A Geochemical and Geophysical Characterization of Sulfide Mine Ponds at the Iberian Pyrite Belt (Spain)

This work presents the results of a geochemical and geophysical characterization of the Monte Romero and La Naya mine ponds, belonging to the Cueva de la Mora and Riotinto mine districts, respectively, based on mineralogical, geochemical and geophysical techniques. In order to obtain a representativ...

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Veröffentlicht in:Water, air, and soil pollution air, and soil pollution, 2011-05, Vol.217 (1-4), p.387-405
Hauptverfasser: Martín-Crespo, Tomás, Martín-Velázquez, Silvia, Gómez-Ortiz, David, De Ignacio-San José, Cristina, Lillo-Ramos, Javier
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container_issue 1-4
container_start_page 387
container_title Water, air, and soil pollution
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creator Martín-Crespo, Tomás
Martín-Velázquez, Silvia
Gómez-Ortiz, David
De Ignacio-San José, Cristina
Lillo-Ramos, Javier
description This work presents the results of a geochemical and geophysical characterization of the Monte Romero and La Naya mine ponds, belonging to the Cueva de la Mora and Riotinto mine districts, respectively, based on mineralogical, geochemical and geophysical techniques. In order to obtain a representative environmental characterization, two deposits showing different mineralogies, physico-chemical parameters, chemical compositions of tailings and pond conditions were selected. Monte Romero mine tailings showed an upper level mainly composed of silicates and a deeper level mainly composed of sulfides and barite. The toxic metal content was different in both levels but high enough to exceed the regional legal concentration limits for agricultural soils. An electrical resistivity tomography survey revealed a homogeneous upper unit (3 m thickness), which displayed low resistivity values, corresponding to water-saturated silt and clay materials with an abundance of sulfides which was interpreted as the pond infilling. The La Naya mine pond presented a homogeneous mineralogical composition made up of quartz as the main mineral and chlorite-smectite and jarosite as accessory phases. The absence of sulfide phases and the low contents of metal elements are directly related to the reworking processes of the sludge dumped in this pond. The geophysical survey revealed that the pond infilling did not have a constant thickness, but ranged between 15 and 20 m. An inner groundwater flow in the infilling was recognized. The low resistivity values allowed the presence of acid waters and related subsurface flows to be identified in both mine ponds, but no acid water drainage occurred across their vessels. When compared to the Aznalcóllar tailings spill, the La Naya pond is large enough to release a similar amount of sludge, but of a very low metal content. The Monte Romero sludge displays a similar, potentially toxic metal content to the Aznalcóllar sludge, but its size is significantly smaller.
doi_str_mv 10.1007/s11270-010-0595-6
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The absence of sulfide phases and the low contents of metal elements are directly related to the reworking processes of the sludge dumped in this pond. The geophysical survey revealed that the pond infilling did not have a constant thickness, but ranged between 15 and 20 m. An inner groundwater flow in the infilling was recognized. The low resistivity values allowed the presence of acid waters and related subsurface flows to be identified in both mine ponds, but no acid water drainage occurred across their vessels. When compared to the Aznalcóllar tailings spill, the La Naya pond is large enough to release a similar amount of sludge, but of a very low metal content. 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The absence of sulfide phases and the low contents of metal elements are directly related to the reworking processes of the sludge dumped in this pond. The geophysical survey revealed that the pond infilling did not have a constant thickness, but ranged between 15 and 20 m. An inner groundwater flow in the infilling was recognized. The low resistivity values allowed the presence of acid waters and related subsurface flows to be identified in both mine ponds, but no acid water drainage occurred across their vessels. When compared to the Aznalcóllar tailings spill, the La Naya pond is large enough to release a similar amount of sludge, but of a very low metal content. The Monte Romero sludge displays a similar, potentially toxic metal content to the Aznalcóllar sludge, but its size is significantly smaller.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11270-010-0595-6</doi><tpages>19</tpages></addata></record>
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ispartof Water, air, and soil pollution, 2011-05, Vol.217 (1-4), p.387-405
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source SpringerNature Journals
subjects Acid mine drainage
Agricultural land
Atmospheric Protection/Air Quality Control/Air Pollution
Chemical properties
Clay
Climate Change/Climate Change Impacts
Earth and Environmental Science
Earth sciences
Earth, ocean, space
Electric properties
Electrical resistivity
Engineering and environment geology. Geothermics
Environment
Environmental impact
Environmental monitoring
Exact sciences and technology
Geochemistry
Groundwater
Groundwater flow
Heavy metals
Hydrogeology
Industrial wastes
Metals
Mine tailings
Mine wastes
Mineralogy
Minerals
Mining
Pollution, environment geology
Ponds
Pyrite
Sediments
Silicates
Silicon compounds
Sludge
Smectite
Soil contaminants
Soil Science & Conservation
Studies
Sulfides
Surveys
Tomography
Trace elements
Water Quality/Water Pollution
Water, Underground
title A Geochemical and Geophysical Characterization of Sulfide Mine Ponds at the Iberian Pyrite Belt (Spain)
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