Two new transition metal inorganic-organic hybrid borates: [tris(2-aminoethoxy)trihydroxyhexaborato]cobalt(II) and its nickel(II) analogue

Two new transition metal inorganic-organic hybrid borates: [tris(2-aminoethoxy)trihydroxyhexaborato]cobalt(II) and its nickel(II) analogue

The two isomorphous title compounds, [1,5,9‐tris(2‐aminoethoxy)‐3,7,11‐trihydroxy‐3,7,11‐tribora‐1,5,9‐triborata‐2,4,6,8,10,12‐hexaoxa‐13‐oxoniatricyclo[7.3.1.05,13]tridecane]cobalt(II), [Co(C6H21B6N3O13)] or Co{B6O7(OH)3[O(CH2)2NH2]3}, and the NiII analogue, [Ni(C6H21B6N3O13)], each consist of an M...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2011-11, Vol.67 (11), p.m338-m341
Hauptverfasser: Lan, Shao-Min, Di, Wen-Jing, Shao, Zhi-Dong, Liang, Yun-Xiao
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Sprache:eng
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Atoms & subatomic particles
Cobalt
Crystallography
Hydrogen bonds
Molecules
Nickel
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container_issue 11
container_start_page m338
container_title Acta crystallographica. Section C, Crystal structure communications
container_volume 67
creator Lan, Shao-Min
Di, Wen-Jing
Shao, Zhi-Dong
Liang, Yun-Xiao
description The two isomorphous title compounds, [1,5,9‐tris(2‐aminoethoxy)‐3,7,11‐trihydroxy‐3,7,11‐tribora‐1,5,9‐triborata‐2,4,6,8,10,12‐hexaoxa‐13‐oxoniatricyclo[7.3.1.05,13]tridecane]cobalt(II), [Co(C6H21B6N3O13)] or Co{B6O7(OH)3[O(CH2)2NH2]3}, and the NiII analogue, [Ni(C6H21B6N3O13)], each consist of an MII cation and an inorganic–organic hybrid {B6O7(OH)3[O(CH2)2NH2]3}2− anion. The MII cation lies on a crystallographic threefold axis (as does one O atom) and is octahedrally coordinated by three N atoms from the organic component. Three O atoms covalently link the B–O cluster and the organic component. Molecules are connected to one another through N—H...O and O—H...O hydrogen bonds, forming a three‐dimensional supramolecular network.
doi_str_mv 10.1107/S0108270111041072
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source Wiley Online Library Journals Frontfile Complete; Alma/SFX Local Collection
subjects Atoms & subatomic particles
Cobalt
Crystallography
Hydrogen bonds
Molecules
Nickel
title Two new transition metal inorganic-organic hybrid borates: [tris(2-aminoethoxy)trihydroxyhexaborato]cobalt(II) and its nickel(II) analogue
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