Characterization of a new cobalt precursor for focused beam deposition of magnetic nanostructures

The electrical and magnetic properties of nanowires deposited from cobalt tricarbonyl nitrosyl (Co(CO)3NO) precursor by focused electron beam- and focused ion beam-induced deposition (FEBID and FIBID) have been investigated. As-deposited nanowires have similar Co content, around 50–55at.%, but diffe...

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Veröffentlicht in:Microelectronic engineering 2011-08, Vol.88 (8), p.1955-1958
Hauptverfasser: Gazzadi, G.C., Mulders, J.J.L., Trompenaars, P., Ghirri, A., Rota, A., Affronte, M., Frabboni, S.
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container_end_page 1958
container_issue 8
container_start_page 1955
container_title Microelectronic engineering
container_volume 88
creator Gazzadi, G.C.
Mulders, J.J.L.
Trompenaars, P.
Ghirri, A.
Rota, A.
Affronte, M.
Frabboni, S.
description The electrical and magnetic properties of nanowires deposited from cobalt tricarbonyl nitrosyl (Co(CO)3NO) precursor by focused electron beam- and focused ion beam-induced deposition (FEBID and FIBID) have been investigated. As-deposited nanowires have similar Co content, around 50–55at.%, but different electrical behaviour: FEBID nanowire is highly resistive (6.3mΩcm at RT) and non-metallic at low T, while the FIBID one has much lower resistivity (189μΩcm at RT) and it is metallic. The magnetic properties, tested with magnetoresistance measurements, reveal a non-magnetic behaviour for both nanowires. After 400°C annealing in vacuum FEBID wire is much less resistive (62μΩcm at RT) and recovers the metallic behaviour at low T, and both FEBID and FIBID wires display ferromagnetic behaviour. Structural analysis by low energy-scanning transmission electron microscopy (LE-STEM) suggests that coarsening and interconnection of the Co nanograins are responsible for the improvement in electrical and magnetic properties.
doi_str_mv 10.1016/j.mee.2010.12.031
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As-deposited nanowires have similar Co content, around 50–55at.%, but different electrical behaviour: FEBID nanowire is highly resistive (6.3mΩcm at RT) and non-metallic at low T, while the FIBID one has much lower resistivity (189μΩcm at RT) and it is metallic. The magnetic properties, tested with magnetoresistance measurements, reveal a non-magnetic behaviour for both nanowires. After 400°C annealing in vacuum FEBID wire is much less resistive (62μΩcm at RT) and recovers the metallic behaviour at low T, and both FEBID and FIBID wires display ferromagnetic behaviour. Structural analysis by low energy-scanning transmission electron microscopy (LE-STEM) suggests that coarsening and interconnection of the Co nanograins are responsible for the improvement in electrical and magnetic properties.</description><identifier>ISSN: 0167-9317</identifier><identifier>EISSN: 1873-5568</identifier><identifier>DOI: 10.1016/j.mee.2010.12.031</identifier><identifier>CODEN: MIENEF</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Co precursor ; Cobalt ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Cross-disciplinary physics: materials science; rheology ; Deposition ; Electronics ; Exact sciences and technology ; Focused beam-induced deposition ; Magnetic nanostructures ; Magnetic properties ; Magnetic properties and materials ; Magnetic properties of nanostructures ; Materials science ; Methods of deposition of films and coatings; film growth and epitaxy ; Microelectronic fabrication (materials and surfaces technology) ; Molecular, atomic, ion, and chemical beam epitaxy ; Nanocomposites ; Nanolithography ; Nanomaterials ; Nanoscale materials and structures: fabrication and characterization ; Nanostructure ; Nanowires ; Physics ; Precursors ; Quantum wires ; Semiconductor electronics. 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subjects Applied sciences
Co precursor
Cobalt
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
Deposition
Electronics
Exact sciences and technology
Focused beam-induced deposition
Magnetic nanostructures
Magnetic properties
Magnetic properties and materials
Magnetic properties of nanostructures
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Microelectronic fabrication (materials and surfaces technology)
Molecular, atomic, ion, and chemical beam epitaxy
Nanocomposites
Nanolithography
Nanomaterials
Nanoscale materials and structures: fabrication and characterization
Nanostructure
Nanowires
Physics
Precursors
Quantum wires
Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices
title Characterization of a new cobalt precursor for focused beam deposition of magnetic nanostructures
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