Synthesis of functionalized fullerene-C₆₀ by the living anionic polymerization technique

The synthesis of functionalized fullerene-C₆₀ (C₆₀) was performed using living anionic polymerization. The metalation of the benzylic hydrogen atom on toluene or p-substituted toluene was conducted with the alkyllithium/amine system, and examined by living anionic polymerization of 1,3-cyclohexadien...

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Veröffentlicht in:	Journal of applied polymer science 2011-05, Vol.120 (3), p.1372-1378
Hauptverfasser:	Natori, Itaru, Natori, Shizue, Hirose, Yuto
Format:	Artikel
Sprache:	eng
Schlagworte:	addition of carbanion alkyllithium/amine system Anionic polymerization Applied sciences Bonding Buckminsterfullerene Cross-disciplinary physics: materials science rheology Exact sciences and technology Fullerenes Fullerenes and related materials diamonds, graphite functionalized fullerene Hydrogen atoms living anionic polymerization Materials science metalation Organic polymers Physicochemistry of polymers Physics Polymerization Polymers Preparation, kinetics, thermodynamics, mechanism and catalysts Solubility Specific materials Synthesis Toluene
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