Efficient gas phase photodecomposition of acetone by Ru-doped Titania

Nanocrystalline titania particles doped with ruthenium oxide have been prepared by homogenous hydrolysis of TiOSO4 in aqueous solutions in the presence of urea. The synthesized particles were characterized by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), High Resolution Transmission E...

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Veröffentlicht in:Applied catalysis. B, Environmental Environmental, 2009-07, Vol.89 (3-4), p.613-619
Hauptverfasser: Houšková, Vendula, Štengl, Václav, Bakardjieva, Snejana, Murafa, Nataliya, Tyrpekl, Václav
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container_end_page 619
container_issue 3-4
container_start_page 613
container_title Applied catalysis. B, Environmental
container_volume 89
creator Houšková, Vendula
Štengl, Václav
Bakardjieva, Snejana
Murafa, Nataliya
Tyrpekl, Václav
description Nanocrystalline titania particles doped with ruthenium oxide have been prepared by homogenous hydrolysis of TiOSO4 in aqueous solutions in the presence of urea. The synthesized particles were characterized by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), High Resolution Transmission Electron Microscopy (HRTEM), Selected Area Electron Diffraction (SAED) and surface area (BET) and porosity determination (BJH). The photocatalytic activity of Ru-doped titania samples was determined in the gas phase by decomposition of acetone during irradiation at 365nm and 400nm. The Ru-doped titania samples demonstrated enhanced photocatalytic activity under visible light. Ruthenium oxide causes the anatase to rutile transformation to occur at lower temperatures and decreasing of band-gap energy of Ru-doped samples.
doi_str_mv 10.1016/j.apcatb.2009.01.023
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subjects Catalysis
Chemistry
Colloidal state and disperse state
Doped
Exact sciences and technology
General and physical chemistry
Photocatalytic activity
Photochemistry
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Porous materials
RuO2
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
TiO2
Urea
title Efficient gas phase photodecomposition of acetone by Ru-doped Titania
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