Synthesis and characterization of cobalt substituted zinc ferri-chromites prepared by sol–gel auto-combustion method

Mixed metal oxides having spinel structure shows interesting structural properties. In the present investigation, cobalt substituted zinc ferri-chromites were prepared by sol–gel auto-combustion method. The completion of solid state reaction and the formation of spinel phase were identified using X-...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2011-08, Vol.22 (8), p.1109-1115
Hauptverfasser: Hankare, P. P., Vader, V. T., Sankpal, U. B., Patil, R. P., Jadhav, A. V., Mulla, I. S.
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container_issue 8
container_start_page 1109
container_title Journal of materials science. Materials in electronics
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creator Hankare, P. P.
Vader, V. T.
Sankpal, U. B.
Patil, R. P.
Jadhav, A. V.
Mulla, I. S.
description Mixed metal oxides having spinel structure shows interesting structural properties. In the present investigation, cobalt substituted zinc ferri-chromites were prepared by sol–gel auto-combustion method. The completion of solid state reaction and the formation of spinel phase were identified using X-ray diffraction technique. All the compounds exhibit cubic spinel symmetry and lattice constant shows an irregular trend with substitution of Co. Infra-red spectral studies shows an two strong bands, one around 600 cm −1 which is attributed to the intrinsic vibrations of tetrahedral complexes and the other at 400 cm −1 is due to octahedral one. The morphology and size of the particles was found out by scanning electron microscopy while the elemental compositions by elemental dispersive X-ray spectroscopy. The various compounds of the present system Zn 1−x Co x FeCrO 4 were also investigated for their thermal and electronic studies.
doi_str_mv 10.1007/s10854-010-0268-7
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The completion of solid state reaction and the formation of spinel phase were identified using X-ray diffraction technique. All the compounds exhibit cubic spinel symmetry and lattice constant shows an irregular trend with substitution of Co. Infra-red spectral studies shows an two strong bands, one around 600 cm −1 which is attributed to the intrinsic vibrations of tetrahedral complexes and the other at 400 cm −1 is due to octahedral one. The morphology and size of the particles was found out by scanning electron microscopy while the elemental compositions by elemental dispersive X-ray spectroscopy. The various compounds of the present system Zn 1−x Co x FeCrO 4 were also investigated for their thermal and electronic studies.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10854-010-0268-7</doi><tpages>7</tpages></addata></record>
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subjects Applied sciences
Characterization and Evaluation of Materials
Chemistry and Materials Science
Cobalt
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Electronics
Exact sciences and technology
Instruments, apparatus, components and techniques common to several branches of physics and astronomy
Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties
Materials Science
Materials synthesis
materials processing
Metals. Metallurgy
Optical and Electronic Materials
Physics
Powder metallurgy. Composite materials
Production techniques
Scanning probe microscopes, components and techniques
Sol gel process
Spinel
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Technology
Vibration
X-rays
Zinc
title Synthesis and characterization of cobalt substituted zinc ferri-chromites prepared by sol–gel auto-combustion method
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