Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′-tetraisobutyl-2,6-dipicolinamide
Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H + B − ) in the presence of N , N , N ′, N ′-tetraisobutyl-2,6-dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the species HL...
Gespeichert in:
| Veröffentlicht in: | Journal of radioanalytical and nuclear chemistry 2011-04, Vol.288 (1), p.233-238 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 238 |
|---|---|
| container_issue | 1 |
| container_start_page | 233 |
| container_title | Journal of radioanalytical and nuclear chemistry |
| container_volume | 288 |
| creator | Makrlík, E. Vaňura, P. Selucký, P. Babain, V. A. Smirnov, I. V. |
| description | Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H
+
B
−
) in the presence of
N
,
N
,
N
′,
N
′-tetraisobutyl-2,6-dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the species HL
+
, HL
2
+
, CaL
2
2+
, SrL
2
2+
and SrL
3
2+
are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined. |
| doi_str_mv | 10.1007/s10967-010-0902-0 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_907956058</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>907956058</sourcerecordid><originalsourceid>FETCH-LOGICAL-c320t-8ad6973e25dd7082a2a709a7950ef6f4f294bd45ee1adb8a4cedf9d1607f4253</originalsourceid><addsrcrecordid>eNp9kU1uFDEQhVuISAwhB8jOOzYxlN0_bi9RBAEpggXZW267enDktgfbjdKsOBLiSDkJngxrVFKVSnrvU5Ve01wyeMMAxNvMQA6CAgMKEjiFZ82O9eNIuRjhebMD3g60Fy170bzM-R4A5Di2u-b31-h_YCgEH0rSprgYSJyJ0d64dSE6WJJLiqEcNxdKJMHVfcLwEwOSaSNrdmFPNMlbwLR3uThDFvdQ1oRH0rfNprjHQKwzOk3R-82bOGlfdMEn_uerWo-__jw1WrDe4XKc1rJ5yq8Gat3Bmehd0Iuz-Ko5m7XPePFvnjd3H97fXX-kt19uPl2_u6Wm5VDoqO0gRYu8t1bAyDXXAqQWsgech7mbuewm2_WITNtp1J1BO0vLBhBzx_v2vHl9wh5S_L5iLmpx2aD3OmBcs5JQUQP0Y1Wyk9KkmHPCWR2SW3TaFAN1zEadslE1G3XMRkH18JMnV23YY1L3cU2h_vMf01_piZjT</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>907956058</pqid></control><display><type>article</type><title>Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′-tetraisobutyl-2,6-dipicolinamide</title><source>SpringerNature Journals</source><creator>Makrlík, E. ; Vaňura, P. ; Selucký, P. ; Babain, V. A. ; Smirnov, I. V.</creator><creatorcontrib>Makrlík, E. ; Vaňura, P. ; Selucký, P. ; Babain, V. A. ; Smirnov, I. V.</creatorcontrib><description>Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H
+
B
−
) in the presence of
N
,
N
,
N
′,
N
′-tetraisobutyl-2,6-dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the species HL
+
, HL
2
+
, CaL
2
2+
, SrL
2
2+
and SrL
3
2+
are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined.</description><identifier>ISSN: 0236-5731</identifier><identifier>EISSN: 1588-2780</identifier><identifier>DOI: 10.1007/s10967-010-0902-0</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Calcium ; Cationic ; Chemistry ; Chemistry and Materials Science ; Diagnostic Radiology ; Hadrons ; Heavy Ions ; Inorganic Chemistry ; Nitrobenzenes ; Nuclear Chemistry ; Nuclear Physics ; Physical Chemistry ; Solvent extraction ; Stability constants ; Strontium</subject><ispartof>Journal of radioanalytical and nuclear chemistry, 2011-04, Vol.288 (1), p.233-238</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c320t-8ad6973e25dd7082a2a709a7950ef6f4f294bd45ee1adb8a4cedf9d1607f4253</citedby><cites>FETCH-LOGICAL-c320t-8ad6973e25dd7082a2a709a7950ef6f4f294bd45ee1adb8a4cedf9d1607f4253</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10967-010-0902-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10967-010-0902-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Makrlík, E.</creatorcontrib><creatorcontrib>Vaňura, P.</creatorcontrib><creatorcontrib>Selucký, P.</creatorcontrib><creatorcontrib>Babain, V. A.</creatorcontrib><creatorcontrib>Smirnov, I. V.</creatorcontrib><title>Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′-tetraisobutyl-2,6-dipicolinamide</title><title>Journal of radioanalytical and nuclear chemistry</title><addtitle>J Radioanal Nucl Chem</addtitle><description>Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H
+
B
−
) in the presence of
N
,
N
,
N
′,
N
′-tetraisobutyl-2,6-dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the species HL
+
, HL
2
+
, CaL
2
2+
, SrL
2
2+
and SrL
3
2+
