A green protocol for the silylation of alcohols using bonded fluorous phase catalysis
The surface of a solid silica support has been functionalized with long perfluoroalkyl chains. The resulting surface layer readily adsorbs fluorous molecules from organic solutions. In this way, dirhodium() perfluorocarboxylate catalysts can be conveniently immobilized on a solid support. The result...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2003-01, Vol.5 (2), p.170-173 |
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| container_end_page | 173 |
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| container_issue | 2 |
| container_start_page | 170 |
| container_title | Green chemistry : an international journal and green chemistry resource : GC |
| container_volume | 5 |
| creator | Biffis, A Zecca, M Basato, M |
| description | The surface of a solid silica support has been functionalized with long perfluoroalkyl chains. The resulting surface layer readily adsorbs fluorous molecules from organic solutions. In this way, dirhodium() perfluorocarboxylate catalysts can be conveniently immobilized on a solid support. The resulting Bonded Fluorous Phase (BFP) catalysts display a high activity in the silane alcoholysis reaction using a solventless procedure and are easily recycled. |
| doi_str_mv | 10.1039/B210992A |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2003-01, Vol.5 (2), p.170-173 |
| issn | 1463-9262 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_907185000 |
| source | Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alcohol |
| title | A green protocol for the silylation of alcohols using bonded fluorous phase catalysis |
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