Growth and optical and field emission properties of flower-like ZnO nanostructures with hexagonal crown

Flower-like zinc oxide (ZnO) nanostructures with hexagonal crown were synthesized on a Si substrate by direct thermal evaporation of zinc power at a low temperature of 600 °C and atmospheric pressure. Field emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, R...

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Veröffentlicht in:Thin solid films 2009-06, Vol.517 (15), p.4385-4389
Hauptverfasser: Yang, X.X., Lei, W., Zhang, X.B., Wang, B.P., Li, C., Hou, K., Cui, Y.K., Di, Y.S.
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container_end_page 4389
container_issue 15
container_start_page 4385
container_title Thin solid films
container_volume 517
creator Yang, X.X.
Lei, W.
Zhang, X.B.
Wang, B.P.
Li, C.
Hou, K.
Cui, Y.K.
Di, Y.S.
description Flower-like zinc oxide (ZnO) nanostructures with hexagonal crown were synthesized on a Si substrate by direct thermal evaporation of zinc power at a low temperature of 600 °C and atmospheric pressure. Field emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Raman spectroscopy and photoluminescence were applied to study the structural characteristics and optical properties of the product. The result indicated that the flower-like product with many slender branches and hexagonal crowns at the ends were single-crystalline wurtzite structures and were preferentially oriented in the direction. The photoluminescence spectrum demonstrated a strong UV emission band at about 386 nm and a green emission band at 516 nm. The field emission of the product showed a turn-on field of 3.0 V/µm at a current density of 0.1 μA/cm 2, while the emission current density reached about 1 mA/cm 2 at an applied field of 5.9 V/μm.
doi_str_mv 10.1016/j.tsf.2009.01.056
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subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
Electron and ion emission by liquids and solids
impact phenomena
Exact sciences and technology
Field emission
Field emission, ionization, evaporation, and desorption
Flower-like structure
Hexagonal crown
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Nanoscale materials and structures: fabrication and characterization
Optical properties
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Other topics in nanoscale materials and structures
Photoluminescence
Physics
Scanning electron microscopy
Theory and models of film growth
Thermal evaporation
X-ray diffraction
Zinc oxide
title Growth and optical and field emission properties of flower-like ZnO nanostructures with hexagonal crown
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