy Azides - chemical synthesis Azides - chemistry Cobalt Decomposition Heterocyclic Compounds - chemistry Imines Imines - chemical synthesis Imines - chemistry Infrared spectroscopy Models, Molecular Photoelectron Spectroscopy Propionates - chemical synthesis Propionates - chemistry Quantum Theory Spectra Spectrophotometry, Infrared Spectroscopy Thermal decomposition Thermodynamics Ultraviolet Rays
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