Preparation and characterization of carbon based acid catalysts for the dehydration of 2-propanol
The catalytic conversion of 2-propanol on carbon based acid catalysts obtained by chemical activation of lignocellulosic waste with H 3PO 4 was investigated. The carbon acid catalysts were prepared in a single step, without the need for incorporating acid surface groups in a complementary step by ch...
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Veröffentlicht in: | Carbon (New York) 2009, Vol.47 (1), p.286-294 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | The catalytic conversion of 2-propanol on carbon based acid catalysts obtained by chemical activation of lignocellulosic waste with H
3PO
4 was investigated. The carbon acid catalysts were prepared in a single step, without the need for incorporating acid surface groups in a complementary step by chemical oxidation of the carbon surface. The porous structure was characterized by N
2 and CO
2 adsorption, showing a strong dependence on the impregnation ratio. The surface chemistry was studied by XPS and TPD. A significant amount of phosphorus remains on the catalysts surface, as phosphate and/or polyphosphate esters, stable at relatively high temperature ( |
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ISSN: | 0008-6223 1873-3891 |
DOI: | 10.1016/j.carbon.2008.10.008 |