Mechanism of silver- and copper-catalyzed decarboxylation reactions of aryl carboxylic acids

Silver- and copper-catalyzed decarboxylation reactions of aryl carboxylic acids were investigated with the aid of density functional theory calculations. The reaction mechanism starts with a carboxylate complex of silver or copper. Decarboxylation occurs via ejecting CO(2) from the carboxylate compl...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2011-01, Vol.40 (44), p.11926-11936
Hauptverfasser:	Xue, Liqin, Su, Weiping, Lin, Zhenyang
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Barriers Carbon dioxide Carboxylates Carboxylic acids Decarboxylation Density functional theory Mathematical analysis
Online-Zugang:	Volltext
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