Theoretical Evaluation of Structural Models of the S2 State in the Oxygen Evolving Complex of Photosystem II: Protonation States and Magnetic Interactions

Protonation states of water ligands and oxo bridges are intimately involved in tuning the electronic structures and oxidation potentials of the oxygen evolving complex (OEC) in Photosystem II, steering the mechanistic pathway, which involves at least five redox state intermediates S n (n = 0–4) resu...

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Veröffentlicht in:	Journal of the American Chemical Society 2011-12, Vol.133 (49), p.19743-19757
Hauptverfasser:	Ames, William, Pantazis, Dimitrios A, Krewald, Vera, Cox, Nicholas, Messinger, Johannes, Lubitz, Wolfgang, Neese, Frank
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalytic Domain Crystallography, X-Ray Electron Spin Resonance Spectroscopy - methods Magnetics Manganese - chemistry Models, Molecular Oxidation-Reduction Oxygen - chemistry Photosystem II Protein Complex - chemistry Protons Water - chemistry
Online-Zugang:	Volltext
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