Sequential catalytic role of bifunctional bicyclic guanidine in asymmetric phospha-Michael reaction

The catalytic mechanism and origin of enantioselectivity of bicyclic guanidine-catalyzed phospha-Michael reaction between diphenyl phosphine oxide and β-nitrostyrene were investigated by DFT calculations at M06-2X/cc-pVTZ//M06-2X/cc-pVDZ level in conjunction with the implicit SMD solvation method. T...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organic & biomolecular chemistry 2011-06, Vol.9 (12), p.4550-4557
Hauptverfasser:	Cho, Bokun, Tan, Choon-Hong, Wong, Ming Wah
Format:	Artikel
Sprache:	eng
Schlagworte:	Bridged Bicyclo Compounds - chemistry Catalysis Chemistry, Organic Crystallography, X-Ray Guanidine - chemistry Hydrogen - chemistry Hydrogen Bonding Models, Molecular Phenyl Ethers - chemistry Phosphines - chemistry Quantum Theory Stereoisomerism Styrenes - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!