A Programmed Polymer Folding: Click and Clip Construction of Doubly Fused Tricyclic and Triply Fused Tetracyclic Polymer Topologies

A tandem alkyne–azide addition, i.e., click, and an olefin metathesis condensation, i.e., clip, reactions in conjunction with an electrostatic self-assembly and covalent fixation (ESA-CF) process, have been demonstrated as effective means to produce constructions of programmed folding of polymers ha...

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Veröffentlicht in:	Journal of the American Chemical Society 2011-12, Vol.133 (49), p.19694-19697
Hauptverfasser:	Sugai, Naoto, Heguri, Hiroyuki, Yamamoto, Takuya, Tezuka, Yasuyuki
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Alkynes - chemistry Azides - chemistry Cyclization Magnetic Resonance Spectroscopy Molecular Conformation Polymers - chemistry Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization Static Electricity
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