Environmental properties of long chain alcohols. Part 1: Physicochemical, environmental fate and acute aquatic toxicity properties

This paper summarises the physicochemical, biodegradation and acute aquatic ecotoxicity properties of long chain aliphatic alcohols. Properties of pure compounds are shown to follow somewhat predictable trends, which are amenable to estimation by quantitative structure–activity relationships ((Q)SAR...

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Veröffentlicht in:Ecotoxicology and environmental safety 2009-05, Vol.72 (4), p.980-995
Hauptverfasser: Fisk, Peter R., Wildey, Rosalind J., Girling, Andrew E., Sanderson, Hans, Belanger, Scott E., Veenstra, Gauke, Nielsen, Allen, Kasai, Yutaka, Willing, Andreas, Dyer, Scott D., Stanton, Kathleen
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container_end_page 995
container_issue 4
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container_title Ecotoxicology and environmental safety
container_volume 72
creator Fisk, Peter R.
Wildey, Rosalind J.
Girling, Andrew E.
Sanderson, Hans
Belanger, Scott E.
Veenstra, Gauke
Nielsen, Allen
Kasai, Yutaka
Willing, Andreas
Dyer, Scott D.
Stanton, Kathleen
description This paper summarises the physicochemical, biodegradation and acute aquatic ecotoxicity properties of long chain aliphatic alcohols. Properties of pure compounds are shown to follow somewhat predictable trends, which are amenable to estimation by quantitative structure–activity relationships ((Q)SARs). This allows predictions of data relating to human and environmental safety profiles and patterns. These alcohols have been shown to be rapidly degradable under standard conditions up to C 18. Furthermore, evidence suggests that longer chain lengths are also rapidly biodegradable. While log K ow values suggest possible bioaccumulation potential, available data suggest that these substances are not as bioaccumulative as estimations would predict. For acute aquatic toxicity, solubility limits the possibility of effects being appropriately observed and become increasingly challenging above C 12. Further, a model has been developed for multi-component mixtures which give an excellent account of aquatic ecotoxicity allowing for the prediction of acute effects of un-tested mixtures.
doi_str_mv 10.1016/j.ecoenv.2008.09.025
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subjects Adsorption
Animals
Biodegradation
Biodegradation, Environmental
Environmental Monitoring
Fatty Alcohols - chemistry
Fatty Alcohols - toxicity
Long chain aliphatic alcohols
Octanol–water partition coefficient ecotoxicity
OECD HPV
Photochemistry
Quantitative Structure-Activity Relationship
Solubility
Structure-Activity Relationship
Volatilization
Waste Disposal, Fluid
Water - chemistry
Water Pollutants, Chemical - chemistry
Water Pollutants, Chemical - toxicity
title Environmental properties of long chain alcohols. Part 1: Physicochemical, environmental fate and acute aquatic toxicity properties
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