Environmental properties of long chain alcohols. Part 1: Physicochemical, environmental fate and acute aquatic toxicity properties
This paper summarises the physicochemical, biodegradation and acute aquatic ecotoxicity properties of long chain aliphatic alcohols. Properties of pure compounds are shown to follow somewhat predictable trends, which are amenable to estimation by quantitative structure–activity relationships ((Q)SAR...
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Veröffentlicht in: | Ecotoxicology and environmental safety 2009-05, Vol.72 (4), p.980-995 |
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creator | Fisk, Peter R. Wildey, Rosalind J. Girling, Andrew E. Sanderson, Hans Belanger, Scott E. Veenstra, Gauke Nielsen, Allen Kasai, Yutaka Willing, Andreas Dyer, Scott D. Stanton, Kathleen |
description | This paper summarises the physicochemical, biodegradation and acute aquatic ecotoxicity properties of long chain aliphatic alcohols. Properties of pure compounds are shown to follow somewhat predictable trends, which are amenable to estimation by quantitative structure–activity relationships ((Q)SARs). This allows predictions of data relating to human and environmental safety profiles and patterns. These alcohols have been shown to be rapidly degradable under standard conditions up to C
18. Furthermore, evidence suggests that longer chain lengths are also rapidly biodegradable. While log
K
ow values suggest possible bioaccumulation potential, available data suggest that these substances are not as bioaccumulative as estimations would predict. For acute aquatic toxicity, solubility limits the possibility of effects being appropriately observed and become increasingly challenging above C
12. Further, a model has been developed for multi-component mixtures which give an excellent account of aquatic ecotoxicity allowing for the prediction of acute effects of un-tested mixtures. |
doi_str_mv | 10.1016/j.ecoenv.2008.09.025 |
format | Article |
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18. Furthermore, evidence suggests that longer chain lengths are also rapidly biodegradable. While log
K
ow values suggest possible bioaccumulation potential, available data suggest that these substances are not as bioaccumulative as estimations would predict. For acute aquatic toxicity, solubility limits the possibility of effects being appropriately observed and become increasingly challenging above C
12. Further, a model has been developed for multi-component mixtures which give an excellent account of aquatic ecotoxicity allowing for the prediction of acute effects of un-tested mixtures.</description><identifier>ISSN: 0147-6513</identifier><identifier>EISSN: 1090-2414</identifier><identifier>DOI: 10.1016/j.ecoenv.2008.09.025</identifier><identifier>PMID: 19038450</identifier><language>eng</language><publisher>Netherlands: Elsevier Inc</publisher><subject>Adsorption ; Animals ; Biodegradation ; Biodegradation, Environmental ; Environmental Monitoring ; Fatty Alcohols - chemistry ; Fatty Alcohols - toxicity ; Long chain aliphatic alcohols ; Octanol–water partition coefficient ecotoxicity ; OECD HPV ; Photochemistry ; Quantitative Structure-Activity Relationship ; Solubility ; Structure-Activity Relationship ; Volatilization ; Waste Disposal, Fluid ; Water - chemistry ; Water Pollutants, Chemical - chemistry ; Water Pollutants, Chemical - toxicity</subject><ispartof>Ecotoxicology and environmental safety, 2009-05, Vol.72 (4), p.980-995</ispartof><rights>2008 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c505t-6a3c0a6afe5b691cbcd185974e386f7ae59bb0403570eeb9dc658f323a93db7b3</citedby><cites>FETCH-LOGICAL-c505t-6a3c0a6afe5b691cbcd185974e386f7ae59bb0403570eeb9dc658f323a93db7b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.ecoenv.2008.09.025$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,46000</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19038450$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Fisk, Peter R.