Chelating agent free-solid phase extraction (CAF-SPE) of Co(II), Cu(II) and Cd(II) by new nano hybrid material (ZrO 2/B 2O 3)

► A novel sorbent for solid phase extraction for the preconcentration of metal ions. ► Hybrid nano-scale ZrO 2/B 2O 3 as a new SPE material. ► There is a no need for using any chelating agents before the preconcentration procedure. New nano hybrid material (ZrO 2/B 2O 3) was synthesized and applied...

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Veröffentlicht in:Journal of hazardous materials 2011-11, Vol.195, p.332-339
Hauptverfasser: Yalçınkaya, Özcan, Kalfa, Orhan Murat, Türker, Ali Rehber
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creator Yalçınkaya, Özcan
Kalfa, Orhan Murat
Türker, Ali Rehber
description ► A novel sorbent for solid phase extraction for the preconcentration of metal ions. ► Hybrid nano-scale ZrO 2/B 2O 3 as a new SPE material. ► There is a no need for using any chelating agents before the preconcentration procedure. New nano hybrid material (ZrO 2/B 2O 3) was synthesized and applied as a sorbent for the separation and/or preconcentration of Co(II), Cu(II) and Cd(II) in water and tea leaves prior to their determination by flame atomic absorption spectrometry. Synthesized nano material was characterized by scanning electron microscope, transmission electron microscope and X-ray diffraction. The optimum conditions for the quantitative recovery of the analytes, including pH, eluent type and volume, flow rate of sample solution were examined. The effect of interfering ions was also investigated. Under the optimum conditions, adsorption isotherms and adsorption capacities have been examined. The recoveries of Co(II), Cu(II) and Cd(II) were 96 ± 3%, 95 ± 3%, 98 ± 4% at 95% confidence level, respectively. The analytical detection limits for Co(II), Cu(II), and Cd(II) were 3.8, 3.3, and 3.1 μg L −1, respectively. The reusability and adsorption capacities (32.2 mg g −1 for Co, 46.5 mg g −1 for Cu and 109.9 mg g −1 for Cd) of the sorbent were found as satisfactory. The accuracy of the method was confirmed by analyzing certified reference material (GBW-07605 Tea leaves) and spiked real samples. The method was applied for the determination of analytes in tap water and tea leaves.
doi_str_mv 10.1016/j.jhazmat.2011.08.048
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New nano hybrid material (ZrO 2/B 2O 3) was synthesized and applied as a sorbent for the separation and/or preconcentration of Co(II), Cu(II) and Cd(II) in water and tea leaves prior to their determination by flame atomic absorption spectrometry. Synthesized nano material was characterized by scanning electron microscope, transmission electron microscope and X-ray diffraction. The optimum conditions for the quantitative recovery of the analytes, including pH, eluent type and volume, flow rate of sample solution were examined. The effect of interfering ions was also investigated. Under the optimum conditions, adsorption isotherms and adsorption capacities have been examined. The recoveries of Co(II), Cu(II) and Cd(II) were 96 ± 3%, 95 ± 3%, 98 ± 4% at 95% confidence level, respectively. The analytical detection limits for Co(II), Cu(II), and Cd(II) were 3.8, 3.3, and 3.1 μg L −1, respectively. 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New nano hybrid material (ZrO 2/B 2O 3) was synthesized and applied as a sorbent for the separation and/or preconcentration of Co(II), Cu(II) and Cd(II) in water and tea leaves prior to their determination by flame atomic absorption spectrometry. Synthesized nano material was characterized by scanning electron microscope, transmission electron microscope and X-ray diffraction. The optimum conditions for the quantitative recovery of the analytes, including pH, eluent type and volume, flow rate of sample solution were examined. The effect of interfering ions was also investigated. Under the optimum conditions, adsorption isotherms and adsorption capacities have been examined. The recoveries of Co(II), Cu(II) and Cd(II) were 96 ± 3%, 95 ± 3%, 98 ± 4% at 95% confidence level, respectively. The analytical detection limits for Co(II), Cu(II), and Cd(II) were 3.8, 3.3, and 3.1 μg L −1, respectively. The reusability and adsorption capacities (32.2 mg g −1 for Co, 46.5 mg g −1 for Cu and 109.9 mg g −1 for Cd) of the sorbent were found as satisfactory. The accuracy of the method was confirmed by analyzing certified reference material (GBW-07605 Tea leaves) and spiked real samples. 