Tuning the Properties of Functional Pyrrolidinium Polymers by (Co)polymerization of Diallyldimethylammonium Ionic Liquids
The synthesis and polymerization of novel diallyldimethylammonium ionic liquid monomers is described. A free‐radical polymerization follows a ring‐closing cyclopolymerization mechanism similar to the one observed previously for diallyldimethylammonium halides that leads to pyrrolidinium functional p...
Gespeichert in:
| Veröffentlicht in: | Macromolecular rapid communications. 2010-09, Vol.31 (18), p.1646-1651 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1651 |
|---|---|
| container_issue | 18 |
| container_start_page | 1646 |
| container_title | Macromolecular rapid communications. |
| container_volume | 31 |
| creator | Jovanovski, V. Marcilla, R. Mecerreyes, David |
| description | The synthesis and polymerization of novel diallyldimethylammonium ionic liquid monomers is described. A free‐radical polymerization follows a ring‐closing cyclopolymerization mechanism similar to the one observed previously for diallyldimethylammonium halides that leads to pyrrolidinium functional polymers. As previously observed in other families of polymeric ionic liquids, their physico‐chemical properties are seriously affected by the nature of the counter‐anion. As an example, the thermal stability increases following the trend SCN− |
| doi_str_mv | 10.1002/marc.201000215 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_901674198</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>866534295</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5105-2e321ca478f53d9eea4dc91591ed38a5fa66594a7c08e02897db7db681de65be3</originalsourceid><addsrcrecordid>eNqFkU1v1DAQhiMEoqVw5YhyQcAhiz_i2D5WC1sqbWGFlvZoeZ0JNTjx1k4E4dfjkGXhVsnSjKXnnbH8ZNlzjBYYIfK21cEsCEo9Ipg9yE4xI7igkvCHqUeEFJjS6iR7EuO3xIgSkcfZSUIrzjg_zcbt0Nnua97fQr4Jfg-htxBz3-SroTO99Z12-WYMwTtb284Obb7xbmwhxHw35q-X_s1-vttfesKn6DurnRtdbVvob0en29b_SV6mYvK1vRtsHZ9mjxrtIjw71LPsy-r9dvmhWH-6uFyerwvDMGIFAUqw0SUXDaO1BNBlbSRmEkNNhWaNriomS80NEoCIkLzepVMJXEPFdkDPslfz3H3wdwPEXrU2GnBOd-CHqCTCFS-xFPeSIm2iJZEskYuZNMHHGKBR-2CTilFhpCYvavKijl5S4MVh9LBroT7if0Uk4OUB0NFo1wTdGRv_cekTuBQTJ2fuh3Uw3rNWXZ1_Xv7_iGLO2tjDz2NWh--q4pQzdfPxQtGb6xW-ktdqS38DdYG4Uw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>866534295</pqid></control><display><type>article</type><title>Tuning the Properties of Functional Pyrrolidinium Polymers by (Co)polymerization of Diallyldimethylammonium Ionic Liquids</title><source>Wiley Online Library All Journals</source><creator>Jovanovski, V. ; Marcilla, R. ; Mecerreyes, David</creator><creatorcontrib>Jovanovski, V. ; Marcilla, R. ; Mecerreyes, David</creatorcontrib><description>The synthesis and polymerization of novel diallyldimethylammonium ionic liquid monomers is described. A free‐radical polymerization follows a ring‐closing cyclopolymerization mechanism similar to the one observed previously for diallyldimethylammonium halides that leads to pyrrolidinium functional polymers. As previously observed in other families of polymeric ionic liquids, their physico‐chemical properties are seriously affected by the nature of the counter‐anion. As an example, the thermal stability increases following the trend SCN− < ${\rm BF}_{4}^{ - }$ < ${\rm PF}_{6}^{ - }$ < bis(trifluoromethane)sulfonamide. Interestingly, this polymerization route may lead to the synthesis of a new family of random copolymers that have a similar poly(diallyldimethylammonium) backbone and a mixture of counter‐anions determined by the comonomer selection.