</creatorcontrib><creatorcontrib>Wildey, Rosalind J.</creatorcontrib><creatorcontrib>Girling, Andrew E.</creatorcontrib><creatorcontrib>Sanderson, Hans</creatorcontrib><creatorcontrib>Belanger, Scott E.</creatorcontrib><creatorcontrib>Veenstra, Gauke</creatorcontrib><creatorcontrib>Nielsen, Allen</creatorcontrib><creatorcontrib>Kasai, Yutaka</creatorcontrib><creatorcontrib>Willing, Andreas</creatorcontrib><creatorcontrib>Dyer, Scott D.</creatorcontrib><creatorcontrib>Stanton, Kathleen</creatorcontrib><title>Environmental properties of long chain alcohols. Part 1: Physicochemical, environmental fate and acute aquatic toxicity properties</title><title>Ecotoxicology and environmental safety</title><addtitle>Ecotoxicol Environ Saf</addtitle><description>This paper summarises the physicochemical, biodegradation and acute aquatic ecotoxicity properties of long chain aliphatic alcohols. Properties of pure compounds are shown to follow somewhat predictable trends, which are amenable to estimation by quantitative structure–activity relationships ((Q)SARs). This allows predictions of data relating to human and environmental safety profiles and patterns. These alcohols have been shown to be rapidly degradable under standard conditions up to C
18. Furthermore, evidence suggests that longer chain lengths are also rapidly biodegradable. While log
K
ow values suggest possible bioaccumulation potential, available data suggest that these substances are not as bioaccumulative as estimations would predict. For acute aquatic toxicity, solubility limits the possibility of effects being appropriately observed and become increasingly challenging above C
12. Further, a model has been developed for multi-component mixtures which give an excellent account of aquatic ecotoxicity allowing for the prediction of acute effects of un-tested mixtures.</description><subject>Adsorption</subject><subject>Animals</subject><subject>Biodegradation</subject><subject>Biodegradation, Environmental</subject><subject>Environmental Monitoring</subject><subject>Fatty Alcohols - chemistry</subject><subject>Fatty Alcohols - toxicity</subject><subject>Long chain aliphatic alcohols</subject><subject>Octanol–water partition coefficient ecotoxicity</subject><subject>OECD HPV</subject><subject>Photochemistry</subject><subject>Quantitative Structure-Activity Relationship</subject><subject>Solubility</subject><subject>Structure-Activity Relationship</subject><subject>Volatilization</subject><subject>Waste Disposal, Fluid</subject><subject>Water - chemistry</subject><subject>Water Pollutants, Chemical - chemistry</subject><subject>Water Pollutants, Chemical - toxicity</subject><issn>0147-6513</issn><issn>1090-2414</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkU1v1DAQhi1ERZfCP0DIJ7iQdBzb-eBQCVUFKlVqD3C2nMmE9SqJt7azYq_8crLalYBLOc0cnnlfaR7G3gjIBYjycpMTepp2eQFQ59DkUOhnbCWggaxQQj1nKxCqykot5Dl7GeMGACRo_YKdiwZkrTSs2K-baeeCn0aakh34NvgtheQoct_zwU8_OK6tm7gd0K_9EHP-YEPi4iN_WO-jQ49rGh3a4QOnf5J6m4jbqeMW58P2ONvkkCf_06FL-7-aXrGz3g6RXp_mBfv--ebb9dfs7v7L7fWnuww16JSVViLY0vak27IR2GInat1UimRd9pUl3bQtKJC6AqK26bDUdS8LaRvZtVUrL9j7Y-5S_ThTTGZ0EWkY7ER-jmb5SSm1FLCQ754kpVIHTv0XLEAXWpfVAqojiMHHGKg32-BGG_ZGgDnoNBtz1GkOOg00ZtG5nL095c_tSN2fo5O_Bbg6ArQ8bucomIiOJqTOBcJkOu-ebvgNtPW1Sg</recordid><startdate>20090501</startdate><enddate>20090501</enddate><creator>Fisk, Peter R.</creator><creator>Wildey, Rosalind J.</creator><creator>Girling, Andrew E.</creator><creator>Sanderson, Hans</creator><creator>Belanger, Scott E.</creator><creator>Veenstra, Gauke</creator><creator>Nielsen, Allen</creator><creator>Kasai, Yutaka</creator><creator>Willing, Andreas</creator><creator>Dyer, Scott D.