Toward Interaction of Sensitizer and Functional Moieties in Hole-Transporting Materials for Efficient Semiconductor-Sensitized Solar Cells
Sb2S3-sensitized mesoporous-TiO2 solar cells using several conjugated polymers as hole-transporting materials (HTMs) are fabricated. We found that the cell performance was strongly correlated with the chemical interaction at the interface of Sb2S3 as sensitizer and the HTMs through the thiophene moi...
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| Veröffentlicht in: | Nano letters 2011-11, Vol.11 (11), p.4789-4793 |
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| container_title | Nano letters |
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| creator | Im, Sang Hyuk Lim, Choong-Sun Chang, Jeong Ah Lee, Yong Hui Maiti, Nilkamal Kim, Hi-Jung Nazeeruddin, Md. K Grätzel, Michael Seok, Sang Il |
| description | Sb2S3-sensitized mesoporous-TiO2 solar cells using several conjugated polymers as hole-transporting materials (HTMs) are fabricated. We found that the cell performance was strongly correlated with the chemical interaction at the interface of Sb2S3 as sensitizer and the HTMs through the thiophene moieties, which led to a higher fill factor (FF), open-circuit voltage (V oc), and short-circuit current density (J sc). With the application of PCPDTBT (poly(2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b′]dithiophene)-alt-4,7(2,1,3-benzothiadiazole)) as a HTM in a Sb2S3-sensitized solar cell, overall power conversion efficiencies of 6.18, 6.57, and 6.53% at 100, 50, and 10% solar irradiation, respectively, were achieved with a metal mask. |
| doi_str_mv | 10.1021/nl2026184 |
| format | Article |
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K ; Grätzel, Michael ; Seok, Sang Il</creator><creatorcontrib>Im, Sang Hyuk ; Lim, Choong-Sun ; Chang, Jeong Ah ; Lee, Yong Hui ; Maiti, Nilkamal ; Kim, Hi-Jung ; Nazeeruddin, Md. K ; Grätzel, Michael ; Seok, Sang Il</creatorcontrib><description>Sb2S3-sensitized mesoporous-TiO2 solar cells using several conjugated polymers as hole-transporting materials (HTMs) are fabricated. We found that the cell performance was strongly correlated with the chemical interaction at the interface of Sb2S3 as sensitizer and the HTMs through the thiophene moieties, which led to a higher fill factor (FF), open-circuit voltage (V oc), and short-circuit current density (J sc). With the application of PCPDTBT (poly(2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b′]dithiophene)-alt-4,7(2,1,3-benzothiadiazole)) as a HTM in a Sb2S3-sensitized solar cell, overall power conversion efficiencies of 6.18, 6.57, and 6.53% at 100, 50, and 10% solar irradiation, respectively, were achieved with a metal mask.</description><identifier>ISSN: 1530-6984</identifier><identifier>EISSN: 1530-6992</identifier><identifier>DOI: 10.1021/nl2026184</identifier><identifier>PMID: 21961842</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Antimony - chemistry ; Applied sciences ; Condensed matter: structure, mechanical and thermal properties ; Correlation ; Electric potential ; Electric Power Supplies ; Electron Transport ; Electronics ; Energy ; Energy conversion efficiency ; Equipment Design ; Equipment Failure Analysis ; Exact sciences and technology ; Materials ; Materials Testing ; Nanocrystalline materials ; Nanostructure ; Nanostructures - chemistry ; Nanostructures - ultrastructure ; Nanotechnology - instrumentation ; Natural energy ; Particle Size ; Photovoltaic cells ; Photovoltaic conversion ; Physics ; Polymers ; Radiation effects on specific materials ; Semiconductors ; Solar cells ; Solar cells. Photoelectrochemical cells ; Solar Energy ; Structure of solids and liquids; crystallography ; Volatile organic compounds ; Voltage</subject><ispartof>Nano letters, 2011-11, Vol.11 (11), p.4789-4793</ispartof><rights>Copyright © 2011 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a443t-db5aae4057adbcfbc961c0fa499779070818f900f481eb11ad74c62de484c8633</citedby><cites>FETCH-LOGICAL-a443t-db5aae4057adbcfbc961c0fa499779070818f900f481eb11ad74c62de484c8633</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/nl2026184$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/nl2026184$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,2752,27057,27905,27906,56719,56769</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24741037$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21961842$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Im, Sang