are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined.</description><subject>Calcium</subject><subject>Cationic</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Diagnostic Radiology</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Inorganic Chemistry</subject><subject>Nitrobenzenes</subject><subject>Nuclear Chemistry</subject><subject>Nuclear Physics</subject><subject>Physical Chemistry</subject><subject>Solvent extraction</subject><subject>Stability constants</subject><subject>Strontium</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kU1uFDEQhVuISAwhB8jOOzYxlN0_bi9RBAEpggXZW267enDktgfbjdKsOBLiSDkJngxrVFKVSnrvU5Ve01wyeMMAxNvMQA6CAgMKEjiFZ82O9eNIuRjhebMD3g60Fy170bzM-R4A5Di2u-b31-h_YCgEH0rSprgYSJyJ0d64dSE6WJJLiqEcNxdKJMHVfcLwEwOSaSNrdmFPNMlbwLR3uThDFvdQ1oRH0rfNprjHQKwzOk3R-82bOGlfdMEn_uerWo-__jw1WrDe4XKc1rJ5yq8Gat3Bmehd0Iuz-Ko5m7XPePFvnjd3H97fXX-kt19uPl2_u6Wm5VDoqO0gRYu8t1bAyDXXAqQWsgech7mbuewm2_WITNtp1J1BO0vLBhBzx_v2vHl9wh5S_L5iLmpx2aD3OmBcs5JQUQP0Y1Wyk9KkmHPCWR2SW3TaFAN1zEadslE1G3XMRkH18JMnV23YY1L3cU2h_vMf01_piZjT</recordid><startdate>20110401</startdate><enddate>20110401</enddate><creator>Makrlík, E.</creator><creator>Vaňura, P.</creator><creator>Selucký, P.</creator><creator>Babain, V. A.</creator><creator>Smirnov, I. V.</creator><general>Springer Netherlands</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7SU</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110401</creationdate><title>Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′-tetraisobutyl-2,6-dipicolinamide</title><author>Makrlík, E. ; Vaňura, P. ; Selucký, P. ; Babain, V. A. ; Smirnov, I. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c320t-8ad6973e25dd7082a2a709a7950ef6f4f294bd45ee1adb8a4cedf9d1607f4253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Calcium</topic><topic>Cationic</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Diagnostic Radiology</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Inorganic Chemistry</topic><topic>Nitrobenzenes</topic><topic>Nuclear Chemistry</topic><topic>Nuclear Physics</topic><topic>Physical Chemistry</topic><topic>Solvent extraction</topic><topic>Stability constants</topic><topic>Strontium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Makrlík, E.</creatorcontrib><creatorcontrib>Vaňura, P.</creatorcontrib><creatorcontrib>Selucký, P.</creatorcontrib><creatorcontrib>Babain, V. A.</creatorcontrib><creatorcontrib>Smirnov, I. V.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Makrlík, E.</au><au>Vaňura, P.</au><au>Selucký, P.</au><au>Babain, V. A.</au><au>Smirnov, I. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′-tetraisobutyl-2,6-dipicolinamide</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2011-04-01</date><risdate>2011</risdate><volume>288</volume><issue>1</issue><spage>233</spage><epage>238</epage><pages>233-238</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H
+
B
−
) in the presence of
N
,
N
,
N
′,
N
′-tetraisobutyl-2,6-dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the species HL
+
, HL
2
+
, CaL
2
2+
, SrL
2
2+
and SrL
3
2+
are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10967-010-0902-0</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0236-5731 |
| ispartof | Journal of radioanalytical and nuclear chemistry, 2011-04, Vol.288 (1), p.233-238 |
| issn | 0236-5731 1588-2780 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_907956058 |
| source | SpringerNature Journals |
| subjects | Calcium Cationic Chemistry Chemistry and Materials Science Diagnostic Radiology Hadrons Heavy Ions Inorganic Chemistry Nitrobenzenes Nuclear Chemistry Nuclear Physics Physical Chemistry Solvent extraction Stability constants Strontium |
| title | Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′-tetraisobutyl-2,6-dipicolinamide |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-19T05%3A50%3A42IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Solvent%20extraction%20of%20calcium%20and%20strontium%20into%20nitrobenzene%20by%20using%20a%20synergistic%20mixture%20of%20hydrogen%20dicarbollylcobaltate%20and%20N,N,N%E2%80%B2,N%E2%80%B2-tetraisobutyl-2,6-dipicolinamide&rft.jtitle=Journal%20of%20radioanalytical%20and%20nuclear%20chemistry&rft.au=Makrl%C3%ADk,%20E.&rft.date=2011-04-01&rft.volume=288&rft.issue=1&rft.spage=233&rft.epage=238&rft.pages=233-238&rft.issn=0236-5731&rft.eissn=1588-2780&rft_id=info:doi/10.1007/s10967-010-0902-0&rft_dat=%3Cproquest_cross%3E907956058%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=907956058&rft_id=info:pmid/&rfr_iscdi=true |