Synthesis of non-equilibrium phases in immiscible metals mechanically mixed by high pressure torsion

The structural changes in mechanically mixed metals of immiscible combinations of elements caused by bulk mechanical alloying (MA) through the use of high pressure torsion (HPT) were investigated in Ag–Ni and Nb–Zr systems. There was no alloying between Ag and Ni on atomic scale even after 100 rotat...

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Veröffentlicht in:Journal of materials science 2011-06, Vol.46 (12), p.4296-4301
Hauptverfasser: Miyazaki, Tatsuya, Terada, Daisuke, Miyajima, Yoji, Suryanarayana, Challapalli, Murao, Reiko, Yokoyama, Yoshihiko, Sugiyama, Kazumasa, Umemoto, Minoru, Todaka, Yoshikazu, Tsuji, Nobuhiro
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container_end_page 4301
container_issue 12
container_start_page 4296
container_title Journal of materials science
container_volume 46
creator Miyazaki, Tatsuya
Terada, Daisuke
Miyajima, Yoji
Suryanarayana, Challapalli
Murao, Reiko
Yokoyama, Yoshihiko
Sugiyama, Kazumasa
Umemoto, Minoru
Todaka, Yoshikazu
Tsuji, Nobuhiro
description The structural changes in mechanically mixed metals of immiscible combinations of elements caused by bulk mechanical alloying (MA) through the use of high pressure torsion (HPT) were investigated in Ag–Ni and Nb–Zr systems. There was no alloying between Ag and Ni on atomic scale even after 100 rotations of HPT. On the other hand, the β-Zr phase started to appear after HPT 2 rotations in the Nb–Zr system, even though β-Zr is a high temperature phase. Further, Nb and Zr were completely mixed to form a bcc structured single phase after HPT 100 rotations. The sequence of alloying in the Nb–Zr system during HPT was discussed. These results clearly suggest that non-equilibrium phases can form in the Nb–Zr system by bulk MA by the use of HPT.
doi_str_mv 10.1007/s10853-010-5240-7
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subjects Alloy systems
Alloying
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Crystallography and Scattering Methods
High temperature
Iib 2010
Materials Science
Mechanical alloying
Miscibility
Nickel
Niobium
Niobium base alloys
Phases
Polymer Sciences
Silver base alloys
Solid Mechanics
Torsion
Zirconium
title Synthesis of non-equilibrium phases in immiscible metals mechanically mixed by high pressure torsion
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