Hyuk</creatorcontrib><creatorcontrib>Lim, Choong-Sun</creatorcontrib><creatorcontrib>Chang, Jeong Ah</creatorcontrib><creatorcontrib>Lee, Yong Hui</creatorcontrib><creatorcontrib>Maiti, Nilkamal</creatorcontrib><creatorcontrib>Kim, Hi-Jung</creatorcontrib><creatorcontrib>Nazeeruddin, Md. K</creatorcontrib><creatorcontrib>Grätzel, Michael</creatorcontrib><creatorcontrib>Seok, Sang Il</creatorcontrib><title>Toward Interaction of Sensitizer and Functional Moieties in Hole-Transporting Materials for Efficient Semiconductor-Sensitized Solar Cells</title><title>Nano letters</title><addtitle>Nano Lett</addtitle><description>Sb2S3-sensitized mesoporous-TiO2 solar cells using several conjugated polymers as hole-transporting materials (HTMs) are fabricated. We found that the cell performance was strongly correlated with the chemical interaction at the interface of Sb2S3 as sensitizer and the HTMs through the thiophene moieties, which led to a higher fill factor (FF), open-circuit voltage (V oc), and short-circuit current density (J sc). With the application of PCPDTBT (poly(2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b′]dithiophene)-alt-4,7(2,1,3-benzothiadiazole)) as a HTM in a Sb2S3-sensitized solar cell, overall power conversion efficiencies of 6.18, 6.57, and 6.53% at 100, 50, and 10% solar irradiation, respectively, were achieved with a metal mask.</description><subject>Antimony - chemistry</subject><subject>Applied sciences</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Correlation</subject><subject>Electric potential</subject><subject>Electric Power Supplies</subject><subject>Electron Transport</subject><subject>Electronics</subject><subject>Energy</subject><subject>Energy conversion efficiency</subject><subject>Equipment Design</subject><subject>Equipment Failure Analysis</subject><subject>Exact sciences and technology</subject><subject>Materials</subject><subject>Materials Testing</subject><subject>Nanocrystalline materials</subject><subject>Nanostructure</subject><subject>Nanostructures - chemistry</subject><subject>Nanostructures - ultrastructure</subject><subject>Nanotechnology - instrumentation</subject><subject>Natural energy</subject><subject>Particle Size</subject><subject>Photovoltaic cells</subject><subject>Photovoltaic conversion</subject><subject>Physics</subject><subject>Polymers</subject><subject>Radiation effects on specific materials</subject><subject>Semiconductors</subject><subject>Solar cells</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar Energy</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Volatile organic compounds</subject><subject>Voltage</subject><issn>1530-6984</issn><issn>1530-6992</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp90c1OFTEYBuDGaATRhTdgujHiYvBrpzOdLs0JCAmEBcf15Jv-mJI57bHtxMAleNUUOR42xlWb9Onbn5eQ9wxOGHD2JcwceM8G8YIcsq6FpleKv9zPB3FA3uR8CwCq7eA1OeBMPXJ-SH6v4y9Mhl6EYhPq4mOg0dEbG7Iv_t4misHQsyX8WcKZXkVvi7eZ-kDP42ybdcKQtzEVH37QK6wxHudMXUz01DmvvQ2l5m28jsEsusTU7NMNvYkzJrqy85zfkleu7rTvduMR-X52ul6dN5fX3y5WXy8bFKItjZk6RCugk2gm7SZdn6LBoVBKSgUSBjY4BeDEwOzEGBopdM-NFYPQQ9-2R-TTU-42xZ-LzWXc-KzrDTDYuORRQcuE5ExUefxfyWTPoeMt55V-fqI6xZyTdeM2-Q2mu5HB-FjSuC-p2g-72GXaWLOXf1up4OMOYNY4u_rD2udnJ6Rg0MpnhzqPt3FJtaD8jwMfAMvapuA</recordid><startdate>20111109</startdate><enddate>20111109</enddate><creator>Im, Sang Hyuk</creator><creator>Lim, Choong-Sun</creator><creator>Chang, Jeong Ah</creator><creator>Lee, Yong Hui</creator><creator>Maiti, Nilkamal</creator><creator>Kim, Hi-Jung</creator><creator>Nazeeruddin, Md. K</creator><creator>Grätzel, Michael</creator><creator>Seok, Sang Il</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20111109</creationdate><title>Toward Interaction of Sensitizer and Functional Moieties in Hole-Transporting Materials for Efficient Semiconductor-Sensitized Solar Cells</title><author>Im, Sang Hyuk ; Lim, Choong-Sun ; Chang, Jeong Ah ; Lee, Yong Hui ; Maiti, Nilkamal ; Kim, Hi-Jung ; Nazeeruddin, Md. K ; Grätzel, Michael ; Seok, Sang Il</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a443t-db5aae4057adbcfbc961c0fa499779070818f900f481eb11ad74c62de484c8633</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Antimony - chemistry</topic><topic>Applied