Column Studies for the Adsorption of Cationic Surfactant onto an Organic Polymer Resin and a Granular Activated Carbon
Adsorption beds containing granular activated carbon and organic polymer resin are used widely to remove organic pollutants from wastewaters and water streams. Adsorption polymers are becoming alternatives to activated carbon for removal of surfactants by adsorption techniques. This study investigat...
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| Veröffentlicht in: | Water environment research 2010-03, Vol.82 (3), p.209-215 |
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| creator | Vergili, Ilda Kaya, Yasemin Gönder, Zeren Beril Barlas, Hulusi |
| description | Adsorption beds containing granular activated carbon and organic polymer resin are used widely to remove organic pollutants from wastewaters and water streams. Adsorption polymers are becoming alternatives to activated carbon for removal of surfactants by adsorption techniques. This study investigated the adsorption characteristics of cetyl trimethylammonium bromide (CTAB) as a cationic surfactant for selected concentrations below and above critical micelle concentration (CMC). A series of column tests were performed to determine the breakthrough curves by using two different adsorbents: (1) Hydraffin CC 8X30 as a commercial granular activated carbon (GAC) and (2) Lewatit VPOC 1064 MD PH as a commercial organic polymer resin. In the experiments, the volumetric flow rate was maintained at 10.5 mL/min (approximately 2 m³/m² -h). Loading of adsorbents was continued until breakthrough was 10% of the feed concentration. The breakthrough took place at 488 bed volume (BV) below CMC (Cₒ = 40 mg/L) and 39 BV above CMC (Cₒ = 400 mg/L) onto GAC. The organic polymer resin, however, showed a higher adsorption capacity than GAC (1412 BV below CMC and 287 BV above CMC). From the Logit method, the value of adsorption rate coefficient (K) and adsorption capacity coefficient (N) were obtained. |
| doi_str_mv | 10.2175/106143009X12487095236351 |
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Adsorption polymers are becoming alternatives to activated carbon for removal of surfactants by adsorption techniques. This study investigated the adsorption characteristics of cetyl trimethylammonium bromide (CTAB) as a cationic surfactant for selected concentrations below and above critical micelle concentration (CMC). A series of column tests were performed to determine the breakthrough curves by using two different adsorbents: (1) Hydraffin CC 8X30 as a commercial granular activated carbon (GAC) and (2) Lewatit VPOC 1064 MD PH as a commercial organic polymer resin. In the experiments, the volumetric flow rate was maintained at 10.5 mL/min (approximately 2 m³/m² -h). Loading of adsorbents was continued until breakthrough was 10% of the feed concentration. The breakthrough took place at 488 bed volume (BV) below CMC (Cₒ = 40 mg/L) and 39 BV above CMC (Cₒ = 400 mg/L) onto GAC. The organic polymer resin, however, showed a higher adsorption capacity than GAC (1412 BV below CMC and 287 BV above CMC). From the Logit method, the value of adsorption rate coefficient (K) and adsorption capacity coefficient (N) were obtained.</description><identifier>ISSN: 1061-4303</identifier><identifier>EISSN: 1554-7531</identifier><identifier>DOI: 10.2175/106143009X12487095236351</identifier><identifier>PMID: 20369564</identifier><language>eng</language><publisher>Water Environment Federation 601 Wythe Street Alexandria, VA 22314‐1994 U.S.A: Water Environment Federation</publisher><subject>Activated carbon ; Adsorbents ; Adsorption ; Applied sciences ; breakthrough curves ; Cetrimonium Compounds - chemistry ; cetyl trimethylammonium bromide ; Charcoal - chemistry ; Chemical engineering ; CMC ; Coefficients ; Continental surface waters ; critical micelle concentration ; CTAB ; Exact sciences and technology ; General purification processes ; granular activated carbon ; Molecular structure ; Molecular weight ; Natural water pollution ; organic polymer resin ; Pollution ; Polymers ; Polymers - chemistry ; Resins ; Studies ; Surface-Active Agents - chemistry ; Surfactants ; Waste Management - methods ; Wastewater ; Wastewater treatment ; Wastewaters ; Water pollution ; Water quality ; Water treatment and pollution</subject><ispartof>Water environment research, 2010-03, Vol.82 (3), p.209-215</ispartof><rights>2010 WATER ENVIRONMENT FEDERATION (WEF)</rights><rights>2010 Water Environment Federation</rights><rights>2015 INIST-CNRS</rights><rights>Copyright Water Environment Federation Mar 2010</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4799-e0912f0ade9033d453097c5619c9c675b1035298d1ef1497189bd3ec6f6db2493</citedby><cites>FETCH-LOGICAL-c4799-e0912f0ade9033d453097c5619c9c675b1035298d1ef1497189bd3ec6f6db2493</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.jstor.org/stable/pdf/40575475$$EPDF$$P50$$Gjstor$$H</linktopdf><linktohtml>$$Uhttps://www.jstor.org/stable/40575475$$EHTML$$P50$$Gjstor$$H</linktohtml><link.rule.ids>314,780,784,803,1417,27924,27925,45574,45575,58017,58250</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22500630$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20369564$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Vergili, Ilda</creatorcontrib><creatorcontrib>Kaya, Yasemin</creatorcontrib><creatorcontrib>Gönder, Zeren Beril</creatorcontrib><creatorcontrib>Barlas, Hulusi</creatorcontrib><title>Column Studies for the Adsorption of Cationic Surfactant onto an Organic Polymer Resin and a Granular Activated Carbon</title><title>Water environment research</title><addtitle>Water Environ Res</addtitle><description>Adsorption beds containing granular activated carbon and organic polymer resin are used widely