Densification of MOF-5 synthesized at ambient temperature for methane adsorption
MOF-5 was synthesized by a direct mixing method at ambient temperature. Relevant treatment procedures of solvothermal activation, preservation in a solvent, and reactivation of MOF-5 under anhydrous conditions were proposed and proved efficient. In order to examine the influence of densification of...
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| Veröffentlicht in: | Materials letters 2011-08, Vol.65 (15), p.2445-2447 |
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| container_issue | 15 |
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| container_title | Materials letters |
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| creator | Jia, Zheng Li, Haibo Yu, Zhenxing Wang, Peng Fan, Xuelei |
| description | MOF-5 was synthesized by a direct mixing method at ambient temperature. Relevant treatment procedures of solvothermal activation, preservation in a solvent, and reactivation of MOF-5 under anhydrous conditions were proposed and proved efficient. In order to examine the influence of densification of MOF-5 on the methane volumetric storage capability, the practical packing densities of the samples mechanically pressed under different pressures were measured. The results indicate that mechanical pressing could improve the packing density, but decrease the methane gravimetric storage quantity to some extent. The optimized effective volumetric storage quantity of methane reached 81
V(STP)/V at 3.69
MPa for the sample pressed under 1.0
MPa. |
| doi_str_mv | 10.1016/j.matlet.2011.04.099 |
| format | Article |
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V(STP)/V at 3.69
MPa for the sample pressed under 1.0
MPa.</description><identifier>ISSN: 0167-577X</identifier><identifier>EISSN: 1873-4979</identifier><identifier>DOI: 10.1016/j.matlet.2011.04.099</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Activation ; Ambient temperature ; Densification ; Energy storage and conversion ; Gravimeters ; Methane ; Methane adsorption ; MOF-5 ; Packing density ; Porous materials ; Pressing ; Solvents</subject><ispartof>Materials letters, 2011-08, Vol.65 (15), p.2445-2447</ispartof><rights>2011 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c338t-1795c07e55ea13f885707f343bd4067755bf35bbb3b17389f267f2207617abc33</citedby><cites>FETCH-LOGICAL-c338t-1795c07e55ea13f885707f343bd4067755bf35bbb3b17389f267f2207617abc33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.matlet.2011.04.099$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Jia, Zheng</creatorcontrib><creatorcontrib>Li, Haibo</creatorcontrib><creatorcontrib>Yu, Zhenxing</creatorcontrib><creatorcontrib>Wang, Peng</creatorcontrib><creatorcontrib>Fan, Xuelei</creatorcontrib><title>Densification of MOF-5 synthesized at ambient temperature for methane adsorption</title><title>Materials letters</title><description>MOF-5 was synthesized by a direct mixing method at ambient temperature. Relevant treatment procedures of solvothermal activation, preservation in a solvent, and reactivation of MOF-5 under anhydrous conditions were proposed and proved efficient. In order to examine the influence of densification of MOF-5 on the methane volumetric storage capability, the practical packing densities of the samples mechanically pressed under different pressures were measured. The results indicate that mechanical pressing could improve the packing density, but decrease the methane gravimetric storage quantity to some extent. The optimized effective volumetric storage quantity of methane reached 81
V(STP)/V at 3.69
MPa for the sample pressed under 1.0
MPa.</description><subject>Activation</subject><subject>Ambient temperature</subject><subject>Densification</subject><subject>Energy storage and conversion</subject><subject>Gravimeters</subject><subject>Methane</subject><subject>Methane adsorption</subject><subject>MOF-5</subject><subject>Packing density</subject><subject>Porous materials</subject><subject>Pressing</subject><subject>Solvents</subject><issn>0167-577X</issn><issn>1873-4979</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEURYMoWKv_wEV2rmZ8aZJmshGkWhUqdaHgLmRmXmhK58MkFeqvd8q4dvU29x7uO4RcM8gZsPntNm9s2mHKZ8BYDiIHrU_IhBWKZ0IrfUomQ0xlUqnPc3IR4xYAhAYxIW8P2EbvfGWT71raOfq6XmaSxkObNhj9D9bUJmqb0mObaMKmx2DTPiB1XaANpo1tkdo6dqE_Ii7JmbO7iFd_d0o-lo_vi-dstX56WdyvsorzImVMaVmBQinRMu6KQipQjgte1gLmSklZOi7LsuQlU7zQbjZXbjYDNWfKlgNjSm5Gbh-6rz3GZBofK9zthjndPhoNSgsQTA5JMSar0MUY0Jk--MaGg2Fgjv7M1oz-zNGfAWEGf0Ptbqzh8MW3x2BiNTiosPYBq2Tqzv8P-AX2aHsA</recordid><startdate>20110801</startdate><enddate>20110801</enddate><creator>Jia, Zheng</creator><creator>Li, Haibo</creator><creator>Yu, Zhenxing</creator><creator>Wang, Peng</creator><creator>Fan, Xuelei</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20110801</creationdate><title>Densification of MOF-5 synthesized at ambient temperature for methane adsorption</title><author>Jia, Zheng ; Li, Haibo ; Yu, Zhenxing ; Wang, Peng ; Fan, Xuelei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c338t-1795c07e55ea13f885707f343bd4067755bf35bbb3b17389f267f2207617abc33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Activation</topic><topic>Ambient temperature</topic><topic>Densification</topic><topic>Energy storage and conversion</topic><topic>Gravimeters</topic><topic>Methane</topic><topic>Methane adsorption</topic><topic>MOF-5</topic><topic>Packing density</topic><topic>Porous materials</topic><topic>Pressing</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jia, Zheng</creatorcontrib><creatorcontrib>Li, Haibo</creatorcontrib><creatorcontrib>Yu, Zhenxing</creatorcontrib><creatorcontrib>Wang, Peng</creatorcontrib><creatorcontrib>Fan, Xuelei</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Materials letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jia, Zheng</au><au>Li, Haibo</au><au>Yu, Zhenxing</au><au>Wang, Peng</au><au>Fan, Xuelei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Densification of MOF-5 synthesized at ambient temperature for methane adsorption</atitle><jtitle>Materials letters</jtitle><date>2011-08-01</date><risdate>2011</risdate><volume>65</volume><issue>15</issue><spage>2445</spage><epage>2447</epage><pages>2445-2447</pages><issn>0167-577X</issn><eissn>1873-4979</eissn><abstract>MOF-5 was synthesized by a direct mixing method at ambient temperature. Relevant treatment procedures of solvothermal activation, preservation in a solvent, and reactivation of MOF-5 under anhydrous conditions were proposed and proved efficient. In order to examine the influence of densification of MOF-5 on the methane volumetric storage capability, the practical packing densities of the samples mechanically pressed under different pressures were measured. The results indicate that mechanical pressing could improve the packing density, but decrease the methane gravimetric storage quantity to some extent. The optimized effective volumetric storage quantity of methane reached 81
V(STP)/V at 3.69
MPa for the sample pressed under 1.0
MPa.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.matlet.2011.04.099</doi><tpages>3</tpages></addata></record> |
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| ispartof | Materials letters, 2011-08, Vol.65 (15), p.2445-2447 |
| issn | 0167-577X 1873-4979 |
| language | eng |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Activation Ambient temperature Densification Energy storage and conversion Gravimeters Methane Methane adsorption MOF-5 Packing density Porous materials Pressing Solvents |
| title | Densification of MOF-5 synthesized at ambient temperature for methane adsorption |
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