New polymeric ionic liquids that have pyrrolidinium moieties in the backbone are synthesized by polymerization of new diallyldimethylammonium ionic liquids having TFSI−, BF4−, PF6−, or SCN− anions. This polymerization route may lead to the synthesis of a new family of random copolymers that having a similar poly(DADMA+) backbone and a mixture of counter‐anions determined by the comonomer selection. The physico‐chemical properties of the polymers are determined by the counter‐anion composition.</description><identifier>ISSN: 1022-1336</identifier><identifier>ISSN: 1521-3927</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.201000215</identifier><identifier>PMID: 21567577</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; Copolymerization ; Exact sciences and technology ; functional polymers ; Halides ; Ionic liquids ; Monomers ; Organic polymers ; Physicochemistry of polymers ; polyelectrolytes ; Polymerization ; Polymers ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Synthesis ; Trends ; Tuning</subject><ispartof>Macromolecular rapid communications., 2010-09, Vol.31 (18), p.1646-1651</ispartof><rights>Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5105-2e321ca478f53d9eea4dc91591ed38a5fa66594a7c08e02897db7db681de65be3</citedby><cites>FETCH-LOGICAL-c5105-2e321ca478f53d9eea4dc91591ed38a5fa66594a7c08e02897db7db681de65be3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmarc.201000215$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmarc.201000215$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23217987$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21567577$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Jovanovski, V.</creatorcontrib><creatorcontrib>Marcilla, R.</creatorcontrib><creatorcontrib>Mecerreyes, David</creatorcontrib><title>Tuning the Properties of Functional Pyrrolidinium Polymers by (Co)polymerization of Diallyldimethylammonium Ionic Liquids</title><title>Macromolecular rapid communications.</title><addtitle>Macromol. Rapid Commun</addtitle><description>The synthesis and polymerization of novel diallyldimethylammonium ionic liquid monomers is described. A free‐radical polymerization follows a ring‐closing cyclopolymerization mechanism similar to the one observed previously for diallyldimethylammonium halides that leads to pyrrolidinium functional polymers. As previously observed in other families of polymeric ionic liquids, their physico‐chemical properties are seriously affected by the nature of the counter‐anion. As an example, the thermal stability increases following the trend SCN− < ${\rm BF}_{4}^{ - }$ < ${\rm PF}_{6}^{ - }$ < bis(trifluoromethane)sulfonamide. Interestingly, this polymerization route may lead to the synthesis of a new family of random copolymers that have a similar poly(diallyldimethylammonium) backbone and a mixture of counter‐anions determined by the comonomer selection.
New polymeric ionic liquids that have pyrrolidinium moieties in the backbone are synthesized by polymerization of new diallyldimethylammonium ionic liquids having TFSI−, BF4−, PF6−, or SCN− anions. This polymerization route may lead to the synthesis of a new family of random copolymers that having a similar poly(DADMA+) backbone and a mixture of counter‐anions determined by the comonomer selection. The physico‐chemical properties of the polymers are determined by the counter‐anion composition.</description><subject>Applied sciences</subject><subject>Copolymerization</subject><subject>Exact sciences and technology</subject><subject>functional polymers</subject><subject>Halides</subject><subject>Ionic liquids</subject><subject>Monomers</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>polyelectrolytes</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Synthesis</subject><subject>Trends</subject><subject>Tuning</subject><issn>1022-1336</issn><issn>1521-3927</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkU1v1DAQhiMEoqVw5YhyQcAhiz_i2D5WC1sqbWGFlvZoeZ0JNTjx1k4E4dfjkGXhVsnSjKXnnbH8ZNlzjBYYIfK21cEsCEo9Ipg9yE4xI7igkvCHqUeEFJjS6iR7EuO3xIgSkcfZSUIrzjg_zcbt0Nnua97fQr4Jfg-htxBz3-SroTO99Z12-WYMwTtb284Obb7xbmwhxHw35q-X_s1-vttfesKn6DurnRtdbVvob0en29b_SV6mYvK1vRtsHZ9mjxrtIjw71LPsy-r9dvmhWH-6uFyerwvDMGIFAUqw0SUXDaO1BNBlbSRmEkNNhWaNriomS80NEoCIkLzepVMJXEPFdkDPslfz3H3wdwPEXrU2GnBOd-CHqCTCFS-xFPeSIm2iJZEskYuZNMHHGKBR-2CTilFhpCYvavKijl5S4MVh9LBroT7if0Uk4OUB0NFo1wTdGRv_cekTuBQTJ2fuh3Uw3rNWXZ1_Xv7_iGLO2tjDz2NWh--q4pQzdfPxQtGb6xW-ktdqS38DdYG4Uw</recordid><startdate>20100915</startdate><enddate>20100915</enddate><creator>Jovanovski, V.