Efficient gas phase photodecomposition of acetone by Ru-doped Titania
Nanocrystalline titania particles doped with ruthenium oxide have been prepared by homogenous hydrolysis of TiOSO4 in aqueous solutions in the presence of urea. The synthesized particles were characterized by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), High Resolution Transmission E...
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Veröffentlicht in: | Applied catalysis. B, Environmental Environmental, 2009-07, Vol.89 (3-4), p.613-619 |
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creator | Houšková, Vendula Štengl, Václav Bakardjieva, Snejana Murafa, Nataliya Tyrpekl, Václav |
description | Nanocrystalline titania particles doped with ruthenium oxide have been prepared by homogenous hydrolysis of TiOSO4 in aqueous solutions in the presence of urea. The synthesized particles were characterized by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), High Resolution Transmission Electron Microscopy (HRTEM), Selected Area Electron Diffraction (SAED) and surface area (BET) and porosity determination (BJH). The photocatalytic activity of Ru-doped titania samples was determined in the gas phase by decomposition of acetone during irradiation at 365nm and 400nm. The Ru-doped titania samples demonstrated enhanced photocatalytic activity under visible light. Ruthenium oxide causes the anatase to rutile transformation to occur at lower temperatures and decreasing of band-gap energy of Ru-doped samples. |
doi_str_mv | 10.1016/j.apcatb.2009.01.023 |
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The synthesized particles were characterized by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), High Resolution Transmission Electron Microscopy (HRTEM), Selected Area Electron Diffraction (SAED) and surface area (BET) and porosity determination (BJH). The photocatalytic activity of Ru-doped titania samples was determined in the gas phase by decomposition of acetone during irradiation at 365nm and 400nm. The Ru-doped titania samples demonstrated enhanced photocatalytic activity under visible light. Ruthenium oxide causes the anatase to rutile transformation to occur at lower temperatures and decreasing of band-gap energy of Ru-doped samples.</description><identifier>ISSN: 0926-3373</identifier><identifier>EISSN: 1873-3883</identifier><identifier>DOI: 10.1016/j.apcatb.2009.01.023</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>Catalysis ; Chemistry ; Colloidal state and disperse state ; Doped ; Exact sciences and technology ; General and physical chemistry ; Photocatalytic activity ; Photochemistry ; Physical chemistry of induced reactions (with radiations, particles and ultrasonics) ; Porous materials ; RuO2 ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ; TiO2 ; Urea</subject><ispartof>Applied catalysis. 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Ruthenium oxide causes the anatase to rutile transformation to occur at lower temperatures and decreasing of band-gap energy of Ru-doped samples.</description><subject>Catalysis</subject><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Doped</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Photocatalytic activity</subject><subject>Photochemistry</subject><subject>Physical chemistry of induced reactions (with radiations, particles and ultrasonics)</subject><subject>Porous materials</subject><subject>RuO2</subject><subject>Theory of reactions, general kinetics. Catalysis. 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Nomenclature, chemical documentation, computer chemistry</topic><topic>TiO2</topic><topic>Urea</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Houšková, Vendula</creatorcontrib><creatorcontrib>Štengl, Václav</creatorcontrib><creatorcontrib>Bakardjieva, Snejana</creatorcontrib><creatorcontrib>Murafa, Nataliya</creatorcontrib><creatorcontrib>Tyrpekl, Václav</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied catalysis. 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subjects | Catalysis Chemistry Colloidal state and disperse state Doped Exact sciences and technology General and physical chemistry Photocatalytic activity Photochemistry Physical chemistry of induced reactions (with radiations, particles and ultrasonics) Porous materials RuO2 Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry TiO2 Urea |
title | Efficient gas phase photodecomposition of acetone by Ru-doped Titania |
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