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Kalfa, Orhan Murat ; Türker, Ali Rehber</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c483t-8f6595197e924a8ce6773560b02716c3d1e416e958abcb7c6f0b23df3d68239c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Adsorption</topic><topic>Applied sciences</topic><topic>atomic absorption spectrometry</topic><topic>Boron Compounds - chemistry</topic><topic>Boron oxide</topic><topic>cadmium</topic><topic>Cadmium - isolation &amp; purification</topic><topic>chelating agents</topic><topic>Chelating Agents - chemistry</topic><topic>Chemical engineering</topic><topic>cobalt</topic><topic>copper</topic><topic>Copper - isolation &amp; purification</topic><topic>detection limit</topic><topic>Exact sciences and technology</topic><topic>Flame atomic absorption spectrometry</topic><topic>Heavy metal</topic><topic>Hydrogen-Ion Concentration</topic><topic>ions</topic><topic>Leaves</topic><topic>Microscopy, Electron, Scanning</topic><topic>Microscopy, Electron, Transmission</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanosorbent</topic><topic>Nanostructure</topic><topic>Nanostructures</topic><topic>Pollution</topic><topic>Preconcentration</topic><topic>scanning electron microscopes</topic><topic>Scanning electron microscopy</topic><topic>Solid Phase Extraction - methods</topic><topic>sorption isotherms</topic><topic>tap water</topic><topic>Tea</topic><topic>Thermodynamics</topic><topic>transmission electron microscopes</topic><topic>X-Ray Diffraction</topic><topic>Zirconia</topic><topic>Zirconium - chemistry</topic><topic>Zirconium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yalçınkaya, Özcan</creatorcontrib><creatorcontrib>Kalfa, Orhan Murat</creatorcontrib><creatorcontrib>Türker, Ali Rehber</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>MEDLINE - Academic</collection><collection>Environment Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><jtitle>Journal of hazardous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yalçınkaya, Özcan</au><au>Kalfa, Orhan Murat</au><au>Türker, Ali Rehber</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chelating agent free-solid phase extraction (CAF-SPE) of Co(II), Cu(II) and Cd(II) by new nano hybrid material (ZrO 2/B 2O 3)</atitle><jtitle>Journal of hazardous materials</jtitle><addtitle>J Hazard Mater</addtitle><date>2011-11-15</date><risdate>2011</risdate><volume>195</volume><spage>332</spage><epage>339</epage><pages>332-339</pages><issn>0304-3894</issn><eissn>1873-3336</eissn><coden>JHMAD9</coden><abstract>► A novel sorbent for solid phase extraction for the preconcentration of metal ions. ► Hybrid nano-scale ZrO 2/B 2O 3 as a new SPE material. ► There is a no need for using any chelating agents before the preconcentration procedure. New nano hybrid material (ZrO 2/B 2O 3) was synthesized and applied as a sorbent for the separation and/or preconcentration of Co(II), Cu(II) and Cd(II) in water and tea leaves prior to their determination by flame atomic absorption spectrometry. Synthesized nano material was characterized by scanning electron microscope, transmission electron microscope and X-ray diffraction. The optimum conditions for the quantitative recovery of the analytes, including pH, eluent type and volume, flow rate of sample solution were examined. The effect of interfering ions was also investigated. Under the optimum conditions, adsorption isotherms and adsorption capacities have been examined. The recoveries of Co(II), Cu(II) and Cd(II) were 96 ± 3%, 95 ± 3%, 98 ± 4% at 95% confidence level, respectively. The analytical detection limits for Co(II), Cu(II), and Cd(II) were 3.8, 3.3, and 3.1 μg L −1, respectively. The reusability and adsorption capacities (32.2 mg g −1 for Co, 46.5 mg g −1 for Cu and 109.9 mg g −1 for Cd) of the sorbent were found as satisfactory. The accuracy of the method was confirmed by analyzing certified reference material (GBW-07605 Tea leaves) and spiked real samples. The method was applied for the determination of analytes in tap water and tea leaves.</abstract><cop>Kidlington</cop><pub>Elsevier B.V</pub><pmid>21889841</pmid><doi>10.1016/j.jhazmat.2011.08.048</doi><tpages>8</tpages></addata></record>
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subjects Adsorption
Applied sciences
atomic absorption spectrometry
Boron Compounds - chemistry
Boron oxide
cadmium
Cadmium - isolation & purification
chelating agents
Chelating Agents - chemistry
Chemical engineering
cobalt
copper
Copper - isolation & purification
detection limit
Exact sciences and technology
Flame atomic absorption spectrometry
Heavy metal
Hydrogen-Ion Concentration
ions
Leaves
Microscopy, Electron, Scanning
Microscopy, Electron, Transmission
Nanocomposites
Nanomaterials
Nanosorbent
Nanostructure
Nanostructures
Pollution
Preconcentration
scanning electron microscopes
Scanning electron microscopy
Solid Phase Extraction - methods
sorption isotherms
tap water
Tea
Thermodynamics
transmission electron microscopes
X-Ray Diffraction
Zirconia
Zirconium - chemistry
Zirconium dioxide
title Chelating agent free-solid phase extraction (CAF-SPE) of Co(II), Cu(II) and Cd(II) by new nano hybrid material (ZrO 2/B 2O 3)
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