Selenacalix[3]triazines: synthesis and host-guest chemistry

Selenacalix[3]triazines: synthesis and host-guest chemistry

The heteracalixarene series (N/O/S) has been expanded with Se-bridged cyclotrimeric macrocycles. Selenacalix[3]triazines were synthesized by convenient one-pot nucleophilic aromatic substitution reactions and they showed peculiar supramolecular features. The N tridentate binding pocket was capable o...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (1), p.43-45
Hauptverfasser: Thomas, Joice, Van Rossom, Wim, Van Hecke, Kristof, Van Meervelt, Luc, Smet, Mario, Maes, Wouter, Dehaen, Wim
Format: Artikel
Sprache:eng
Schlagworte:
Anions
Binding
Chemistry Techniques, Synthetic - methods
Copper
Models, Molecular
Molecular Conformation
Organoselenium Compounds - chemical synthesis
Organoselenium Compounds - chemistry
Pocket
Substitution reactions
Synthesis
Triazines - chemistry
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Beschreibung
Zusammenfassung:The heteracalixarene series (N/O/S) has been expanded with Se-bridged cyclotrimeric macrocycles. Selenacalix[3]triazines were synthesized by convenient one-pot nucleophilic aromatic substitution reactions and they showed peculiar supramolecular features. The N tridentate binding pocket was capable of coordinating both copper ions and anions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc15473g