</creator><creator>Marcilla, R.</creator><creator>Mecerreyes, David</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20100915</creationdate><title>Tuning the Properties of Functional Pyrrolidinium Polymers by (Co)polymerization of Diallyldimethylammonium Ionic Liquids</title><author>Jovanovski, V. ; Marcilla, R. ; Mecerreyes, David</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5105-2e321ca478f53d9eea4dc91591ed38a5fa66594a7c08e02897db7db681de65be3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>Copolymerization</topic><topic>Exact sciences and technology</topic><topic>functional polymers</topic><topic>Halides</topic><topic>Ionic liquids</topic><topic>Monomers</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>polyelectrolytes</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Synthesis</topic><topic>Trends</topic><topic>Tuning</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jovanovski, V.</creatorcontrib><creatorcontrib>Marcilla, R.</creatorcontrib><creatorcontrib>Mecerreyes, David</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jovanovski, V.</au><au>Marcilla, R.</au><au>Mecerreyes, David</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tuning the Properties of Functional Pyrrolidinium Polymers by (Co)polymerization of Diallyldimethylammonium Ionic Liquids</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2010-09-15</date><risdate>2010</risdate><volume>31</volume><issue>18</issue><spage>1646</spage><epage>1651</epage><pages>1646-1651</pages><issn>1022-1336</issn><issn>1521-3927</issn><eissn>1521-3927</eissn><abstract>The synthesis and polymerization of novel diallyldimethylammonium ionic liquid monomers is described. A free‐radical polymerization follows a ring‐closing cyclopolymerization mechanism similar to the one observed previously for diallyldimethylammonium halides that leads to pyrrolidinium functional polymers. As previously observed in other families of polymeric ionic liquids, their physico‐chemical properties are seriously affected by the nature of the counter‐anion. As an example, the thermal stability increases following the trend SCN− < ${\rm BF}_{4}^{ - }$ < ${\rm PF}_{6}^{ - }$ < bis(trifluoromethane)sulfonamide. Interestingly, this polymerization route may lead to the synthesis of a new family of random copolymers that have a similar poly(diallyldimethylammonium) backbone and a mixture of counter‐anions determined by the comonomer selection.
New polymeric ionic liquids that have pyrrolidinium moieties in the backbone are synthesized by polymerization of new diallyldimethylammonium ionic liquids having TFSI−, BF4−, PF6−, or SCN− anions. This polymerization route may lead to the synthesis of a new family of random copolymers that having a similar poly(DADMA+) backbone and a mixture of counter‐anions determined by the comonomer selection. The physico‐chemical properties of the polymers are determined by the counter‐anion composition.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>21567577</pmid><doi>10.1002/marc.201000215</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1022-1336 |
| ispartof | Macromolecular rapid communications., 2010-09, Vol.31 (18), p.1646-1651 |
| issn | 1022-1336 1521-3927 1521-3927 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_901674198 |
| source | Wiley Online Library All Journals |
| subjects | Applied sciences Copolymerization Exact sciences and technology functional polymers Halides Ionic liquids Monomers Organic polymers Physicochemistry of polymers polyelectrolytes Polymerization Polymers Preparation, kinetics, thermodynamics, mechanism and catalysts Synthesis Trends Tuning |
| title | Tuning the Properties of Functional Pyrrolidinium Polymers by (Co)polymerization of Diallyldimethylammonium Ionic Liquids |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-12T14%3A37%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Tuning%20the%20Properties%20of%20Functional%20Pyrrolidinium%20Polymers%20by%20(Co)polymerization%20of%20Diallyldimethylammonium%20Ionic%20Liquids&rft.jtitle=Macromolecular%20rapid%20communications.&rft.au=Jovanovski,%20V.&rft.date=2010-09-15&rft.volume=31&rft.issue=18&rft.spage=1646&rft.epage=1651&rft.pages=1646-1651&rft.issn=1022-1336&rft.eissn=1521-3927&rft_id=info:doi/10.1002/marc.201000215&rft_dat=%3Cproquest_cross%3E866534295%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=866534295&rft_id=info:pmid/21567577&rfr_iscdi=true |