Influences of process parameters on texture and microstructure of NiO films

The experimental result shows that the preferred orientations of NiO thin films are closely related to the working pressure of argon. All of NiO(111), NiO(200), and NiO(220) diffraction peaks are observed in the XRD patterns and exhibited random orientation of NiO film when the film is deposited in...

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Veröffentlicht in:Thin solid films 2011-05, Vol.519 (15), p.4940-4943
Hauptverfasser: Kuo, T.Y., Chen, S.C., Peng, W.C., Lin, Y.C., Lin, H.C.
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container_end_page 4943
container_issue 15
container_start_page 4940
container_title Thin solid films
container_volume 519
creator Kuo, T.Y.
Chen, S.C.
Peng, W.C.
Lin, Y.C.
Lin, H.C.
description The experimental result shows that the preferred orientations of NiO thin films are closely related to the working pressure of argon. All of NiO(111), NiO(200), and NiO(220) diffraction peaks are observed in the XRD patterns and exhibited random orientation of NiO film when the film is deposited in low Ar pressure of 0.67 Pa. As the Ar pressure is increased to 2.67 Pa, only the NiO(200) peak appears and shows (200)-textured NiO films. However, the lattice parameter of NiO film deposited in high Ar pressure of 2.67 Pa is 0.426 nm, which is much larger than that of the NiO bulk (0.417 nm). The lattice parameter can be reduced by post-annealing the film because the interstitial Ar atoms are released from the NiO lattice, decreasing continuously from 0.423 to 0.417 nm as the NiO films are annealed by rapid thermal annealing (RTA) from 300 to 600 °C.
doi_str_mv 10.1016/j.tsf.2011.01.057
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subjects Annealing
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Deposition
Deposition by sputtering
Diffraction patterns
Exact sciences and technology
Glass substrate
Lattice parameters
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Microstructure
NiO films
Physics
Process parameters
rf magnetron sputtering
Structure and morphology
thickness
Surface layer
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Texture
Thin film structure and morphology
Thin films
title Influences of process parameters on texture and microstructure of NiO films
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