sciences</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Correlation</topic><topic>Electric potential</topic><topic>Electric Power Supplies</topic><topic>Electron Transport</topic><topic>Electronics</topic><topic>Energy</topic><topic>Energy conversion efficiency</topic><topic>Equipment Design</topic><topic>Equipment Failure Analysis</topic><topic>Exact sciences and technology</topic><topic>Materials</topic><topic>Materials Testing</topic><topic>Nanocrystalline materials</topic><topic>Nanostructure</topic><topic>Nanostructures - chemistry</topic><topic>Nanostructures - ultrastructure</topic><topic>Nanotechnology - instrumentation</topic><topic>Natural energy</topic><topic>Particle Size</topic><topic>Photovoltaic cells</topic><topic>Photovoltaic conversion</topic><topic>Physics</topic><topic>Polymers</topic><topic>Radiation effects on specific materials</topic><topic>Semiconductors</topic><topic>Solar cells</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar Energy</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Volatile organic compounds</topic><topic>Voltage</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Im, Sang Hyuk</creatorcontrib><creatorcontrib>Lim, Choong-Sun</creatorcontrib><creatorcontrib>Chang, Jeong Ah</creatorcontrib><creatorcontrib>Lee, Yong Hui</creatorcontrib><creatorcontrib>Maiti, Nilkamal</creatorcontrib><creatorcontrib>Kim, Hi-Jung</creatorcontrib><creatorcontrib>Nazeeruddin, Md. K</creatorcontrib><creatorcontrib>Grätzel, Michael</creatorcontrib><creatorcontrib>Seok, Sang Il</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Nano letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Im, Sang Hyuk</au><au>Lim, Choong-Sun</au><au>Chang, Jeong Ah</au><au>Lee, Yong Hui</au><au>Maiti, Nilkamal</au><au>Kim, Hi-Jung</au><au>Nazeeruddin, Md. K</au><au>Grätzel, Michael</au><au>Seok, Sang Il</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Toward Interaction of Sensitizer and Functional Moieties in Hole-Transporting Materials for Efficient Semiconductor-Sensitized Solar Cells</atitle><jtitle>Nano letters</jtitle><addtitle>Nano Lett</addtitle><date>2011-11-09</date><risdate>2011</risdate><volume>11</volume><issue>11</issue><spage>4789</spage><epage>4793</epage><pages>4789-4793</pages><issn>1530-6984</issn><eissn>1530-6992</eissn><abstract>Sb2S3-sensitized mesoporous-TiO2 solar cells using several conjugated polymers as hole-transporting materials (HTMs) are fabricated. We found that the cell performance was strongly correlated with the chemical interaction at the interface of Sb2S3 as sensitizer and the HTMs through the thiophene moieties, which led to a higher fill factor (FF), open-circuit voltage (V oc), and short-circuit current density (J sc). With the application of PCPDTBT (poly(2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b′]dithiophene)-alt-4,7(2,1,3-benzothiadiazole)) as a HTM in a Sb2S3-sensitized solar cell, overall power conversion efficiencies of 6.18, 6.57, and 6.53% at 100, 50, and 10% solar irradiation, respectively, were achieved with a metal mask.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>21961842</pmid><doi>10.1021/nl2026184</doi><tpages>5</tpages></addata></record> |
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| ispartof | Nano letters, 2011-11, Vol.11 (11), p.4789-4793 |
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| subjects | Antimony - chemistry Applied sciences Condensed matter: structure, mechanical and thermal properties Correlation Electric potential Electric Power Supplies Electron Transport Electronics Energy Energy conversion efficiency Equipment Design Equipment Failure Analysis Exact sciences and technology Materials Materials Testing Nanocrystalline materials Nanostructure Nanostructures - chemistry Nanostructures - ultrastructure Nanotechnology - instrumentation Natural energy Particle Size Photovoltaic cells Photovoltaic conversion Physics Polymers Radiation effects on specific materials Semiconductors Solar cells Solar cells. Photoelectrochemical cells Solar Energy Structure of solids and liquids crystallography Volatile organic compounds Voltage |
| title | Toward Interaction of Sensitizer and Functional Moieties in Hole-Transporting Materials for Efficient Semiconductor-Sensitized Solar Cells |
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