Control of the Photocatalytic Activity of Bimetallic Complexes of Pyropheophorbide-a by Nucleic Acids

Photocatalytic activity of a photosensitizer (PS) in an oligodeoxyribonucleotide duplex 5′-PS∼ODN1/ODN2∼Q-3′ is inhibited because of close proximity of a quencher Q. The ODN2 in this duplex is selected to be longer than the ODN1. Therefore, in the presence of a nucleic acid (analyte), which is fully...

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Veröffentlicht in:	Inorganic chemistry 2011-12, Vol.50 (23), p.12010-12017
Hauptverfasser:	Arian, Dumitru, Kovbasyuk, Larisa, Mokhir, Andriy
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chlorophyll - analogs & derivatives Chlorophyll - chemistry Nucleic Acid Hybridization Nucleic Acids - chemistry Oligodeoxyribonucleotides - chemistry Organometallic Compounds - chemistry Photochemical Processes
Online-Zugang:	Volltext
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