</creator><creator>Stanton, Kathleen</creator><general>Elsevier Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7QO</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>7U9</scope><scope>7UA</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>FR3</scope><scope>H94</scope><scope>H97</scope><scope>L.G</scope><scope>P64</scope><scope>KR7</scope></search><sort><creationdate>20090501</creationdate><title>Environmental properties of long chain alcohols. Part 1: Physicochemical, environmental fate and acute aquatic toxicity properties</title><author>Fisk, Peter R. ; Wildey, Rosalind J. ; Girling, Andrew E. ; Sanderson, Hans ; Belanger, Scott E. ; Veenstra, Gauke ; Nielsen, Allen ; Kasai, Yutaka ; Willing, Andreas ; Dyer, Scott D. ; Stanton, Kathleen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c505t-6a3c0a6afe5b691cbcd185974e386f7ae59bb0403570eeb9dc658f323a93db7b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Adsorption</topic><topic>Animals</topic><topic>Biodegradation</topic><topic>Biodegradation, Environmental</topic><topic>Environmental Monitoring</topic><topic>Fatty Alcohols - chemistry</topic><topic>Fatty Alcohols - toxicity</topic><topic>Long chain aliphatic alcohols</topic><topic>Octanol–water partition coefficient ecotoxicity</topic><topic>OECD HPV</topic><topic>Photochemistry</topic><topic>Quantitative Structure-Activity Relationship</topic><topic>Solubility</topic><topic>Structure-Activity Relationship</topic><topic>Volatilization</topic><topic>Waste Disposal, Fluid</topic><topic>Water - chemistry</topic><topic>Water Pollutants, Chemical - chemistry</topic><topic>Water Pollutants, Chemical - toxicity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fisk, Peter R.</creatorcontrib><creatorcontrib>Wildey, Rosalind J.</creatorcontrib><creatorcontrib>Girling, Andrew E.</creatorcontrib><creatorcontrib>Sanderson, Hans</creatorcontrib><creatorcontrib>Belanger, Scott E.</creatorcontrib><creatorcontrib>Veenstra, Gauke</creatorcontrib><creatorcontrib>Nielsen, Allen</creatorcontrib><creatorcontrib>Kasai, Yutaka</creatorcontrib><creatorcontrib>Willing, Andreas</creatorcontrib><creatorcontrib>Dyer, Scott D.</creatorcontrib><creatorcontrib>Stanton, Kathleen</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Biotechnology Research Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Engineering Research Database</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Civil Engineering Abstracts</collection><jtitle>Ecotoxicology and environmental safety</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fisk, Peter R.</au><au>Wildey, Rosalind J.</au><au>Girling, Andrew E.</au><au>Sanderson, Hans</au><au>Belanger, Scott E.</au><au>Veenstra, Gauke</au><au>Nielsen, Allen</au><au>Kasai, Yutaka</au><au>Willing, Andreas</au><au>Dyer, Scott D.</au><au>Stanton, Kathleen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Environmental properties of long chain alcohols. 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18. Furthermore, evidence suggests that longer chain lengths are also rapidly biodegradable. While log
K
ow values suggest possible bioaccumulation potential, available data suggest that these substances are not as bioaccumulative as estimations would predict. For acute aquatic toxicity, solubility limits the possibility of effects being appropriately observed and become increasingly challenging above C
12. Further, a model has been developed for multi-component mixtures which give an excellent account of aquatic ecotoxicity allowing for the prediction of acute effects of un-tested mixtures.</abstract><cop>Netherlands</cop><pub>Elsevier Inc</pub><pmid>19038450</pmid><doi>10.1016/j.ecoenv.2008.09.025</doi><tpages>16</tpages></addata></record> |
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subjects | Adsorption Animals Biodegradation Biodegradation, Environmental Environmental Monitoring Fatty Alcohols - chemistry Fatty Alcohols - toxicity Long chain aliphatic alcohols Octanol–water partition coefficient ecotoxicity OECD HPV Photochemistry Quantitative Structure-Activity Relationship Solubility Structure-Activity Relationship Volatilization Waste Disposal, Fluid Water - chemistry Water Pollutants, Chemical - chemistry Water Pollutants, Chemical - toxicity |
title | Environmental properties of long chain alcohols. Part 1: Physicochemical, environmental fate and acute aquatic toxicity properties |
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