to remove organic pollutants from wastewaters and water streams. Adsorption polymers are becoming alternatives to activated carbon for removal of surfactants by adsorption techniques. This study investigated the adsorption characteristics of cetyl trimethylammonium bromide (CTAB) as a cationic surfactant for selected concentrations below and above critical micelle concentration (CMC). A series of column tests were performed to determine the breakthrough curves by using two different adsorbents: (1) Hydraffin CC 8X30 as a commercial granular activated carbon (GAC) and (2) Lewatit VPOC 1064 MD PH as a commercial organic polymer resin. In the experiments, the volumetric flow rate was maintained at 10.5 mL/min (approximately 2 m³/m² -h). Loading of adsorbents was continued until breakthrough was 10% of the feed concentration. The breakthrough took place at 488 bed volume (BV) below CMC (Cₒ = 40 mg/L) and 39 BV above CMC (Cₒ = 400 mg/L) onto GAC. The organic polymer resin, however, showed a higher adsorption capacity than GAC (1412 BV below CMC and 287 BV above CMC). From the Logit method, the value of adsorption rate coefficient (K) and adsorption capacity coefficient (N) were obtained.</description><subject>Activated carbon</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Applied sciences</subject><subject>breakthrough curves</subject><subject>Cetrimonium Compounds - chemistry</subject><subject>cetyl trimethylammonium bromide</subject><subject>Charcoal - chemistry</subject><subject>Chemical engineering</subject><subject>CMC</subject><subject>Coefficients</subject><subject>Continental surface waters</subject><subject>critical micelle concentration</subject><subject>CTAB</subject><subject>Exact sciences and technology</subject><subject>General purification processes</subject><subject>granular activated carbon</subject><subject>Molecular structure</subject><subject>Molecular weight</subject><subject>Natural water pollution</subject><subject>organic polymer resin</subject><subject>Pollution</subject><subject>Polymers</subject><subject>Polymers - chemistry</subject><subject>Resins</subject><subject>Studies</subject><subject>Surface-Active Agents - chemistry</subject><subject>Surfactants</subject><subject>Waste Management - methods</subject><subject>Wastewater</subject><subject>Wastewater treatment</subject><subject>Wastewaters</subject><subject>Water pollution</subject><subject>Water quality</subject><subject>Water treatment and 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research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vergili, Ilda</au><au>Kaya, Yasemin</au><au>Gönder, Zeren Beril</au><au>Barlas, Hulusi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Column Studies for the Adsorption of Cationic Surfactant onto an Organic Polymer Resin and a Granular Activated Carbon</atitle><jtitle>Water environment research</jtitle><addtitle>Water Environ Res</addtitle><date>2010-03</date><risdate>2010</risdate><volume>82</volume><issue>3</issue><spage>209</spage><epage>215</epage><pages>209-215</pages><issn>1061-4303</issn><eissn>1554-7531</eissn><abstract>Adsorption beds containing granular activated carbon and organic polymer resin are used widely to remove organic pollutants from wastewaters and water streams. Adsorption polymers are becoming alternatives to activated carbon for removal of surfactants by adsorption techniques. This study investigated the adsorption characteristics of cetyl trimethylammonium bromide (CTAB) as a cationic surfactant for selected concentrations below and above critical micelle concentration (CMC). A series of column tests were performed to determine the breakthrough curves by using two different adsorbents: (1) Hydraffin CC 8X30 as a commercial granular activated carbon (GAC) and (2) Lewatit VPOC 1064 MD PH as a commercial organic polymer resin. In the experiments, the volumetric flow rate was maintained at 10.5 mL/min (approximately 2 m³/m² -h). Loading of adsorbents was continued until breakthrough was 10% of the feed concentration. The breakthrough took place at 488 bed volume (BV) below CMC (Cₒ = 40 mg/L) and 39 BV above CMC (Cₒ = 400 mg/L) onto GAC. The organic polymer resin, however, showed a higher adsorption capacity than GAC (1412 BV below CMC and 287 BV above CMC). From the Logit method, the value of adsorption rate coefficient (K) and adsorption capacity coefficient (N) were obtained.</abstract><cop>Water Environment Federation 601 Wythe Street Alexandria, VA 22314‐1994 U.S.A</cop><pub>Water Environment Federation</pub><pmid>20369564</pmid><doi>10.2175/106143009X12487095236351</doi><tpages>7</tpages></addata></record> |
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| ispartof | Water environment research, 2010-03, Vol.82 (3), p.209-215 |
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| source | MEDLINE; JSTOR Archive Collection A-Z Listing; Wiley Online Library All Journals |
| subjects | Activated carbon Adsorbents Adsorption Applied sciences breakthrough curves Cetrimonium Compounds - chemistry cetyl trimethylammonium bromide Charcoal - chemistry Chemical engineering CMC Coefficients Continental surface waters critical micelle concentration CTAB Exact sciences and technology General purification processes granular activated carbon Molecular structure Molecular weight Natural water pollution organic polymer resin Pollution Polymers Polymers - chemistry Resins Studies Surface-Active Agents - chemistry Surfactants Waste Management - methods Wastewater Wastewater treatment Wastewaters Water pollution Water quality Water treatment and pollution |
| title | Column Studies for the Adsorption of Cationic Surfactant onto an Organic Polymer Resin and a Granular Activated Carbon |
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