Concerted vs Stepwise Mechanisms in Dehydro-Diels–Alder Reactions

The Diels–Alder reaction is not limited to 1,3-dienes. Many cycloadditions of enynes and a smaller number of examples with 1,3-diynes have been reported. These “dehydro”-Diels–Alder cycloadditions are one class of dehydropericyclic reactions which have long been used to generate strained cyclic alle...

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Veröffentlicht in:	Journal of organic chemistry 2011-11, Vol.76 (22), p.9320-9328
Hauptverfasser:	Ajaz, Aida, Bradley, Alexander Z, Burrell, Richard C, Li, William Hoi Hong, Daoust, Kimberly J, Bovee, Laura Boddington, DiRico, Kenneth J, Johnson, Richard P
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology Free radicals chemistry Kinetics and mechanisms Organic chemistry Preparations and properties Reactivity and mechanisms
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