Liquid phase oxidation of p-xylene to terephthalic acid at medium-high temperatures: multiple benefits of CO2-expanded liquids

The Co/Mn/Br catalyzed oxidation of p-xylene to terephthalic acid (TPA) is demonstrated in CO2-expanded solvents at temperatures lower than those of the traditional Mid-Century (MC) process. As compared with the traditional air (N2/O2) oxidation system, the reaction with CO2/O2 mixture at 160 [degre...

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Veröffentlicht in:	Green chemistry : an international journal and green chemistry resource : GC 2010-01, Vol.12 (2), p.260-267
Hauptverfasser:	XIAOBIN ZUO, FENGHUI NIU, SNAVELY, Kirk, SUBRAMANIAM, Bala, BUSCH, Daryle H
Format:	Artikel
Sprache:	eng
Schlagworte:	Byproducts Chemistry Exact sciences and technology Kinetics and mechanisms Noncondensed benzenic compounds Organic chemistry Preparations and properties Reactivity and mechanisms
Online-Zugang:	Volltext
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