Cation Distribution in Zn Doped Cobalt Nanoferrites Determined by X-ray Absorption Spectroscopy

Information on local crystal and electronic structure with elemental specificity is of paramount importance to understand many scientific problems. X-ray Absorption Spectroscopy (XAS) is particularly suited for this. Spinel structured ferrites exhibit a range of electrical and magnetic properties th...

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Veröffentlicht in:Journal of superconductivity and novel magnetism 2011-01, Vol.24 (1-2), p.659-663
Hauptverfasser: Aquilanti, Giuliana, Cognigni, Andrea, Anis-ur-Rehman, M.
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container_title Journal of superconductivity and novel magnetism
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Cognigni, Andrea
Anis-ur-Rehman, M.
description Information on local crystal and electronic structure with elemental specificity is of paramount importance to understand many scientific problems. X-ray Absorption Spectroscopy (XAS) is particularly suited for this. Spinel structured ferrites exhibit a range of electrical and magnetic properties that make them particularly appealing for many technological applications such as permanent magnets, microwave absorbers, catalysts, and chemical sensors. Since the peculiar properties of ferrites are strictly related to the distribution of cations between octahedral and tetrahedral sites in the spinel structure, the control of cation distribution provides a means to tailor their properties. An EXAFS study of Co x Zn 1− x Fe 2 O 4 nanoparticles is presented here. Using this technique, the information about the site distribution for Fe and Co/Zn is determined. The information obtained on the cation distribution is important to understand the microstructure of spinel ferrites which is useful to study their effects on structural, electrical, and magnetic properties.
doi_str_mv 10.1007/s10948-010-0929-z
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subjects Absorption spectroscopy
Cations
Characterization and Evaluation of Materials
Condensed Matter Physics
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Ferrites
Inorganic compounds
Magnetic Materials
Magnetic properties
Magnetism
Nanostructure
Original Paper
Physics
Physics and Astronomy
Spinel
Strongly Correlated Systems
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Superconductivity
Water, oxides, hydroxides, peroxides
X-rays
Zinc
title Cation Distribution in Zn Doped Cobalt Nanoferrites Determined by X-ray Absorption Spectroscopy
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