Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO2

Even in the context of hydrocarbons' general resistance to selective functionalization, methane's volatility and strong bonds pose a particular challenge. We report here that silver complexes bearing perfluorinated indazolylborate ligands catalyze the reaction of methane (CH4) with ethyl d...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2011-05, Vol.332 (6031), p.835-838
Hauptverfasser:	CABALLERO, Ana, DESPAGNET-AYOUB, Emmanuelle, PEREZ, Pedro ], DIAZ-REQUEJO, M. Mar, DIAZ-RODRIGUEZ, Alba, GONZALEZ-NUNEZ, María Elena, MELLO, Rossella, MUNOZ, Bianca K, OJO, Wilfried-Solo, ASENSIO, Gregorio, ETIENNE, Michel
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Carbon dioxide Carbon-carbon composites Catalysis Catalysts Catalysts: preparations and properties Chemical bonds Chemistry Ethyl propionate Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Hydrocarbons Ligands Methane Organic chemistry Preparations and properties Solvents Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Volatility
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